{"id":28508,"date":"2018-08-06T01:00:00","date_gmt":"2018-08-09T03:55:56","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/08\/09\/%e7%a2%b3-%e7%a2%b3%e9%94%ae%e6%b4%bb%e5%8c%96%e6%96%b0%e7%aa%81%e7%a0%b4%ef%bc%81science%e6%8a%a5%e9%81%93%e9%9d%9e%e5%bc%a0%e5%8a%9b%e6%83%b0%e6%80%a7csp3-csp3%e9%94%ae%e6%96%ad%e8%a3%82\/"},"modified":"2018-08-09T11:55:59","modified_gmt":"2018-08-09T03:55:59","slug":"%e7%a2%b3-%e7%a2%b3%e9%94%ae%e6%b4%bb%e5%8c%96%e6%96%b0%e7%aa%81%e7%a0%b4%ef%bc%81science%e6%8a%a5%e9%81%93%e9%9d%9e%e5%bc%a0%e5%8a%9b%e6%83%b0%e6%80%a7csp3-csp3%e9%94%ae%e6%96%ad%e8%a3%82","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/28508\/","title":{"rendered":"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;\"><span style=\"line-height: 0px;\">\u200d\u200d<\/span><span style=\"font-size: 18.018px;line-height: 0px;\">\u200d<a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"      src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress8-1533786957.gif\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/span><\/a><\/span><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657574730&amp;idx=1&amp;sn=7001a26433acb77dcdd5629f27cd8b20&amp;chksm=80f7769ab780ff8cedab5baefd9bc7a02dd18b2191cd29afb2d190e8ea149564133c9437e7d5&amp;scene=21#wechat_redirect\" target=\"_blank\"><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u78b3-\u78b3\u952e\u662f\u6784\u6210\u6709\u673a\u5316\u5408\u7269\u57fa\u672c\u9aa8\u67b6\u7684\u5316\u5b66\u952e\uff0c\u78b3-\u78b3\u952e\u7684\u65ad\u88c2\u53cd\u5e94\u5728\u751f\u547d\u4f53\u7cfb\u548c\u5de5\u4e1a\u751f\u4ea7\u4e2d\u666e\u904d\u5b58\u5728\u3002\u53d1\u5c55\u78b3-\u78b3\u952e\u65ad\u88c2\u7684\u65b0\u65b9\u6cd5\u5177\u6709\u5341\u5206\u91cd\u8981\u7684\u610f\u4e49\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u4e3a\u73b0\u4ee3\u5408\u6210\u5316\u5b66\u7684\u5e94\u7528\u63d0\u4f9b\u5927\u91cf\u81ea\u7136\u754c\u4e2d\u5ec9\u4ef7\u6613\u5f97\u7684\u539f\u6750\u6599\uff0c\u8fd8\u80fd\u4e3a\u7f13\u89e3\u80fd\u6e90\u5371\u673a\u3001\u51cf\u5c11\u73af\u5883\u6c61\u67d3\u548c\u53ef\u518d\u751f\u8d44\u6e90\u7684\u5229\u7528\u63d0\u4f9b\u65b0\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u5982\u77f3\u6cb9\u5de5\u4e1a\u4ea7\u54c1\u7684\u6539\u6027\u5229\u7528\u3001\u9020\u6210\u767d\u8272\u6c61\u67d3\u7684\u5851\u6599\u5236\u54c1\u964d\u89e3\u4ee5\u53ca\u9ad8\u805a\u7269\u964d\u89e3\u518d\u8f6c\u5316\u5229\u7528\u7b49\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u4e0e\u5df2\u5e7f\u6cdb\u7814\u7a76\u3001\u65e5\u8d8b\u6210\u719f\u7684\u78b3-\u78b3\u952e\u5f62\u6210\u7684\u65b9\u6cd5\u76f8\u6bd4\uff0c\u78b3-\u78b3\u952e\u65ad\u88c2\u7684\u65b9\u6cd5\u5b66\u7814\u7a76\u4ecd\u76f8\u5bf9\u6ede\u540e\u3002<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u76f8\u6bd4\u4e8e\u57fa\u4e8e\u5b98\u80fd\u56e2\u5316\u5b66\uff08\u5982C-X\u952e\u8f6c\u5316\uff09\u548c\u975e\u5b98\u80fd\u56e2\u5316\u5b66\uff08\u5982C-H\u952e\u8f6c\u5316\uff09\u76ee\u6807\u5206\u5b50\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u73af\u72b6\u5206\u5b50\u7684\u78b3-\u78b3\u952e\u65ad\u88c2\u91cd\u7ec4\u7b56\u7565\u51e0\u4e4e\u65e0\u53ef\u66ff\u4ee3\uff0c\u5b83\u53ef\u4ee5\u6700\u5927\u9650\u5ea6\u5730\u6539\u53d8\u76ee\u6807\u5206\u5b50\u7684\u9aa8\u67b6\u7ed3\u6784\uff0c\u5728\u6784\u5efa\u5168\u65b0\u5f00\u94fe\u5206\u5b50\u7684\u540c\u65f6\u5bf9\u4e24\u4e2a\u672b\u7aef\u78b3\u539f\u5b50\u8fdb\u884c\u5b98\u80fd\u5316\u3002\u76ee\u524d\uff0c\u8fd9\u4e00\u7b56\u7565\u5df2\u5e7f\u6cdb\u7528\u4e8eC=C\u952e\u7684\u5f00\u73af\u590d\u5206\u89e3\u53ca\u81ed\u6c27\u5316\uff08\u56fe1A\uff09\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cC-C\u5355\u952e\u7684\u5f00\u73af\u65ad\u88c2\u91cd\u7ec4\u5177\u6709\u8f83\u5927\u7684\u5c40\u9650\u6027\uff0c\u4e00\u822c\u53ea\u53d1\u751f\u4e8e\u5177\u6709\u8f83\u5927\u5f20\u529b\u7684\u4e09\u3001\u56db\u5143\u73af\u5206\u5b50\u3002\u5c3d\u7ba1\u8fd1\u5e74\u6765\u4e00\u4e9b\u62a5\u9053\u53d1\u73b0\uff0c\u975e\u5f20\u529b\u7684\u4e94\u3001\u516d\u5143\u73af\u5e95\u7269\u4e5f\u80fd\u5b9e\u73b0\u8fd9\u4e00\u7c7b\u578b\u7684\u53cd\u5e94\uff0c\u4f46\u4e3b\u8981\u6d89\u53ca\u73af\u916e\u3001\u73af\u916e\u4e9a\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u4e14\u53d1\u751f\u65ad\u88c2\u7684\u78b3-\u78b3\u952e\u7c7b\u578b\u591a\u4e3a\u73af\u4e0a\u76f8\u5bf9\u6d3b\u6cfc\u7684C(sp<\/span><span style=\"font-size: 14px;\"><sup>2<\/sup><\/span><span style=\"font-size: 18px;\">)-C(sp<\/span><span style=\"font-size: 14px;\"><sup>2<\/sup><\/span><span style=\"font-size: 18px;\">\/sp<\/span><span style=\"font-size: 14px;\"><sup>3<\/sup><\/span><span style=\"font-size: 18px;\">)\u952e\u3002\u5982\u4f55\u901a\u8fc7\u5207\u65ad\u76f8\u5bf9\u60f0\u6027\u7684C(<span style=\"text-align: justify;font-size: 18px;\">sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span>)-C(<span style=\"text-align: justify;font-size: 18px;\">sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span>)\u952e\u6765\u6253\u5f00\u975e\u5f20\u529b\u7684\u7b80\u5355\u73af\u72b6\u5206\u5b50\uff08\u5982\u73af\u72b6\u80fa\u3001\u73af\u72b6\u919a\u3001\u73af\u72b6\u916e\uff09\u5e76\u91cd\u7ec4\u4ecd\u65e7\u5177\u6709\u76f8\u5f53\u7684\u96be\u5ea6\u548c\u6311\u6218\u6027\uff08\u56fe1B\uff09\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress4-1533786957.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe1. \u73af\u72b6\u5206\u5b50\u78b3-\u78b3\u952e\u65ad\u88c2\u91cd\u7ec4\u7b56\u7565\u91cd\u5efa\u5206\u5b50\u9aa8\u67b6\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Science<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u8fd1\u65e5\uff0c<strong>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/strong>\uff08UC Berkeley\uff09\u7684<strong>Richmond Sarpong<\/strong>\u6559\u6388\u8bfe\u9898\u7ec4\u5f00\u521b\u4e86<strong>\u4e00\u79cd\u5207\u65ad\u975e\u5f20\u529b\u73af\u72b6\u80fa\u5206\u5b50<span style=\"font-size: 18px;text-align: justify;\">C(sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span><span style=\"font-size: 18px;text-align: justify;\">)-C(sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span><span style=\"font-size: 18px;text-align: justify;\">)<\/span>\u952e\u7684\u65b0\u65b9\u6cd5<\/strong>\u3002\u8be5\u7814\u7a76\u4f7f\u7528\u94f6\u76d0\u4f5c\u4e3a\u4fc3\u8fdb\u5242\uff0cSelectflour\u4e3a\u6c27\u5316\u5242\u548c\u6c1f\u5316\u8bd5\u5242\uff0c\u901a\u8fc7\u5355\u7535\u5b50\u8f6c\u79fb\u673a\u7406\u5c06\u73af\u72b6\u80fa\u03b1-\u78b3\u6c27\u5316\u5e76\u751f\u6210\u70f7\u6c27\u81ea\u7531\u57faC-C-O\u2022\uff0c\u968f\u540e\u70f7\u6c27\u81ea\u7531\u57fa\u9a71\u52a8\u7684\u03b2-\u65ad\u88c2\u53ef\u9009\u62e9\u6027\u5730\u5b9e\u73b0\u73af\u4e0a\u60f0\u6027<span style=\"font-size: 18px;text-align: justify;\">C(sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span><span style=\"font-size: 18px;text-align: justify;\">)-C(sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span><span style=\"font-size: 18px;text-align: justify;\">)<\/span>\u952e\u65ad\u88c2\uff0c\u8fdb\u800c\u4ea7\u751f\u672b\u7aef\u78b3\u7532\u9170\u5316\u7684\u70f7\u57fa\u81ea\u7531\u57fa\uff0c\u5e76\u88ab\u6c1f\u6e90\u6355\u83b7\u3002\u8be5\u65b9\u6cd5\u53ef\u4ee5\u5b9e\u73b0\u4e00\u7cfb\u5217\u9971\u548c\u56db\u81f3\u516b\u5143\u6c2e\u6742\u73af\u5316\u5408\u7269\u7684\u78b3-\u78b3\u952e\u65ad\u88c2\uff0c\u751f\u6210\u672b\u7aef\u919b\u57fa\u548cF\u539f\u5b50\u53d6\u4ee3\u7684\u8102\u80aa\u94fe\u5206\u5b50\uff0c\u5e76\u53ef\u7528\u4e8e\u80bd\u7684\u540e\u671f\u4fee\u9970\uff0c\u76f8\u5173\u6210\u679c\u53d1\u8868\u5728<\/span><span style=\"font-size: 16px;\"><em><strong>Science&nbsp;<\/strong><\/em><\/span><span style=\"font-size: 18px;\">\u4e0a\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress6-1533786957.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe2. \u9971\u548c\u73af\u72b6\u80fa<span style=\"font-size: 16px;text-align: justify;\">C(sp<\/span><\/span><span style=\"text-align: justify;color: rgb(136, 136, 136);font-size: 12px;\"><sup>3<\/sup><\/span><span style=\"color: rgb(136, 136, 136);font-size: 16px;text-align: justify;\">)-C(sp<\/span><span style=\"text-align: justify;color: rgb(136, 136, 136);font-size: 12px;\"><sup>3<\/sup><\/span><span style=\"font-size: 16px;color: rgb(136, 136, 136);\"><span style=\"font-size: 16px;text-align: justify;\">)<\/span>\u952e\u65ad\u88c2\u3001\u7532\u9170\u5316-\u6c1f\u5316\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Science<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u70f7\u6c27\u81ea\u7531\u57fa\u9a71\u52a8\u7684\u03b2-\u65ad\u88c2\uff08\u03b2-Scission\/\u03b2-fragmentation\uff09\u548c\u70f7\u6c27\u91d1\u5c5e\u9a71\u52a8\u7684\u03b2-\u78b3\u6d88\u9664\uff08\u03b2-carbon elimination\uff09\u662f\u5b9e\u73b0\u9187\u7c7b\u5316\u5408\u7269\u03b2\u4f4dC-C\u952e\u65ad\u88c2\u4e0e\u91cd\u7ec4\u6700\u5e38\u7528\u7684\u65b9\u6cd5\uff0c\u4e5f\u662fC-C\u952e\u6d3b\u5316\u7684\u4e24\u5927\u57fa\u5143\u53cd\u5e94\u3002\u03b2-\u65ad\u88c2\u5c06\u9187\u5206\u5b50\u5207\u5272\u4e3a\u7fb0\u57fa\u4e0e\u78b3\u81ea\u7531\u57fa\uff0c\u03b2-\u78b3\u6d88\u9664\u5219\u5c06\u9187\u5206\u5b50\u5207\u5272\u4e3a\u7fb0\u57fa\u4e0e\u78b3\u91d1\u5c5e\u7269\u79cd\u3002\u867d\u7136\u4e8c\u8005\u90fd\u53ef\u9002\u7528\u4e8e\u5f20\u529b\u73af\u9187\u7c7b\u5e95\u7269\uff0c\u4f46\u662f\u5728\u975e\u5f20\u529b\u9187\u5206\u5b50\u4f53\u7cfb\u4e0b\u5374\u6709\u7740\u660e\u663e\u7684\u4e0d\u540c\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress4-1533786957-1.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">Richmond Sarpong\u6559\u6388\u3002\u56fe\u7247\u6765\u6e90\uff1aUC Berkeley<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u5728\u03b2-\u78b3\u6d88\u9664\u7684\u7b56\u7565\u4e2d\uff0c\u4e3a\u4e86\u907f\u514d\u70f7\u6c27\u57fa\u91d1\u5c5e\u7684\u03b2-H\u6d88\u9664\uff0c\u5e95\u7269\u9009\u62e9\u4e0a\u66f4\u591a\u662f\u4e09\u7ea7\u9187\u6216\u662f\u6709\u5bfc\u5411\u57fa\u56e2\u7684\u4e8c\u7ea7\u9187\uff1b\u6b64\u5916\uff0c\u5728\u78b3-\u78b3\u952e\u65ad\u88c2\u7684\u8fc7\u7a0b\u4e2d\uff0c\u91d1\u5c5e\u9700\u8981\u4e0eC-C\u7684\u03c3\u952e\u53d1\u751f\u4f5c\u7528\uff1b\u5728\u80fd\u91cf\u4e0a\uff0cC-C\u7684\u03c3\u6210\u952e\u8f68\u9053\u548c\u03c3*\u53cd\u952e\u8f68\u9053\u90fd\u96be\u4ee5\u4e0e\u91d1\u5c5e\u7684\u7a7a\u8f68\u9053\u3001\u586b\u5145\u8f68\u9053\u5339\u914d\uff08\u9664\u4e86\u5f20\u529bC-C\u7684\u03c3\u952e\uff09\uff0c\u8fd9\u65f6\u5c31\u9700\u8981\u501f\u52a9\u914d\u4f53\u548c\u9644\u8fd1\u03c0\u8f68\u9053\u57fa\u56e2\u3002\u56e0\u6b64\uff0c\u03b2-\u6d88\u9664\u7b56\u7565\u503e\u5411\u4e8e\u5207\u65ad\u9187\u5206\u5b50\u4e2d\u76f8\u5bf9\u5bcc\u7535\u6027\u7684\u82b3\u57fa\u78b3\u3001\u70ef\u4e19\u57fa\u78b3\u3001\u82c4\u57fa\u78b3\u3001\u7094\u57fa\u78b3\u7b49\uff0c\u540c\u65f6\u4e5f\u53ef\u4ee5\u751f\u6210\u65e0\u03b2-H\u3001\u76f8\u5bf9\u7a33\u5b9a\u7684\u78b3-\u91d1\u5c5e\u7269\u79cdR-M\uff08\u56fe3\uff09\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress9-1533786957.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe3. \u03b2-\u78b3\u6d88\u9664\u7b56\u7565\u4ee3\u8868\u6027\u7684\u975e\u5f20\u529b\u9187\u5206\u5b50<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u03b2-\u65ad\u88c2\u53ef\u4ee5\u4e0e\u03b2-\u78b3\u6d88\u9664\u5f62\u6210\u8f83\u597d\u7684\u4e92\u8865\uff0c\u8be5\u8fc7\u7a0b\u4e0d\u6d89\u53ca\u03b2-\u6c22\u6d88\u9664\u7684\u95ee\u9898\uff0c\u70f7\u6c27\u81ea\u7531\u57fa\u4e2d\u6c27\u539f\u5b50\u7684\u534a\u586b\u5145\u8f68\u9053\u4e5f\u53ef\u4ee5\u8f83\u597d\u5730\u4e0eC-C\u7684\u03c3\u952e\u53d1\u751f\u4f5c\u7528\uff0c\u9002\u7528\u4e8e\u5207\u65ad\u76f8\u5bf9\u60f0\u6027\u7684<span style=\"font-size: 18px;text-align: justify;\">C(sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span><span style=\"font-size: 18px;text-align: justify;\">)-C(sp<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>3<\/sup><\/span><span style=\"font-size: 18px;text-align: justify;\">)<\/span>\u952e\uff0c\u5e76\u5f62\u6210\u76f8\u5bf9\u7a33\u5b9a\u7684\u70f7\u57fa\u81ea\u7531\u57faR\u2022\uff0c\u7ee7\u800c\u53d1\u751f\u52a0\u6210\u6216\u53d6\u4ee3\u53cd\u5e94\u3002\u4f8b\u5982\uff0cBeckwith\u66fe\u62a5\u9053\u4e86\u4e8c\u7ea7\u73af\u620a\u6c27\u81ea\u7531\u57fa\u5728\u5ba4\u6e29\u4e0b\u53d1\u751f\u03b2-\u65ad\u88c2\u5f00\u73af\u53cd\u5e94\uff0c\u5f62\u6210\u70f7\u57fa\u81ea\u7531\u57fa\uff08<em>J. Am. Chem. Soc.<\/em>, <strong>1989<\/strong>, <em>111<\/em>, 230\uff09\uff08\u56fe4\uff09\u3002\u76ee\u524d\uff0c\u5728\u03b2-\u65ad\u88c2\u7684\u7b56\u7565\u4e2d\uff0c\u4eba\u4eec\u53ef\u4ee5\u901a\u8fc7\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\uff08\u4e3b\u8981\u4e3aAg\u50ac\u5316\uff09\u6216\u5149\u8bf1\u5bfc\u7b49\u65b9\u6cd5\u4fc3\u8fdb\u9187\u5206\u5b50\u4ea7\u751f\u70f7\u6c27\u81ea\u7531\u57fa\uff0c\u4ece\u800c\u8bf1\u5bfc\u78b3-\u78b3\u952e\u65ad\u88c2\u91cd\u7ec4\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress5-1533786957.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe4. \u70f7\u6c27\u81ea\u7531\u57fa\u8bf1\u5bfc\u03b2-\u65ad\u88c2\u5207\u65ad\u60f0\u6027<span style=\"font-size: 16px;text-align: justify;\">C(sp<\/span><\/span><span style=\"text-align: justify;color: rgb(136, 136, 136);font-size: 12px;\"><sup>3<\/sup><\/span><span style=\"color: rgb(136, 136, 136);font-size: 16px;text-align: justify;\">)-C(sp<\/span><span style=\"text-align: justify;color: rgb(136, 136, 136);font-size: 12px;\"><sup>3<\/sup><\/span><span style=\"font-size: 16px;color: rgb(136, 136, 136);\"><span style=\"font-size: 16px;text-align: justify;\">)<\/span>\u952e\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>J. Am. Chem. Soc.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u57fa\u4e8e\u6b64\uff0c\u4f5c\u8005\u8bbe\u60f3\u4f7f\u7528Ag\u76d0\uff08Ag<\/span><span style=\"font-size: 14px;\"><sup>2+<\/sup><\/span><span style=\"font-size: 18px;\">\/Ag<\/span><span style=\"font-size: 14px;\"><sup>+<\/sup><\/span><span style=\"font-size: 18px;\">\u6807\u51c6\u8fd8\u539f\u7535\u52bf\u4e3a+1.98 V vs SCE\uff09\u5c06\u73af\u80fa\u5206\u5b50\u6c27\u5316\u4e3a\u73af\u72b6\u4e9a\u94f5\u9633\u79bb\u5b50<strong>A<\/strong>\uff08\u9633\u6781\u5cf0\u7535\u4f4d\u4e3a+1.13 V vs SCE\uff09\uff0c\u968f\u540e\u5728H<\/span><span style=\"font-size: 14px;\"><sub>2<\/sub><\/span><span style=\"font-size: 18px;\">O\u7684\u4eb2\u6838\u8fdb\u653b\u4e0b\u751f\u6210\u03b1-\u78b3\u7f9f\u57fa\u53d6\u4ee3\u7684\u534a\u80fa\u919b<strong>B<\/strong>\uff0c<strong>B<\/strong>\u8fdb\u4e00\u6b65\u5728Ag\u76d0\u4f5c\u7528\u4e0b\u5f62\u6210\u70f7\u6c27\u81ea\u7531\u57fa\u5e76\u8bf1\u5bfc\u03b2-\u65ad\u88c2\u53d1\u751f\u5f00\u73af\uff0c\u751f\u6210\u672b\u7aef\u78b3\u7532\u9170\u5316\u7684\u70f7\u57fa\u81ea\u7531\u57fa<strong>C<\/strong>\uff0c<strong>C<\/strong>\u6700\u7ec8\u88ab\u4eb2\u7535\u6c1f\u5316\u8bd5\u5242\u6355\u83b7\u5f97\u5230\u7532\u9170\u5316-\u6c1f\u5316\u4ea7\u7269\uff08\u56fe5\uff09\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress1-1533786957-1.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe5. Ag\u76d0\u4fc3\u8fdb\u9971\u548c\u73af\u80fa\u5206\u5b50\u78b3-\u78b3\u952e\u65ad\u88c2\u91cd\u7ec4\u7684\u8bbe\u60f3\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Science<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u867d\u7136\u8fd9\u4e00\u4e32\u8054\u53cd\u5e94\u7b56\u7565\u770b\u4f3c\u5f88\u7b80\u5355\uff0c\u4f46\u8981\u5b9e\u73b0\u8fd9\u4e00\u8fc7\u7a0b\u4ecd\u7136\u5177\u6709\u76f8\u5f53\u7684\u96be\u5ea6\u3002\u4e00\u65b9\u9762\uff0c\u73af\u80fa\u5206\u5b50\u751f\u6210\u73af\u4e9a\u94f5\u9633\u79bb\u5b50<strong>A<\/strong>\u7684\u8fc7\u7a0b\u4e2d\u8fd8\u672a\u66fe\u6709\u4f7f\u7528Ag\u50ac\u5316\u4f53\u7cfb\u7684\u62a5\u9053\uff0c\u5e76\u4e14Ag\u50ac\u5316\u9187\u5206\u5b50\u7684\u03b2-\u65ad\u88c2\u91cd\u7ec4\u7b56\u7565\u4e2d\u591a\u4f7f\u7528\u4e09\u7ea7\u9187\u5e95\u7269\uff0c\u4e8c\u7ea7\u9187\u5e95\u7269\u9c9c\u6709\u62a5\u9053\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u534a\u80fa\u919b<strong>B<\/strong>\u66f4\u5bb9\u6613\u53d1\u751fC-N\u952e\u65ad\u88c2\u5f00\u73af\u6216\u8fc7\u5ea6\u6c27\u5316\u5f97\u5230\u73af\u72b6\u9170\u80fa\uff08\u56fe6\uff09\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress0-1533786957.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe6. Ag\u4fc3\u8fdb\u73af\u80fa\u5206\u5b50\u78b3-\u78b3\u952e\u65ad\u88c2\u91cd\u7ec4\u7684\u96be\u70b9\u3002<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u7ecf\u8fc7\u5927\u91cf\u7684\u53cd\u5e94\u6761\u4ef6\u7b5b\u9009\uff0c\u4f5c\u8005\u53d1\u73b0\u57284\u5f53\u91cfAgBF<\/span><span style=\"font-size: 14px;\"><sub>4<\/sub><\/span><span style=\"font-size: 18px;\">\u548cSelectflour\u7684\u4f5c\u7528\u4e0b\uff0c\u54cc\u5576<strong>1a<\/strong>\u5728\u4e19\u916e-\u6c34\uff081:9\uff09\u7684\u6df7\u5408\u6eb6\u5242\u4e2d\u300140 \u2103\u7684\u6761\u4ef6\u4e0b\u53cd\u5e941 h\u5373\u80fd\u53d1\u751f\u78b3-\u78b3\u952e\u65ad\u88c2\u5f00\u73af\u53cd\u5e94\uff0c\u4ee581%\u7684\u4ea7\u7387\u751f\u6210\u7532\u9170\u5316-\u6c1f\u5316\u4ea7\u7269<strong>2a<\/strong>\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress8-1533786957.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe7. \u53cd\u5e94\u6761\u4ef6\u7684\u7b5b\u9009\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Science<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u5728\u6700\u4f73\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf\u3002\u54cc\u5576N\u4e0a\u7684\u53d6\u4ee3\u57fa\u53ef\u4ee5\u662fBz\u3001Ac\u3001Boc\u3001Piv\uff08<strong>1a-1d<\/strong>\uff09\uff0c\u6c2e\u6742\u73af\u5927\u5c0f\u53ef\u4ee5\u662f\u56db\u5143\u5230\u516b\u5143\u73af\uff08<strong>1e-1h<\/strong>\uff09\uff0c\u54cc\u5576\u73af\u4e0a\u53ef\u4ee5\u517c\u5bb9\u70f7\u57fa\u548c\u916f\u57fa\uff0c\u5f53\u73af\u4e0a\u5b58\u5728\u7fa7\u57fa\u65f6\uff0c\u53cd\u5e94\u53ef\u901a\u8fc7\u81ea\u7531\u57fa\u8131\u7fa7\u5f15\u5165\u7b2c\u4e8c\u4e2aF\u539f\u5b50\uff08<strong>1s<\/strong>\u3001<strong>1t<\/strong>\uff09\u3002\u5bf9\u4e8eN-Bz\u54cc\u5576\u916e<strong>1r<\/strong>\uff0c\u53cd\u5e94\u751f\u6210\u6c1f\u5316\u4ea7\u7269\uff0c\u800cN-Me\u54cc\u5576\u916e\u6216\u5421\u54af\u916e<strong>1p<\/strong>\u3001<strong>1q<\/strong>\u53ca\u812f\u6c28\u9178\u916f<strong>1o<\/strong>\u5219\u751f\u6210\u8fc7\u5ea6\u6c27\u5316\u7684\u4ea7\u7269\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u90e8\u5206\u5e95\u7269\u5728\u53cd\u5e94\u540e\u751f\u6210\u4e86\u53bb\u7532\u9170\u5316-\u6c1f\u5316\u4ea7\u7269\u3002\u6b64\u5916\uff0c\u8be5\u65b9\u6cd5\u8fd8\u53ef\u5bf9\u80bd\u5206\u5b50\u4e2d\u7684\u542b\u6c2e\u6742\u73af\u8fdb\u884c\u540e\u671f\u4fee\u9970\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress7-1533786958.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe8. \u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Science<\/em><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><br  \/><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress0-1533786958.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe9. \u80bd\u5206\u5b50\u7684\u540e\u671f\u6c1f\u5316\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Science<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u63d0\u51fa\u4e86\u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406\uff1aSelectflour\u5c06Ag(I)\u6c27\u5316\u4e3aAg(II)\uff0c\u540c\u65f6\u751f\u6210\u81ea\u7531\u57fa\u9633\u79bb\u5b50<strong>5<\/strong>\uff0c\u968f\u540e\u73af\u80fa<strong>1a<\/strong>\u5728Ag(II)\u548c<strong>5<\/strong>\u7684\u4f5c\u7528\u4e0b\u751f\u6210\u73af\u72b6\u4e9a\u94f5\u9633\u79bb\u5b50<strong>A<\/strong>\uff0c\u5e76\u88ab<span style=\"text-align: justify;font-size: 18px;\">H<\/span><span style=\"text-align: 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A\u9014\u5f84\u751f\u6210<strong>2a<\/strong>\u540e\u53ef\u8fdb\u4e00\u6b65\u8f6c\u5316\u4e3a\u53bb\u7532\u9170\u5316\u4ea7\u7269<strong>6<\/strong>\uff0854%\uff09\u3002\u867d\u7136\u4f7f\u7528\u65e0\u6cd5\u53d1\u751fC-N\u952e\u73af\u5316\u7684\u919b<strong>7<\/strong>\u65f6\uff0c\u53cd\u5e94\u53ef\u901a\u8fc7Path B\u9014\u5f84\u5148\u6c27\u5316\u540e\u8131\u7fa7\u5f62\u6210\u53bb\u7532\u9170\u5316-\u6c1f\u5316\u4ea7\u7269<strong>8<\/strong>\uff0870%\uff09\uff1b\u4f46\u662f\u4f7f\u7528\u7fa7\u9178<strong>9<\/strong>\u65f6\u8131\u7fa7\u53cd\u5e94\u4ec5\u4ee523%\u7684\u4ea7\u7387\u751f\u6210\u53bb\u7532\u9170\u5316-\u6c1f\u5316\u4ea7\u7269<strong>6<\/strong>\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u53cd\u5e94\u4e2d\u4e24\u79cd\u4ea7\u7269\u5927\u90e8\u5206\u53ef\u80fd\u4e3b\u8981\u901a\u8fc7\u78b3-\u78b3\u952e\u65ad\u88c2\u5f00\u73af\u673a\u7406\uff0c\u5373Path A\u9014\u5f84\u751f\u6210\uff08\u56fe10C\uff09\u3002\u6b64\u5916\uff0c\u73af\u72b6\u70ef\u9170\u80fa<strong>10<\/strong>\u572825 mol%\u7684Ag\u76d0\u50ac\u5316\u4e0b\uff0c\u53ef\u901a\u8fc7C=C\u952e\u7684\u4eb2\u7535\u6c1f\u5316\u5f62\u6210\u03b2-\u6c1f\u4ee3\u4e2d\u95f4\u4f53<strong>11<\/strong>\uff0c<strong>11<\/strong>\u518d\u8fdb\u4e00\u6b65\u53d1\u751f\u78b3-\u78b3\u952e\u65ad\u88c2\u5f00\u73af\u751f\u6210\u672b\u7aef\u78b3\u5055\u4e8c\u6c1f\u53d6\u4ee3\u7684\u4ea7\u7269<strong>12<\/strong>\uff08\u56fe10D\uff09\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress5-1533786958.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe10. \u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406\u53ca\u5b9e\u9a8c\u9a8c\u8bc1\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Science<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u5728\u8c08\u5230\u8fd9\u9879\u5de5\u4f5c\u7684\u610f\u4e49\u65f6\uff0cRichmond Sarpong\u6559\u6388\u8bf4\u9053\uff0c\u201c\u5927\u591a\u6570\u590d\u6742\u5316\u5408\u7269\u7684\u540e\u671f\u5b98\u80fd\u5316\u90fd\u91c7\u7528C-H\u952e\u8f6c\u5316\u7684\u7b56\u7565\uff0c\u4f46\u8fd9\u53ea\u80fd\u5bf9\u5206\u5b50\u4e2d\u7684\u8fb9\u8fb9\u89d2\u89d2\u8fdb\u884c\u4fee\u9970\u201d\uff0c\u4ed6\u8fd8\u8865\u5145\u9053\uff0c\u201c\u5982\u679c\u60f3\u8981\u83b7\u5f97\u66f4\u5927\u7684\u6539\u53d8\uff0c\u4f60\u9700\u8981\u8003\u8651\u5206\u5b50\u6838\u5fc3\u4e0a\u7684C-C\u952e\u3002\u201d\u968f\u5fc3\u6240\u6b32\u5730\u5207\u65ad\u5206\u5b50\u4e2d\u7684\u78b3-\u78b3\u952e\uff0c\u53ef\u4ee5\u83b7\u5f97\u66f4\u4e30\u5bcc\u591a\u6837\u7684\u5206\u5b50\uff0c\u8fd9\u79cd\u5bf9\u5316\u5b66\u7a7a\u95f4\u7684\u81ea\u7531\u63a2\u7d22\u6709\u52a9\u4e8e\u53d1\u73b0\u65b0\u7684\u836f\u7269\u5206\u5b50<\/span>\u3002<span style=\"font-size: 14px;\"><sup>[1]<\/sup><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u82f1\u56fd\u683c\u62c9\u65af\u54e5\u5927\u5b66\u7684Jo\u00eblle Prunet\u6559\u6388\u5bf9\u8fd9\u9879\u5de5\u4f5c\u8d5e\u8d4f\u4e0d\u5df2\uff0c\u201c\u53cd\u5e94\u7b80\u6d01\u6709\u7528\uff0c\u8fd9\u6b63\u662f\u6211\u559c\u6b22\u7684\uff08\u6709\u673a\u5408\u6210\uff09\u65b9\u6cd5\u5b66\uff0c\u663e\u7136\uff0c\u8fd9\u662f\u4e00\u4e2a\u5f88\u6709\u60f3\u6cd5\u7684\u5de5\u4f5c\u3002\u201d\u5f53\u7136\uff0c\u8fd9\u9879\u65b0\u7684\u7814\u7a76\u4e5f\u5e76\u975e\u5b8c\u7f8e\u65e0\u7455\uff0c\u4f7f\u7528\u8fc7\u91cf\u7684Ag\u76d0\u548cSelectflour\u53ef\u80fd\u4f1a\u8ba9\u8fd9\u4e00\u65b9\u6cd5\u7684\u5b9e\u7528\u6027\u5927\u6253\u6298\u6263\u3002\u5bf9\u6b64\uff0cJo\u00eblle Prunet\u6559\u6388\u8868\u793a\uff0c\u201c4\u5f53\u91cf\u7684Ag\u76d0\u6709\u65f6\u53ef\u80fd\u8981\u6bd410 mol%\u7684Pd\u50ac\u5316\u5242\u66f4\u4fbf\u5b9c\u2026\u2026\u6211\u76f8\u4fe1\u8fd9\u4e2a\u7f3a\u70b9\u6700\u7ec8\u4f1a\u89e3\u51b3\uff0c\u4ea7\u7387\u4e5f\u4f1a\u63d0\u9ad8\u3002\u201d<span style=\"text-align: justify;font-size: 14px;\"><sup>[1]<\/sup><\/span><\/span><\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n<p><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress9-1533786958.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Deconstructive fluorination of cyclic amines by carbon-carbon cleavage<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">Science<\/span><\/em><span style=\"font-size: 14px;\">, <strong>2018<\/strong>, <em>361<\/em>, 171, DOI: 10.1126\/science.aat6365<\/span><\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n<p><span style=\"font-size: 14px;\">Richmond Sarpong<\/span><\/p>\n<p><span style=\"font-size: 14px;\">http:\/\/www.x-mol.com\/university\/faculty\/32<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 14px;\">\u53c2\u8003\u5185\u5bb9\uff1a<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 14px;\">1.https:\/\/www.chemistryworld.com\/news\/break-it-to-make-it-reaction-to-diversify-drugs-structures\/3009257.article&nbsp;<\/span><\/p>\n<p><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress10-1533786958.jpeg\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress4-1533786958.png\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"display: inline-block;color: transparent;clear: both;box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;word-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n<p style=\"box-sizing: border-box;\"><br style=\"box-sizing: border-box;\"  \/><\/p>\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\"><span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">\u957f\u6309<\/strong><\/span>\u4e0b\u56fe<strong style=\"box-sizing: border-box;\">\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<p style=\"margin-top: 10px;margin-bottom: 10px;text-align: center;box-sizing: border-box;\">\n<\/section>\n<\/section>\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-bottom: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-bottom: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section style=\"white-space: normal;\">\n<section >\n<section>\n<section>\n<section>\n<section >\n<section>\n<section>\n<p style=\"text-align: center;\"><br  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;word-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 18px;box-sizing: border-box !important;word-wrap: break-word !important;\">\u70b9\u51fb\u201c<span style=\"max-width: 100%;color: rgb(0, 122, 170);\">\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b&nbsp;<strong>\u5316\u5b66 \u2022 \u6750\u6599&nbsp;<\/strong>\u9886\u57df<span style=\"max-width: 100%;background-color: rgb(255, 218, 81);\">\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;word-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 14px;box-sizing: border-box !important;word-wrap: break-word !important;\"><\/span><img     style=\"color: rgb(0, 0, 0);font-size: 14px;line-height: 25.6px;box-sizing: border-box !important;word-wrap: break-word !important;width: auto !important;visibility: visible !important;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress0-1533786958.gif\" alt=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\" title=\"\u78b3-\u78b3\u952e\u6d3b\u5316\u65b0\u7a81\u7834\uff01Science\u62a5\u9053\u975e\u5f20\u529b\u60f0\u6027C(sp3)-C(sp3)\u952e\u65ad\u88c2\"  \/><\/p>\n<blockquote class='keep-source'>\n<p>\u59cb\u53d1\u4e8e\u5fae\u4fe1\u516c\u4f17\u53f7\uff1a                         X\u4e00MOL\u8d44\u8baf                      <\/p>\n<\/blockquote>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u200d\u200d\u200d \u78b3-\u78b3\u952e\u662f\u6784\u6210\u6709\u673a\u5316\u5408\u7269\u57fa\u672c\u9aa8\u67b6\u7684\u5316\u5b66\u952e\uff0c\u78b3-\u78b3\u952e\u7684\u65ad\u88c2\u53cd\u5e94\u5728\u751f\u547d\u4f53\u7cfb\u548c\u5de5\u4e1a\u751f\u4ea7\u4e2d\u666e\u904d\u5b58\u5728\u3002\u53d1\u5c55\u78b3-\u78b3 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":28509,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28508"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=28508"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28508\/revisions"}],"predecessor-version":[{"id":28530,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28508\/revisions\/28530"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/28509"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=28508"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=28508"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=28508"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}