{"id":28531,"date":"2018-08-06T01:00:00","date_gmt":"2018-08-09T03:56:01","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/08\/09\/tio2%e7%94%b5%e5%ad%90%e4%bc%a0%e8%be%93%e5%b1%82%e8%a1%a8%e9%9d%a2%e5%b7%a5%e7%a8%8b%ef%bc%8c%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e6%80%a7%e8%83%bd%e5%a4%a7\/"},"modified":"2018-08-09T11:56:04","modified_gmt":"2018-08-09T03:56:04","slug":"tio2%e7%94%b5%e5%ad%90%e4%bc%a0%e8%be%93%e5%b1%82%e8%a1%a8%e9%9d%a2%e5%b7%a5%e7%a8%8b%ef%bc%8c%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e6%80%a7%e8%83%bd%e5%a4%a7","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/28531\/","title":{"rendered":"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347"},"content":{"rendered":"
\n

\u200d\u200d<\/span>\u200d\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/span><\/a><\/span><\/a><\/p>\n


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\u9499\u949b\u77ff\u6750\u6599\u5728\u8fc7\u53bb\u51e0\u5e74\u5438\u5f15\u4e86\u5927\u91cf\u79d1\u7814\u56e2\u961f\u7684\u6ce8\u610f\u529b\u3002\u8fd9\u4e9b\u6750\u6599\u7531\u4e8e\u5177\u6709\u6781\u597d\u7684\u5149\u7535\u7279\u6027\uff0c\u5728\u592a\u9633\u80fd\u7535\u6c60\u5e94\u7528\u65b9\u9762\u53d6\u5f97\u4e86\u4e0d\u53ef\u601d\u8bae\u7684\u8fdb\u6b65\uff0c\u5b9e\u73b0\u4e86\u9ad8\u8fbe22.7%\u7684\u8ba4\u8bc1\u5149\u7535\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u3002\u8fd9\u4e9b\u8fdb\u6b65\u4e3b\u8981\u662f\u57fa\u4e8e\u754c\u9762\u5de5\u7a0b\u3001\u6210\u5206\u5de5\u7a0b\u3001\u7ed3\u6676\u5de5\u7a0b\u3001\u6dfb\u52a0\u5242\u5de5\u7a0b\u4ee5\u53ca\u949d\u5316\u6280\u672f\u7b49\u65b9\u9762\u7684\u4e00\u7cfb\u5217\u7a81\u7834\u3002\u4e0d\u8fc7\uff0c\u5728\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5546\u4e1a\u5316\u4e4b\u524d\uff0c\u5f88\u591a\u6311\u6218\u4ecd\u9700\u8981\u89e3\u51b3\uff0c\u6bd4\u5982\u5668\u4ef6\u7a33\u5b9a\u6027\u3001\u6269\u5c55\u6027\u3001\u8fdf\u6ede\u6548\u5e94\u4ee5\u53ca\u5236\u5907\u65f6\u95f4\u53ca\u6210\u672c\u3002\u5176\u4e2d\uff0c\u5e73\u9762\u5f02\u8d28\u7ed3\u7684\u5668\u4ef6\u5728\u5927\u89c4\u6a21\u5236\u5907\u65b9\u9762\u660e\u663e\u4f18\u4e8e\u4f20\u7edf\u7ed3\u6784\u7684\u4ecb\u5b54\u5668\u4ef6\uff0c\u6210\u672c\u66f4\u4f4e\u5236\u5907\u66f4\u5feb\uff0c\u8fd9\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\u662f\u4e00\u5927\u4f18\u52bf\u3002\u4f46\u662f\uff0c\u5e73\u9762\u9499\u949b\u77ff\u5668\u4ef6\u5374\u5b58\u5728\u8fdf\u6ede\u6548\u5e94\u53ca\u7a33\u5b9a\u6027\u7684\u95ee\u9898\u3002<\/span><\/p>\n


<\/p>\n

\u8fd1\u671f\u7684\u7814\u7a76\u8868\u660e\uff0c\u4f7f\u7528\u5bcc\u52d2\u70ef\u7c7b\u5206\u5b50PCBM\u53caC<\/span>60<\/sub><\/span>\u4f5c\u4e3a\u5e73\u9762\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7535\u5b50\u4f20\u8f93\u5c42\uff0c\u53ef\u5236\u5907\u9ad8\u6548\u65e0\u8fdf\u6ede\u7684\u5668\u4ef6\u3002\u4f46\u662f\uff0c\u5668\u4ef6\u7a33\u5b9a\u6027\u4ecd\u7136\u5b58\u5728\u5f88\u5927\u6311\u6218\u3002\u5728\u6b63\u5e38\u5668\u4ef6\u7ed3\u6784\u4e2d\uff0c\u56e0\u4e3a\u5177\u6709\u975e\u5e38\u597d\u7684\u80fd\u7ea7\u5339\u914d\uff0cTiO<\/span>2<\/sub><\/span>\u662f\u6700\u5e38\u89c4\u7684\u7535\u5b50\u4f20\u8f93\u5c42\u3002\u4f46\u662f\uff0c\u57fa\u4e8eTiO<\/span>2<\/sub><\/span>\u5668\u4ef6\u7684\u7535\u5b50\u8fc1\u79fb\u7387\u5374\u76f8\u5bf9\u8f83\u4f4e\uff0c\u8fd9\u4f7f\u5f97\u4e0e\u9499\u949b\u77ff\u5c42\u7684\u7535\u8377\u5206\u79bb\u4e0d\u5145\u5206\u3002\u4e3a\u4e86\u514b\u670dTiO<\/span>2<\/sub><\/span>\u7684\u5c40\u9650\uff0c\u4e4b\u524d\u62a5\u9053\u4e86\u5f88\u591a\u7b56\u7565\uff0c\u5305\u62ec\u7528\u65e0\u673a\u5143\u7d20\u63ba\u6742TiO<\/span>2<\/sub><\/span>\u6216\u8005\u7528\u5bcc\u52d2\u70ef\u6c27\u5316\u7269\u53caPCBM\u949d\u5316TiO<\/span>2<\/sub><\/span>\u8868\u9762\uff0c\u4e0d\u8fc7\u8fd9\u4e9b\u63aa\u65bd\u4e0d\u8db3\u4ee5\u5236\u5907\u7406\u60f3\u7684\u5e73\u9762\u9499\u949b\u77ff\u7535\u6c60\u3002\u8fd1\u65e5\uff0c\u9ebb\u7701\u7406\u5de5\u5b66\u9662<\/strong>\uff08MIT\uff09Jing Kong<\/strong>\u6559\u6388\u4e0eMohammad Mahdi Tavakoli<\/strong>\u535a\u58eb\u7b49\u7814\u7a76\u8005\u627e\u5230\u4e86\u4e00\u79cd\u65b0\u7684\u89e3\u51b3\u65b9\u6848\u3002\u4ed6\u4eec\u5728TiO<\/span>2<\/sub><\/span>\u4e0e\u9499\u949b\u77ff\u4e4b\u95f4\u63d2\u5165\u975e\u6676SnO<\/span>2<\/sub><\/span>\uff08a-SnO<\/span>2<\/sub><\/span>\uff09\u5c42<\/strong>\uff0c\u8fd9\u79cdTiO<\/span>2<\/sub><\/span>\u81f4\u5bc6\u5c42\uff08c-TiO<\/span>2<\/sub><\/span>\uff09\u548ca-SnO<\/span>2<\/sub><\/span>\u7684\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\u7ed3\u6784<\/strong>\uff0c\u4f7f\u5f97\u9499\u949b\u77ff\u7535\u6c60\u5668\u4ef6\u83b7\u5f97\u9ad8\u8fbe19.33\uff05\u7684PCE\uff0c\u5f00\u8def\u7535\u538b\uff08V<\/span>oc<\/sub><\/span>\uff09\u548c\u7a33\u5b9a\u6027\u90fd\u83b7\u5f97\u63d0\u9ad8\uff0c\u540c\u65f6\u8fdf\u6ede\u6548\u5e94\u51e0\u53ef\u5ffd\u7565\u3002<\/span><\/p>\n

\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/p>\n

\u56fe1. a\uff09a-SnO<\/span><\/span>2<\/sub><\/span>\u4e0a\u5c42\u626b\u63cf\u7535\u955c\u56fe\u3002b\uff09XRD\u56fe\u3002c\uff09\u754c\u9762\u626b\u9762\u7535\u955c\u56fe\u3002d\uff09\u5668\u4ef6\u793a\u610f\u56fe\u3002e\uff09\u622a\u9762\u7535\u955c\u4ee5\u5c55\u793a\u9499\u949b\u77ff\u5c42\u4e0eFTO\u73bb\u7483\u76f4\u63a5\u63a5\u89e6\u3002\u56fe\u7247\u6765\u6e90\uff1aAdv. Energy Mater.<\/em><\/span><\/p>\n


<\/p>\n

\u7531\u4e8ea-SnO<\/span>2<\/sub><\/span>\u7684\u975e\u6676\u6027\u8d28\uff0c\u626b\u63cf\u7535\u955c\u56fe\u53ea\u6709FTO\u7684\u6676\u7c92\u53ef\u89c1\uff08\u56fe1a\uff09\u3002\u5728FTO\u4e0a\u7684a-SnO<\/span>2<\/sub><\/span>\u8584\u819c\u5e76\u4e0d\u5e73\u6574\uff0c\u5982\u7ea2\u8272\u5708\u51fa\u7684\u533a\u57df\uff0c\u9499\u949b\u77ff\u8584\u819c\u53ef\u80fd\u4f1a\u4e0eFTO\u73bb\u7483\u76f4\u63a5\u63a5\u89e6\uff0c\u8fd9\u6837\u4f1a\u5bfc\u81f4\u5668\u4ef6\u7684\u91cd\u590d\u6027\u51fa\u73b0\u95ee\u9898\uff08\u56fe1e\uff09\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u4f5c\u8005\u5728a-SnO<\/span>2<\/sub><\/span>\u4e0eFTO\u73bb\u7483\u4e4b\u95f4\u6c89\u79ef\u4e86\u4e00\u5c42\u8584\u7684c-TiO<\/span>2<\/sub><\/span>\uff08\u56fe1c\uff09\u3002\u901a\u8fc7\u5229\u7528c-TiO<\/span>2<\/sub><\/span>\u5c42\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u5145\u5206\u5229\u7528a-SnO<\/span>2<\/sub><\/span>\u5c42\u826f\u597d\u7684\u7535\u8377\u62bd\u53d6\u80fd\u529b\uff0c\u8fd8\u53ef\u4ee5\u89e3\u51b3\u7c97\u7cd9FTO\u73bb\u7483\u8868\u9762a-SnO<\/span>2<\/sub><\/span>\u7684\u5747\u4e00\u6027\u95ee\u9898\uff08\u56fe1d\uff09\u3002<\/span><\/p>\n

\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/p>\n

\u56fe2. \u9499\u949b\u77ff\u8584\u819c\u7684\u5149\u5b66\u6d4b\u8bd5\u3002a\uff09\u7d2b\u5916\u5438\u6536\u53ca\u8367\u5149\u3002 b\uff09\u65f6\u95f4\u5206\u8fa8\u8367\u5149\u3002\u56fe\u7247\u6765\u6e90\uff1aAdv. Energy Mater.<\/em><\/span><\/p>\n


<\/p>\n

\u5149\u5b66\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0ca-SnO<\/span>2<\/sub><\/span>\u6bd4c-TiO<\/span>2<\/sub><\/span>\u5177\u6709\u66f4\u597d\u7684\u7535\u5b50\u4f20\u8f93\u80fd\u529b\uff0c\u800c\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\u5177\u6709\u4e0ea-SnO<\/span>2<\/sub><\/span>\u7c7b\u4f3c\u7684\u7535\u8377\u4f20\u8f93\u80fd\u529b\uff08\u56fe2a\uff09\u3002\u4ece\u56fe2b\u53ef\u4ee5\u770b\u51fa\uff0c\u53cc\u5c42\u754c\u9762\u53caa-SnO<\/span>2<\/sub><\/span>\u754c\u9762\u7684\u7535\u8377\u4f20\u8f93\u66f4\u5feb\uff0c\u8fd9\u4e9b\u6570\u636e\u4e5f\u652f\u6301\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\u53caa-SnO<\/span>2<\/sub><\/span>\u754c\u9762\u4f18\u826f\u7684\u4f20\u8f93\u6027\u80fd\u3002<\/span><\/p>\n


<\/p>\n

\u57fa\u4e8e\u8fd9\u79cd\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\uff0c\u4f5c\u8005\u5236\u5907\u4e86\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u5e76\u6d4b\u8bd5\u4e86\u5b83\u4eec\u7684\u6027\u80fd\u3002\u6570\u636e\u8868\u660e\uff08\u56fe3a\u53ca\u88681\uff09\uff0c\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\u80fd\u591f\u4f7f\u5f97\u9499\u949b\u77ff\u7535\u6c60\u7684\u6548\u7387\u5927\u589e\uff0c\u4e3b\u8981\u4f53\u73b0\u5728\u586b\u5145\u56e0\u5b50\uff08FF\uff09\u7684\u660e\u663e\u63d0\u9ad8\u3002\u800c\u4e14\uff0c\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u5668\u4ef6\u6709\u8f83\u4e3a\u7a33\u5b9a\u7684\u529f\u7387\u8f93\u51fa\uff08\u56fe3b\uff09\uff0c\u5916\u91cf\u5b50\u6548\u7387\uff08EQE\uff09\u4e5f\u53ef\u8fbe\u5230\u6700\u5927\u503c\uff08\u56fe3c\uff09\uff0c\u540c\u65f6\u8fd8\u5177\u6709\u826f\u597d\u7684\u7a33\u5b9a\u6027\uff08\u56fe3d\uff09\uff0c\u8fd9\u4e9b\u6027\u80fd\u90fd\u4f18\u4e8e\u4f20\u7edf\u7684\u5355\u5c42\u7ed3\u6784\u3002<\/span><\/p>\n

\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/p>\n

\u56fe3. a\uff09J-V\u66f2\u7ebf\u3002b\uff09\u6700\u5927\u529f\u7387\u968f\u65f6\u95f4\u53d8\u5316\u3002c\uff09\u5916\u91cf\u5b50\u6548\u7387\u66f2\u7ebf\u3002d\uff09\u7a33\u5b9a\u6027\u66f2\u7ebf\u3002\u56fe\u7247\u6765\u6e90\uff1aAdv. Energy Mater.<\/em><\/span><\/p>\n


<\/p>\n

\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/p>\n

\u88681. \u5668\u4ef6\u6548\u7387\u53c2\u6570\u8868\u3002\u56fe\u7247\u6765\u6e90\uff1aAdv. Energy Mater.<\/em><\/span><\/p>\n


<\/p>\n

\u672c\u6587\u91c7\u7528\u53cc\u5c42\u7ed3\u6784\u7684\u7535\u5b50\u4f20\u8f93\u5c42\u5236\u5907\u4e86\u9ad8\u6548\u7a33\u5b9a\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\uff0c\u83b7\u5f97\u4e86\u4e0d\u9519\u7684\u6027\u80fd\u6570\u636e\u3002\u4f46\u662f\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\u52bf\u5fc5\u4f1a\u589e\u52a0\u5236\u5907\u6210\u672c\uff0c\u51b5\u4e14\u53cc\u5c42\u7535\u5b50\u4f20\u8f93\u5c42\u8fd9\u4e2a\u6982\u5ff5\u672c\u8eab\u5e76\u4e0d\u65b0\u9c9c\uff0c\u5728\u8f83\u65e9\u65f6\u5019\u5c31\u5df2\u7ecf\u88ab\u62a5\u9053\u8fc7\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u672c\u6587\u7684\u8f83\u9ad8PCE\u66f4\u53d7\u4eba\u5173\u6ce8\u3002\u672a\u6765\u7684\u7814\u7a76\uff0c\u5982\u679c\u80fd\u5408\u6210\u4e00\u79cd\u66f4\u52a0\u7b80\u5355\u7684\u7535\u5b50\u4f20\u8f93\u6750\u6599\u6765\u89e3\u51b3\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u95ee\u9898\uff0c\u90a3\u5c06\u4f1a\u5e26\u6765\u5de8\u5927\u7684\u8fdb\u6b65\u3002<\/span><\/p>\n


<\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/p>\n

Surface Engineering of TiO<\/span>2<\/sub><\/span> ETL for Highly Efficient and Hysteresis-Less Planar Perovskite Solar Cell (21.4%) with Enhanced Open-Circuit Voltage and Stability<\/span><\/p>\n

Adv. Energy Mater.<\/span><\/em>, 2018<\/strong>, DOI: 10.1002\/aenm.201800794<\/span><\/p>\n


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\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n


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\"TiO2\u7535\u5b50\u4f20\u8f93\u5c42\u8868\u9762\u5de5\u7a0b\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd\u5927\u63d0\u5347\"<\/p>\n

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