{"id":28557,"date":"2018-08-06T01:00:00","date_gmt":"2018-08-09T03:56:10","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/08\/09\/%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91%e6%b0%b4%e4%bf%83%e8%bf%9b%e7%9a%84c-s%e6%88%90%e9%94%ae%e5%8f%8d%e5%ba%94\/"},"modified":"2018-08-09T11:56:13","modified_gmt":"2018-08-09T03:56:13","slug":"%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91%e6%b0%b4%e4%bf%83%e8%bf%9b%e7%9a%84c-s%e6%88%90%e9%94%ae%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/28557\/","title":{"rendered":"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94"},"content":{"rendered":"
\n

\u200d\u200d<\/span>\u200d\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/span><\/a><\/span><\/a><\/p>\n


<\/p>\n

\u6ce8\uff1a\u6587\u672b\u6709\u7814\u7a76\u56e2\u961f\u7b80\u4ecb <\/strong><\/em>\u53ca\u672c\u6587\u4f5c\u8005\u79d1\u7814\u601d\u8def\u5206\u6790<\/strong><\/em><\/span><\/p>\n


<\/span><\/p>\n

\u539f\u5b50\u7ecf\u6d4e\u6027\u9ad8\u3001\u65e0\u9700\u91d1\u5c5e\u53c2\u4e0e\u3001\u4ee5\u4e2d\u6027\u6c34\u6eb6\u6db2\u4f5c\u4e3a\u4ecb\u8d28\u3001\u80fd\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\u8fdb\u884c\u3001\u53cd\u5e94\u8fc7\u7a0b\u7b80\u4fbf\u3001\u4ea7\u7269\u6613\u4e8e\u5206\u79bb\u7684\u6709\u673a\u8f6c\u5316\u65b9\u6cd5\u662f\u5f53\u4eca\u5408\u6210\u5316\u5b66\u8ffd\u6c42\u7684\u76ee\u6807\u4e4b\u4e00\u3002\u8fd1\u65e5\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66<\/strong>\u7684\u7f57\u5fb7\u5e73<\/strong>\u6559\u6388\u56e2\u961f\u5b9e\u73b0\u4e86\u751f\u7269\u76f8\u5bb9\u6027\u7684\u6761\u4ef6\u4e0b\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94<\/strong>\u3002<\/span><\/p>\n


<\/span><\/p>\n

\u4f7f\u7528\u73af\u5883\u53cb\u597d\u3001\u7b80\u4fbf\u6613\u5f97\u3001\u65e0\u6bd2\u6216\u4f4e\u6bd2\u7684\u9187\u7c7b\u5316\u5408\u7269\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\uff0c\u8131\u6c34\u5076\u8054\u7684\u7b56\u7565\u6784\u7b51\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u952e\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u5173\u6ce8\u3002\u8be5\u53cd\u5e94\u539f\u5b50\u7ecf\u6d4e\u6027\u548c\u6b65\u9aa4\u7ecf\u6d4e\u6027\u9ad8\uff0c\u6c34\u662f\u4ec5\u6709\u7684\u526f\u4ea7\u7269\u3001\u73af\u5883\u53cb\u597d\u3002\u7136\u800cC-OH\u952e\u5177\u6709\u8f83\u9ad8\u7684\u952e\u80fd\uff0c\u5176\u6d3b\u6cfc\u7684\u8d28\u5b50\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u5236\u7ea6\u4e86\u9187\u5728\u8131\u6c34\u5076\u8054\u53cd\u5e94\u4e2d\u7684\u76f4\u63a5\u5229\u7528\uff0c\u56e0\u6b64\u901a\u5e38\u9700\u8981\u8f83\u4e3a\u82db\u523b\u7684\u6761\u4ef6\uff0c\u4f8b\u5982\u8f83\u9ad8\u7684\u6e29\u5ea6\u3001\u5b9a\u91cf\u7684\u9178\u6027\u6dfb\u52a0\u5242\u548c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\u6765\u6d3b\u5316C-OH\u952e\u3002\u6e29\u548c\u6761\u4ef6\u3001\u65e0\u91d1\u5c5e\u53c2\u4e0e\u4e0b\u76f4\u63a5\u901a\u8fc7\u9187\u7c7b\u5316\u5408\u7269\u53c2\u4e0e\u8131\u6c34\u5076\u8054\u53cd\u5e94\u6784\u7b51\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u952e\u662f\u5341\u5206\u5177\u6709\u5438\u5f15\u529b\u53c8\u5145\u6ee1\u6311\u6218\u6027\u7684\u8bfe\u9898\u3002<\/span><\/p>\n


<\/span><\/p>\n

\u7f57\u5fb7\u5e73\u6559\u6388\u56e2\u961f\u5728\u4e0a\u4e16\u7eaa\u4e5d\u5341\u5e74\u4ee3\u5f00\u59cb\u7eff\u8272\u6c34\u76f8\u53cd\u5e94\u7684\u7814\u7a76\uff0c\u4e3b\u8981\u63a2\u7a76\u94df\u5316\u5408\u7269\u76f8\u5173\u7684\u6c34\u76f8\u53cd\u5e94\u548c\u63a2\u7d22\u86cb\u767d\u5728\u65e0\u91d1\u5c5e\u53c2\u4e0e\u7684\u6e29\u548c\u6761\u4ef6\u4e0b\u9009\u62e9\u6027\u5b98\u80fd\u5316\u3002\u968f\u540e\uff0c\u8be5\u56e2\u961f\u81f4\u529b\u4e8e\u53d1\u5c55\u751f\u7269\u76f8\u5bb9\u6027\u6c34\u76f8\u6709\u673a\u5316\u5b66\u8f6c\u5316\u3002\u8fd1\u65e5\uff0c\u4ed6\u4eec\u56e2\u961f\u5728\u524d\u671f\u5173\u4e8e\u534a\u80f1\u6c28\u9178\u751f\u7269\u5076\u8054\uff08Angew. Chem. Int. Ed.<\/em>, 2014<\/strong>, 53<\/em>, 7491\uff09\u4ee5\u53caC-OH\/P-H\u952e\u8131\u6c34\u5076\u8054\u53cd\u5e94\uff08Green Chem.<\/em>, 2017<\/strong>, 19<\/em>, 2135\uff09\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u5b9e\u73b0\u4e86\u4e00\u79cd\u6e29\u548c\u6761\u4ef6\u4e0b\u4e9a\u78fa\u9178\u548c\u70ef\u4e19\u9187\u5316\u5408\u7269\u4e4b\u95f4\u8131\u6c34\u5076\u8054\u7684\u65b9\u6cd5\u3002\u8be5\u53cd\u5e94\u65e0\u9700\u91d1\u5c5e\u50ac\u5316\uff0c\u4ee5\u4e2d\u6027\u6c34\u6eb6\u6db2\u4e3a\u4ecb\u8d28\uff0c\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\u9ad8\u6548\u6784\u7b51\u4e86\u70ef\u4e19\u57fa\u781c\u7c7b\u5316\u5408\u7269\uff08\u542b\u4e00\u7cfb\u5217\u5df2\u77e5\u5b58\u5728\u6297\u764c\u6d3b\u6027\u7684\u5206\u5b50\uff09\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u6c34\u5bf9\u8be5\u53cd\u5e94\u5177\u6709\u663e\u8457\u7684\u4fc3\u8fdb\u4f5c\u7528\uff0c\u4ed6\u4eec\u8fd8\u901a\u8fc7DFT\u8ba1\u7b97\u5bf9\u53cd\u5e94\u7684\u673a\u7406\u8fdb\u884c\u4e86\u521d\u6b65\u63a8\u6d4b\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n


<\/p>\n

\u8be5\u53cd\u5e94\u5bf9\u5b98\u80fd\u56e2\u7684\u517c\u5bb9\u6027\u597d\uff0c\u6e29\u548c\u6761\u4ef6\u4e0b\u534a\u80f1\u6c28\u9178\u4e9a\u78fa\u9178\u3001\u4e9a\u725b\u78fa\u9178\u90fd\u80fd\u5f88\u597d\u5730\u53c2\u4e0e\u53cd\u5e94\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u70ef\u4e19\u57fa\u781c\u5316\u5408\u7269\u3002\u56e0\u6b64\uff0c\u8be5\u7814\u7a76\u5bf9\u4e8e\u8148\u6c34\u5408\u9176\u3001\u57fa\u8d28\u6eb6\u89e3\u56e0\u5b50\u3001\u5e15\u91d1\u68ee\u75be\u75c5DJ-1\u86cb\u767d\u7684\u4e9a\u78fa\u9170\u5316\u7684\u7814\u7a76\u5177\u6709\u6f5c\u5728\u7684\u91cd\u8981\u610f\u4e49\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n


<\/p>\n

\u8fd9\u4e00\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728Nature Communications <\/em><\/strong>\u4e0a\uff0c\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u89e3\u6c9b\u5fe0<\/strong>\u526f\u6559\u6388\u3002Katherine J. Geogheghan<\/strong>\u6559\u6388\uff08Associate Editor, Nature Chemistry<\/em>\uff09\u5bf9\u8be5\u7814\u7a76\u6210\u679c\u8fdb\u884c\u4e86\u4e13\u6587\u4eae\u70b9\u8bc4\u8ff0<\/span>\u30021<\/sup><\/span><\/p>\n


<\/span><\/p>\n

\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong>Peizhong Xie, Jinyu Wang, Yanan Liu, Jing Fan, Xiangyang Wo, Weishan Fu, Zuolian Sun, Teck-Peng Loh<\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n

Water-promoted C-S bond formation reactions<\/span><\/p>\n

Nat. Commun.<\/span><\/em>, 2018<\/strong>, 9<\/em>, 1321, DOI: 10.1038\/s41467-018-03698-8<\/span><\/p>\n


<\/p>\n

\u53c2\u8003\u5185\u5bb9\uff1a<\/span><\/p>\n

1.\thttps:\/\/www.nature.com\/articles\/s41570-018-0002-1<\/span><\/p>\n


<\/p>\n

\u7f57\u5fb7\u5e73\u6559\u6388\u7b80\u4ecb<\/span><\/strong><\/p>\n


<\/p>\n

\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n

\u7f57\u5fb7\u5e73\uff08Teck-Peng Loh\uff09\u6559\u6388\uff0c\u7537\uff0c\u56fd\u9645\u8457\u540d\u5316\u5b66\u5bb6\u3001\u4e2d\u7ec4\u90e8\u5343\u4eba\u8ba1\u5212\u83b7\u5f97\u8005\uff0c\u65b0\u52a0\u5761\u56fd\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\u3001\u9a6c\u6765\u897f\u4e9a\u79d1\u5b66\u9662\u9662\u58eb\u3001\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u5316\u5b66\u7cfb\u521b\u5efa\u8005\uff1b1994\u5e74\u83b7\u5f97\u7f8e\u56fd\u54c8\u4f5b\u5927\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c1994\u5e74\u81f32005\u5e74\u5148\u540e\u62c5\u4efb\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u52a9\u7406\u6559\u6388\u3001\u526f\u6559\u6388\u548c\u6559\u6388\uff1b2005\u5e74\u8d77\u52a0\u5165\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\uff0c\u7531\u5176\u7ec4\u5efa\u7684\u6570\u7406\u5b66\u9662\u5316\u5b66\u4e0e\u751f\u7269\u5316\u5b66\u7cfb\u5728\u77ed\u77ed\u5341\u5e74\u5185\u4e00\u8dc3\u6210\u4e3a\u540d\u5217\u4e16\u754c\u524d\u8305\u7684\u77e5\u540d\u9662\u7cfb\uff1b2010\u5e74\u5165\u9009\u4e2d\u7ec4\u90e8\u201c\u5343\u4eba\u8ba1\u5212\u201d\u4e13\u5bb6\uff1b2016\u5e74\u52a0\u76df\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\uff0c\u62c5\u4efb\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u3001\u5148\u8fdb\u5316\u5b66\u5236\u9020\u7814\u7a76\u9662\u9662\u957f\uff1b2004\u5e74\u83b7\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u7814\u7a76\u4f18\u79c0\u5956\uff08\u4e2a\u4eba\uff09\uff0c2007\u5e74\u83b7\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u7814\u7a76\u4e0e\u521b\u65b0\u5956\uff08\u4e2a\u4eba\uff09\uff0c2009-2015\u5e74\u83b7\u4e9a\u6d32\u6838\u5fc3\u8ba1\u5212\u8bb2\u5ea7\u5956\uff0c2010\u5e74\u83b7\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u6570\u7406\u79d1\u5b66\u5b66\u9662\uff08SPMS\uff09\u4f18\u79c0\u6559\u5b66\u5956\uff0c2010\u5e74\u83b7GSK-SNIC\u6709\u673a\u5316\u5b66\u5956\uff0c2017\u5e74\u83b7\u5f97\u65e5\u672c\u7b2c\u4e09\u5c4a\u5409\u7530\u5956\uff08Yoshida Prize\uff09\u3002\u7f57\u5fb7\u5e73\u6559\u6388\u7684\u7814\u7a76\u5174\u8da3\u6d89\u53ca\u6709\u673a\u5408\u6210\u7684\u5404\u4e2a\u9886\u57df\uff0c\u5305\u62ec\u7eff\u8272\u5316\u5b66\u3001\u4e0d\u5bf9\u79f0\u50ac\u5316\u3001\u65b0\u7684\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\u3001\u751f\u7269\u8d28\u8f6c\u5316\u3001\u6709\u751f\u7269\u6d3b\u6027\u7684\u5929\u7136\u4ea7\u7269\u5206\u5b50\u7684\u5168\u5408\u6210\uff0c\u5df2\u7ecf\u5728Nat. Commun.\u3001J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed. <\/em>\u7b49\u56fd\u9645\u8457\u540d\u5316\u5b66\u671f\u520a\u53d1\u8868\u9ad8\u6c34\u5e73\u8bba\u6587300\u4f59\u7bc7\uff0c\u5176\u4e2d\u5f71\u54cd\u56e0\u5b50\u5927\u4e8e10\u7684\u6587\u7ae060\u4f59\u7bc7\uff1b\u5728\u836f\u7269\u5408\u6210\u65b9\u9762\u7684\u4e13\u5229\u6388\u6743\u8d85\u8fc710\u9879\u3002\u7f57\u5fb7\u5e73\u6559\u6388\u8fd8\u53d7\u9080\u62c5\u4efbThe Journal of Organic Chemistry\u3001Asian Journal Organic Chemistry <\/em>\u526f\u4e3b\u7f16\u4ee5\u53ca\u591a\u4e2a\u56fd\u9645\u671f\u520a\u7f16\u59d4\u6216\u987e\u95ee\u3002<\/span><\/p>\n


<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/14779<\/span><\/p>\n


<\/p>\n

\u89e3\u6c9b\u5fe0\u526f\u6559\u6388\u7b80\u4ecb<\/span><\/strong><\/p>\n


<\/p>\n

\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n

\u89e3\u6c9b\u5fe0\uff0c\u526f\u6559\u6388\uff0c2013\u5e74\u6bd5\u4e1a\u4e8e\u5357\u5f00\u5927\u5b66\uff0c\u83b7\u5f97\u6709\u673a\u5316\u5b66\u4e13\u4e1a\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u9ec4\u6709\u6559\u6388\uff1b\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u662f\u6709\u673a\u5c0f\u5206\u5b50\u50ac\u5316\u7684Domino\u53cd\u5e94\uff1b\u540c\u5e74\u8fdb\u5165\u65e5\u672c\u4e1c\u4eac\u5927\u5b66Sh\u016b Kobayashi\u6559\u6388\u8bfe\u9898\u7ec4\u5f00\u5c55\u535a\u58eb\u540e\u7814\u7a76\uff0c\u4ece\u4e8b\u8d85\u5f3a\u78b1\u50ac\u5316\u5242\u5408\u6210\u4ee5\u53ca\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u7814\u7a76\uff1b2014\u5e7411\u6708\u8fdb\u5165\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u5de5\u4f5c\uff1b\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5728Nat. Commun.\u3001Green Chem.\u3001Org. Lett.\u3001Chem. Eur. J.\u3001Adv. Synth. Catal.<\/em>\u7b49\u520a\u7269\u53d1\u8868\u6587\u7ae010\u4f59\u7bc7\uff1b\u76ee\u524d\u7684\u4e3b\u8981\u7814\u7a76\u9886\u57df\u662f\uff1a\uff081\uff09\u7eff\u8272\u6709\u673a\u8f6c\u5316\u53cd\u5e94\u53ca\u5176\u673a\u7406\u7814\u7a76\uff1b\uff082\uff09\u65b0\u578b\u78b1\u571f\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u5176\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u7814\u7a76\uff1b\uff083\uff09\u751f\u7269\u6d3b\u6027\u5206\u5b50\u4e3a\u5bfc\u5411\u7684Domino\u53cd\u5e94\u7684\u7814\u7a76\u3002<\/span><\/p>\n


<\/p>\n

\u79d1\u7814\u601d\u8def\u5206\u6790<\/span><\/strong><\/p>\n


<\/p>\n

Q\uff1a\u8fd9\u9879\u7814\u7a76\u6700\u521d\u662f\u4ec0\u4e48\u76ee\u7684\uff1f\u6216\u8005\u8bf4\u60f3\u6cd5\u662f\u600e\u4e48\u4ea7\u751f\u7684\uff1f<\/span><\/strong><\/p>\n

A\uff1a<\/span><\/strong>\u6211\u4eec\u5728\u4e0a\u4e16\u7eaa\u4e5d\u5341\u5e74\u4ee3\u5bf9\u7eff\u8272\u6c34\u76f8\u53cd\u5e94\u7814\u7a76\u4ea7\u751f\u4e86\u6d53\u539a\u7684\u5174\u8da3\uff0c\u7814\u7a76\u53d1\u73b0\u94df\u5316\u5408\u7269\u662f\u6781\u5176\u6709\u7528\u7684\u3001\u5373\u4f7f\u5728\u6c34\u6eb6\u6db2\u4e2d\u517c\u5bb9\u6027\u4e5f\u5f88\u597d\u7684\u8def\u6613\u65af\u9178\u3002\u6211\u4eec\u4e5f\u7814\u7a76\u5e76\u5b9e\u73b0\u4e86\u6c34\u76f8\u4e2d\u6709\u673a\u94df\u8bd5\u5242\u7684\u5236\u5907\u548c\u5e94\u7528\u3002\u968f\u540e\uff0c\u6211\u4eec\u5f00\u59cb\u63a2\u7d22\u548c\u5229\u7528\u6c34\u76f8\u4e2d\u6709\u673a\u5316\u5b66\u7684\u8f6c\u5316\u65b9\u6cd5\u5bf9\u86cb\u767d\u8fdb\u884c\u9009\u62e9\u6027\u5b98\u80fd\u5316\u3002\u7814\u7a76\u8fc7\u7a0b\u4e2d\u6211\u4eec\u53d1\u73b0\uff0c\u6c34\u76f8\u6eb6\u5242\u548c\u65e0\u91d1\u5c5e\u6761\u4ef6\u5bf9\u4e8e\u86cb\u767d\u56db\u7ea7\u7ed3\u6784\u7684\u4fdd\u6301\u662f\u6781\u5176\u91cd\u8981\u7684\u3002\u56e0\u6b64\uff0c\u6211\u4eec\u4e00\u76f4\u81f4\u529b\u4e8e\u53d1\u5c55\u751f\u7269\u76f8\u5bb9\u6027\u7684\u6c34\u76f8\u6709\u673a\u5316\u5b66\u8f6c\u5316\u3002<\/span><\/p>\n


<\/p>\n

Q\uff1a\u8be5\u7814\u7a76\u6700\u5927\u7684\u4eae\u70b9\u5728\u54ea\u91cc\uff1f<\/span><\/strong><\/p>\n

A\uff1a<\/span><\/strong>\u8be5\u53cd\u5e94\u5728\u751f\u7269\u517c\u5bb9\u6027\u7684\u6761\u4ef6\uff08\u6c34\/\u4e59\u9187\u6eb6\u5242\u4f53\u7cfb\u3001\u5ba4\u6e29\u3001\u5e38\u538b\u3001pH=7\uff09\u4e0b\u8fdb\u884c\uff0c\u539f\u5b50\u7ecf\u6d4e\u6027\u9ad8\u3001\u6536\u7387\u9ad8\uff0c\u6c34\u662f\u4ec5\u6709\u7684\u526f\u4ea7\u7269\u3002\u5927\u591a\u6570\u60c5\u51b5\u4e0b\u4ea7\u7269\u70ef\u4e19\u57fa\u781c\u53ef\u4ee5\u76f4\u63a5\u4ee5\u56fa\u4f53\u5f62\u5f0f\u6790\u51fa\uff0c\u56e0\u6b64\u53ef\u4ee5\u901a\u8fc7\u7b80\u4fbf\u8fc7\u6ee4\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff0c\u907f\u514d\u4e86\u8403\u53d6\u548c\u67f1\u5c42\u6790\u7b49\u64cd\u4f5c\u3002\u9664\u4e86\u53cd\u5e94\u7eff\u8272\u73af\u4fdd\u4e4b\u5916\uff0c\u8be5\u53cd\u5e94\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u597d\uff0c\u6e29\u548c\u6761\u4ef6\u4e0b\u534a\u80f1\u6c28\u9178\u4e9a\u78fa\u9178\u3001\u4e9a\u725b\u78fa\u9178\u90fd\u80fd\u5f88\u597d\u5730\u53c2\u4e0e\u53cd\u5e94\u5f97\u5230\u76f8\u5e94\u7684\u70ef\u4e19\u57fa\u781c\u5316\u5408\u7269\uff0c\u56e0\u6b64\u8be5\u53cd\u5e94\u5bf9\u4e8e\u540e\u7eed\u590d\u6742\u4e9a\u78fa\u9178\u7684\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\u3002\u6211\u4eec\u901a\u8fc7DFT\u5bf9\u8be5\u53cd\u5e94\u7684\u673a\u7406\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u6c34\u7684\u5b58\u5728\u5bf9\u4e8e\u5206\u5b50\u5185\u6c22\u952e\uff0c\u7279\u522b\u662f\u6865\u73af\u8fc7\u6e21\u6001\u7684\u5f62\u6210\u8d77\u5230\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/span><\/p>\n


<\/p>\n

Q\uff1a\u8be5\u7814\u7a76\u6210\u679c\u53ef\u80fd\u6709\u54ea\u4e9b\u91cd\u8981\u7684\u5e94\u7528\uff1f\u63a5\u4e0b\u6765\u4f60\u4eec\u4f1a\u4ece\u54ea\u4e9b\u65b9\u9762\u7ee7\u7eed\u7814\u7a76\uff1f<\/span><\/strong><\/p>\n

A\uff1a<\/span><\/strong>\u5728\u8be5\u7814\u7a76\u4e2d\uff0c\u6c34\u4e0d\u4ec5\u4ec5\u88ab\u5f53\u4f5c\u4e00\u79cd\u7eff\u8272\u7684\u6eb6\u5242\u4f7f\u7528\uff0c\u5bf9\u4e8e\u53cd\u5e94\u7684\u8fdb\u884c\u8d77\u5230\u91cd\u8981\u7684\u4fc3\u8fdb\u4f5c\u7528\u3002\u56e0\u6b64\uff0c\u6211\u4eec\u76f8\u4fe1\u8be5\u7814\u7a76\u5bf9\u4e8e\u540e\u7eed\u6c34\u4fc3\u8fdb\u7684\u6709\u673a\u5316\u5b66\u53cd\u5e94\u7684\u7814\u7a76\u5177\u6709\u6f5c\u5728\u7684\u542f\u53d1\u610f\u4e49\u3002\u5728\u6b64\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u6211\u4eec\u5c06\u7ee7\u7eed\u7814\u7a76\u8be5\u7c7b\u53cd\u5e94\u5728\u751f\u7269\u5076\u8054\u4e2d\u7684\u5e94\u7528\u4ee5\u53ca\u534a\u80f1\u6c28\u9178\u7684\u4ee3\u8c22\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u6211\u4eec\u4f1a\u7ee7\u7eed\u7814\u7a76\u751f\u7269\u517c\u5bb9\u6027\u6761\u4ef6\u4e0b\u6c34\u4fc3\u8fdb\u7684\u5176\u5b83\u78b3-\u78b3\u3001\u78b3-\u6742\u539f\u5b50\u6210\u952e\u53cd\u5e94\u3002<\/span><\/p>\n


<\/p>\n

\n
\n
\n
\n

\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n


<\/p>\n

\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n

\n
\n
\n
\n
<\/section>\n
<\/section>\n
<\/section>\n<\/section>\n
\n
\n
\n
\n

\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n


<\/p>\n

\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n

\n

\n<\/section>\n<\/section>\n

\n
<\/section>\n
<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\n
\n
\n
\n
\n
\n
\n
\n


<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

<\/span>\"\u3010\u6709\u673a\u3011\u6c34\u4fc3\u8fdb\u7684C-S\u6210\u952e\u53cd\u5e94\"<\/p>\n

\n

\u59cb\u53d1\u4e8e\u5fae\u4fe1\u516c\u4f17\u53f7\uff1a X\u4e00MOL\u8d44\u8baf <\/p>\n<\/blockquote>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

\u200d\u200d\u200d \u6ce8\uff1a\u6587\u672b\u6709\u7814\u7a76\u56e2\u961f\u7b80\u4ecb \u53ca\u672c\u6587\u4f5c\u8005\u79d1\u7814\u601d\u8def\u5206\u6790 \u539f\u5b50\u7ecf\u6d4e\u6027\u9ad8\u3001\u65e0\u9700\u91d1\u5c5e\u53c2\u4e0e\u3001\u4ee5\u4e2d\u6027\u6c34\u6eb6\u6db2\u4f5c\u4e3a […]<\/p>\n","protected":false},"author":1,"featured_media":28558,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28557"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=28557"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28557\/revisions"}],"predecessor-version":[{"id":28572,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28557\/revisions\/28572"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/28558"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=28557"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=28557"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=28557"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}