{"id":28828,"date":"2018-08-02T01:00:00","date_gmt":"2018-08-09T03:57:40","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/08\/09\/nat-chem-%ef%bc%9a%e7%8e%af%e9%87%91%e5%b1%9e%e9%92%8c%e5%82%ac%e5%8c%96%e5%89%82%e5%8f%82%e4%b8%8e%e8%8d%af%e7%89%a9%e5%88%86%e5%ad%90%e7%9a%84%e5%90%8e%e6%9c%9f%e8%8a%b3%e5%9f%ba%e5%8c%96\/"},"modified":"2018-08-09T11:57:44","modified_gmt":"2018-08-09T03:57:44","slug":"nat-chem-%ef%bc%9a%e7%8e%af%e9%87%91%e5%b1%9e%e9%92%8c%e5%82%ac%e5%8c%96%e5%89%82%e5%8f%82%e4%b8%8e%e8%8d%af%e7%89%a9%e5%88%86%e5%ad%90%e7%9a%84%e5%90%8e%e6%9c%9f%e8%8a%b3%e5%9f%ba%e5%8c%96","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/28828\/","title":{"rendered":"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;\"><span style=\"line-height: 0px;\">\u200d\u200d<\/span><span style=\"font-size: 18.018px;line-height: 0px;\">\u200d<a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"      src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress9-1533787061.gif\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/span><\/a><\/span><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657574730&amp;idx=1&amp;sn=7001a26433acb77dcdd5629f27cd8b20&amp;chksm=80f7769ab780ff8cedab5baefd9bc7a02dd18b2191cd29afb2d190e8ea149564133c9437e7d5&amp;scene=21#wechat_redirect\" target=\"_blank\"><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4ee5\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u6784\u5efa\u8054\u82ef\u7ed3\u6784\u5df2\u7ecf\u6210\u4e3a\u836f\u7269\u8bbe\u8ba1\u7684\u4e3b\u8981\u65b9\u6cd5\u3002\u82b3\u9999\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5728\u86cb\u767d\u8d28-\u914d\u4f53\u8bc6\u522b\u4e2d\u5177\u6709\u5173\u952e\u7684\u4f5c\u7528\uff0c\u5728\u5019\u9009\u836f\u7269\u4e2d\u5f15\u5165\u82b3\u57fa\u7ed3\u6784\u5355\u5143\u53ef\u80fd\u4f1a\u5f97\u5230\u5177\u6709\u8f83\u9ad8\u6d3b\u6027\u7684\u884d\u751f\u7269\u3002\u56e0\u6b64\uff0c\u5bfb\u627e\u9ad8\u6548\u7684\u65b9\u6cd5\u5b9e\u73b0\u540e\u671fC-H\u952e\u82b3\u57fa\u5316\u5728\u836f\u7269\u53d1\u73b0\u548c\u5f00\u53d1\u4e2d\u975e\u5e38\u9700\u8981\u3002\u7edd\u5927\u591a\u6570\u836f\u7269\u90fd\u542b\u6709\u51e0\u79cd\u6781\u6027\u5b98\u80fd\u56e2\uff0c\u901a\u5e38\u662f\u6c27\u3001\u6c2e\u548c\u786b\u6742\u73af\u7c7b\u7ed3\u6784\uff0c\u7136\u800c\u6781\u6027\u57fa\u56e2\u5728C-H\u952e\u6d3b\u5316\u4e2d\u7ecf\u5e38\u4e0d\u517c\u5bb9\uff0cLewis\u78b1\u6027\u7684\u6742\u539f\u5b50\u4f1a\u4fc3\u4f7f\u50ac\u5316\u5242\u4e2d\u6bd2\u6216\u5e95\u7269\u5206\u89e3\u3002\u6b64\u5916\uff0c\u5728\u5bfc\u5411\u57fa\u56e2\u53c2\u4e0e\u7684C-H\u952e\u6d3b\u5316\u53cd\u5e94\u4e2d\uff0c\u5f3a\u914d\u4f4d\u57fa\u56e2\u8fdb\u4e00\u6b65\u4e3a\u53cd\u5e94\u7684\u53d1\u751f\u5e26\u6765\u6311\u6218\u3002\u8fd1\u671f\uff0c<strong>\u82f1\u56fd\u66fc\u5f7b\u65af\u7279\u5927\u5b66\u5316\u5b66\u7cfb<\/strong>\u7684<strong>Igor Larrosa<\/strong>\u8bfe\u9898\u7ec4\u5728<\/span><span style=\"font-size: 16px;\"><em><strong>Nature Chemistry<\/strong><\/em><\/span><span style=\"font-size: 18px;\"> \u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u4ed6\u4eec\u62a5\u9053\u7684<strong>\u73af\u72b6\u948c\u50ac\u5316\u5242\u53ef\u4ee5\u9ad8\u6548\u5b9e\u73b0\u9ad8\u5ea6\u5b98\u80fd\u5316\u7684\u5e95\u7269\uff08\u5982\u590d\u6742\u7684\u836f\u7269\u5206\u5b50\uff09\u7684\u540e\u671f\u82b3\u57fa\u5316<\/strong>\u3002\u8fd9\u7c7b\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u53d1\u5c55\u5f97\u76ca\u4e8eRu(\u2161)\u50ac\u5316<em>N<\/em>-\u87af\u5408\u5e95\u7269\u4e0e\u82b3\u57fa\u5364\u5316\u7269\u6216\u62df\u5364\u5316\u7269C-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u673a\u7406\u7684\u6df1\u5165\u7814\u7a76\u3002\u4ee5\u5f80\u7684\u7814\u7a76\u63d0\u51fa\u8be5\u53cd\u5e94\u901a\u8fc7\u4ee5\u4e0b\u50ac\u5316\u5faa\u73af\u8fdb\u884c\uff1aC-H\u952e\u6d3b\u5316\u5f62\u6210\u73af\u72b6\u948c\u7269\u79cd<strong>I<\/strong>\uff0c<strong>I<\/strong>\u4e0e\u82b3\u57fa\u5364\u4ee3\u7269\u53d1\u751f\u6c27\u5316\u52a0\u6210\u5f62\u6210Ru(IV)\u4e2d\u95f4\u4f53<strong>II<\/strong>\uff0c\u8fd8\u539f\u6d88\u9664\u540e\u5f97\u5230\u4e8c\u82b3\u57fa\u4ea7\u7269\u3002\u4f5c\u8005\u63a8\u6d4b\u8fd9\u79cd\u8fc7\u5ea6\u7b80\u5316\u7684\u673a\u7406\u53ef\u80fd\u963b\u788d\u4e86\u4eba\u4eec\u53d1\u73b0\u771f\u6b63\u7684\u50ac\u5316\u6d3b\u6027\u7269\u79cd\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress4-1533787061.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe1. Ru(II)\u50ac\u5316\u5bfc\u5411\u57fa\u56e2\u53c2\u4e0e\u7684\u82b3\u9999\u70c3\u548c\u82b3\u57fa\u5364\u5316\u7269\u6216\u8005\u62df\u5364\u5316\u7269\u7684\u82b3\u57fa\u5316\u53cd\u5e94\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4e0e\u4ee5\u524d\u7684\u5047\u8bbe\u76f8\u53cd\uff0c\u4f5c\u8005\u53d1\u73b0\u5728\u6c27\u5316\u52a0\u6210\u4e4b\u524d\uff0c\u53cd\u5e94\u9700\u8981\u7b2c\u4e8c\u4e2aC-H\u952e\u6d3b\u5316\u7684\u8fc7\u7a0b\u4ee5\u5f62\u6210\u53cc\u73af\u91d1\u5c5e\u5316\u7684Ru(II)\u914d\u5408\u7269<strong>\u2162<\/strong>\uff0c\u4ece\u800c\u5bfc\u81f4Ru(IV)\u7269\u79cd<strong>IV<\/strong>\u751f\u6210\uff08\u56fe1c\uff09\u3002\u73af\u72b6\u948c\u914d\u5408\u7269<strong>I<\/strong>\uff08\u56fe1d\uff0cRuB\uff09\u80fd\u5728\u975e\u5e38\u4f4e\u7684\u6e29\u5ea6\u4e0b\u50ac\u5316C-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u3002\u6700\u8fd1\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u7b2c\u4e00\u4f8bRu(II)\u50ac\u5316\u201c\u7b80\u5355\u201d\u7f3a\u7535\u5b50\u82b3\u9999\u70c3C-H\u952e\u82b3\u57fa\u5316\u7684\u65b9\u6cd5\u3002\u4f5c\u8005\u53d1\u73b0\uff0c\u4e0e\u5148\u524d\u7684\u5047\u8bbe\u76f8\u53cd\uff0c\u948c\u50ac\u5316\u5242\u4e2d\u5b58\u5728\u7684\u5bf9\u4f1e\u82b1\u70c3\u914d\u4f53\uff08\u56fe1a\uff0cRuA\uff09\u5bf9\u53cd\u5e94\u5177\u6709\u6291\u5236\u4f5c\u7528\uff0c\u4e8e\u662f\u5bf9Ru(II)\u50ac\u5316C-H\u952e\u82b3\u57fa\u5316\u7684\u673a\u7406\u8fdb\u884c\u66f4\u6df1\u5165\u7684\u7814\u7a76\u3002\u4ed6\u4eec\u63a2\u7a76\u4e862-\uff08\u90bb\u7532\u82ef\u57fa\uff09\u5421\u5576\uff08<strong>1<\/strong>\uff09\u4e0e5-\u7898-\u95f4\u4e8c\u7532\u82ef\uff08<strong>2<\/strong>\uff09\u7684\u82b3\u57fa\u5316\u8fc7\u7a0b\uff08\u56fe2\uff09\uff0c\u5bf9\u4e24\u79cd\u50ac\u5316\u4e2d\u95f4\u4f53<strong>Ru1<\/strong>\u548c<strong>Ru2<\/strong>\u4e0e\u5316\u5b66\u8ba1\u91cf\u7684\u7898\u4ee3\u82b3\u9999\u70c3<strong>2<\/strong>\u7684\u53cd\u5e94\u6027\u8fdb\u884c\u8003\u5bdf\u3002<strong>Ru1<\/strong>\u548c<strong>Ru2<\/strong>\u4e0e<strong>2<\/strong>\u53cd\u5e94\u5747\u8f83\u6162\uff0c\u8868\u660e\u8be5\u53cd\u5e94\u5b58\u5728\u6bd4\u56fe1b\u66f4\u590d\u6742\u7684\u673a\u7406\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u65e0\u03b7<\/span><span style=\"font-size: 14px;\"><sup>6<\/sup><\/span><span style=\"font-size: 18px;\">-\u82b3\u9999\u70c3\u7684\u73af\u72b6\u948c\u7269\u79cd\u5982<strong>Ru2<\/strong>\u548c<strong>1<\/strong>\u4e4b\u95f4\u7684C-H\u952e\u6d3b\u5316\u5fc5\u987b\u53d1\u751f\u5728\u4e0e\u7898\u4ee3\u82b3\u9999\u70c3<strong>2<\/strong>\u53d1\u751f\u53cd\u5e94\u4e4b\u524d\u3002\u53cd\u5e94\u6dfb\u52a00.2\u5f53\u91cf\u7684<strong>1<\/strong>\u540e\uff0c\u4ed6\u4eec\u5f00\u59cb\u76d1\u6d4b<strong>Ru1<\/strong>\u548c<strong>Ru2<\/strong>\u53c2\u4e0e\u82b3\u57fa\u5316\u53cd\u5e94\u7684\u6d53\u5ea6\u53d8\u5316\u60c5\u51b5\uff0c\u89c2\u5bdf\u5230<strong>1<\/strong>\u53d1\u751f\u5feb\u901f\u6d88\u8017\uff0c\u82b3\u57fa\u5316\u901f\u7387\u663e\u8457\u63d0\u9ad8\u3002\u6b64\u5916\uff0c\u53cd\u5e94\u5728\u4e0d\u52a0\u5165\u78b1KOAc\u65f6\uff0cC-H\u952e\u6d3b\u5316\u82b3\u57fa\u5316\u7684\u901f\u7387\u5927\u5927\u964d\u4f4e\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress6-1533787061.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe2. \u948c\u6742\u53cc\u73af\u4e2d\u95f4\u4f53\u53c2\u4e0eC-H\u952e\u6d3b\u5316\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u5b9e\u9a8c\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4e3a\u4e86\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u8fd9\u4e2a\u673a\u7406\uff0c\u4f5c\u8005\u901a\u8fc7<\/span><span style=\"font-size: 14px;\"><sup>1<\/sup><\/span><span style=\"font-size: 18px;\">H NMR\u548c<\/span><span style=\"font-size: 14px;\"><sup>19<\/sup><\/span><span style=\"font-size: 18px;\">F&nbsp;<span style=\"text-align: justify;font-size: 18px;\"><\/span> NMR\u8ddf\u8e2a\u4e86\u91d1\u5c5e\u73af\u72b6\u914d\u5408\u7269<strong>Ru3<\/strong>\u4e0e2-\u82b3\u57fa\u5421\u5576<strong>5<\/strong>\u7684\u53cd\u5e94\u3002\u5ba4\u6e29\u4e0b<strong>Ru3<\/strong>\u7684\u4e59\u8148\u914d\u4f53\u548cNMP\u4e4b\u95f4\u53d1\u751f\u5feb\u901f\u914d\u4f53\u4ea4\u6362\u5f62\u6210<strong>Ru4<\/strong>\uff08\u56fe3\uff0ci-iii\uff09\u3002\u572880 \u2103\u7684\u6761\u4ef6\u4e0b\u53cd\u5e94180\u5206\u949f\uff0c<strong>Ru3<\/strong>\/<strong>Ru4<\/strong>\u4e0e<strong>5<\/strong>\u5b9a\u91cf\u53cd\u5e94\u5f62\u6210\u9884\u671f\u7684\u91d1\u5c5eRu(II)\u53cc\u73af\u7269\u79cd<strong>Ru5<\/strong>\uff0c\u5176\u7ed3\u6784\u901a\u8fc7X\u5c04\u7ebf\u884d\u5c04\u5206\u6790\u8bc1\u5b9e\u3002\u968f\u540e\u4ed6\uff0c\u4e8c\u8302\u52a0\u5165\u7898\u4ee3\u82b3\u9999\u70c3<strong>2<\/strong>\uff0c\u5e76\u572825 \u2103\u4e0b\u76d1\u6d4b\u53cd\u5e94\uff08\u56fe3\uff0c\u6d45\u9ec4\u8272\u9634\u5f71\uff09\u3002600\u5206\u949f\u540e\uff0c<strong>Ru5<\/strong>\u4e0e<strong>2<\/strong>\u5b9a\u91cf\u53cd\u5e94\u5f62\u6210\u82b3\u57fa\u5316\u4ea7\u7269<strong>6<\/strong>\u4ee5\u53ca\u8fd8\u539f\u6d88\u9664\u7684\u73af\u91d1\u5c5e\u914d\u5408\u7269<strong>Ru6<\/strong>\u548c<strong>Ru4<\/strong>\u3002\u5b9e\u9a8c\u6570\u636e\u4e0e\u4f5c\u8005\u7684\u5047\u8bbe\u5b8c\u5168\u4e00\u81f4\uff0c\u5e76\u63d0\u4f9b\u4e86\u5f3a\u6709\u529b\u7684\u8bc1\u636e\uff0c\u8bc1\u660e\u56fe1c\u4e2d\u62a5\u9053\u7684\u50ac\u5316\u5faa\u73af\u786e\u5b9e\u5b58\u5728\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress7-1533787062.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe3. \u948c\u6742\u53cc\u73af\u914d\u5408\u7269<strong>Ru5<\/strong>\u7684\u68c0\u6d4b\u3001\u5206\u79bb\u548c\u53cd\u5e94\u6d3b\u6027\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u8fd8\u5c06<strong>Ru2<\/strong>\u548cKOAc\u7ec4\u5408\u50ac\u5316\u7684\u53cd\u5e94\u901f\u7387\u4e0e<strong>Ru7<\/strong>\u548c<strong>Ru8<\/strong>\u8fdb\u884c\u6bd4\u8f83\uff0c<strong>Ru7<\/strong>\u548c<strong>Ru8<\/strong>\u662f\u5e94\u7528\u6700\u5e7f\u6cdb\u7684\u948c\u50ac\u5316\u5242\uff08\u56fe4a\uff09\u3002\u968f\u7740\u65f6\u95f4\u7684\u63a8\u79fb\uff0c\u4f5c\u8005\u63a2\u7a76\u4e8635 \u00b0C\u4e0b2-\u82ef\u57fa\u5421\u5576\uff08<strong>7<\/strong>\uff09\u4e0e5-\u7898-\u95f4\u4e8c\u7532\u82ef\uff08<strong>2<\/strong>\uff09\u7684C-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u3002\u5c3d\u7ba1\u4f7f\u7528\u73af\u91d1\u5c5e\u5316\u7684<strong>Ru2<\/strong>\u50ac\u5316\u5242\u5728420\u5206\u949f\u5185\u5355\u82b3\u57fa\uff08<strong>8<\/strong>\uff09\u548c\u4e8c\u82b3\u57fa\u914d\u5408\u7269\uff08<strong>9<\/strong>\uff09\u7684\u603b\u6536\u7387\u8fbe\u523089%\uff0c\u4f46<strong>Ru7<\/strong>\u548c<strong>Ru8<\/strong>\u57fa\u672c\u5904\u4e8e\u4f11\u7720\u72b6\u6001\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u57fa\u4e8e\u50ac\u5316\u5faa\u73af\u4e2d\u95f4\u4f53\u7684\u50ac\u5316\u5242\uff0c\u5982<strong>I<\/strong>\u6bd4\u901a\u5e38\u4f7f\u7528\u7684Ru(\u2161)\u7269\u79cd\u5177\u6709\u66f4\u597d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u53cd\u5e94\u80fd\u5728\u4f4e\u6e29\u4e0b\u53d1\u751f\u3002\u4f5c\u8005\u8fd8\u5c1d\u8bd5\u4e86\u4e0d\u540c\u6c2e\u914d\u4f53\u73af\u5316\u914d\u5408\u7269\u7684\u50ac\u5316\u6d3b\u6027\uff0c<em>N,N<\/em>-\u4e8c\u7532\u57fa\u82c4\u80fa\u7684<strong>Ru9<\/strong>\u4ee596%\u7684\u6536\u7387\u50ac\u5316\u53cd\u5e94\u5f62\u6210\u4e8c\u82b3\u57fa\u914d\u5408\u7269<strong>9<\/strong>\uff0c\u5e76\u6291\u5236\u4e86\u50ac\u5316\u5242\u82b3\u57fa\u5316\u540e\u964d\u89e3\u7684\u53d1\u751f\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress7-1533787062-1.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe4. \u73af\u72b6\u948c\u914d\u5408\u7269\u662f\u5bfc\u5411\u57fa\u56e2\u53c2\u4e0e\u82b3\u9999\u70c3\u4e0e\u82b3\u57fa\u5364\u5316\u7269C-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u4e2d\u4f18\u5f02\u7684\u50ac\u5316\u5242\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u8fd8\u5bf9\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u63a2\u7a76\uff0c\u4ee5\u5e26\u6709\u82b3\u57fa\u6c2f\u3001\u6eb4\u3001\u7898\u5316\u7269\u6216\u5c06\u5176\u8f6c\u5316\u4e3a\u4e09\u6c1f\u7532\u78fa\u9178\u916f\u884d\u751f\u7269\u7684\u5929\u7136\u4ea7\u7269\u548c\u836f\u7269\u4f5c\u4e3a\u5e95\u7269\uff08<strong>X1-X34<\/strong>\uff09\u53c2\u4e0eC-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\uff08\u56fe5\uff09\u3002\u8be5\u53cd\u5e94\u5177\u6709\u975e\u5e38\u597d\u7684\u5e95\u7269\u9002\u7528\u6027\uff0c\u8bb8\u591a\u5728\u836f\u7269\u4e2d\u5e7f\u6cdb\u5b58\u5728\u7684\u82b3\u9999\u6742\u73af\u548c\u5b98\u80fd\u56e2\u5bf9\u53cd\u5e94\u90fd\u5177\u6709\u5f88\u597d\u7684\u517c\u5bb9\u6027\uff0c\u5e76\u53d6\u5f97\u4e86\u826f\u597d\u5230\u4f18\u79c0\u7684\u4ea7\u7387\u3002\u8be5\u53cd\u5e94\u8fd8\u53ef\u4ee5\u572810 g\u91cf\u7ea7\u89c4\u6a21\u4e0b\u5b9e\u73b0\u6c2f\u4e19\u54aa\u55ea<strong>X12<\/strong>\u53c2\u4e0e\u7684\u53cd\u5e94\uff0c\u50ac\u5316\u5242\u7684\u7528\u91cf\u80fd\u964d\u4f4e\u52303 mol%\uff0c\u7ecf\u8fc7\u7b80\u5355\u7684\u6c34\u5904\u7406\uff0c\u5c31\u80fd\u4ee595%\u7684\u6536\u7387\u5f97\u5230\u76f8\u5e94\u7684\u4ea7\u7269<strong>A12<\/strong>\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u51f8\u663e\u8be5\u65b9\u6cd5\u7684\u666e\u9002\u6027\uff0c\u4f5c\u8005\u8fd8\u5c1d\u8bd5\u4e86\u6eb4\u4ee3\u91d1\u521a\u70f7\u548c\u836f\u7269\u62c9\u8fbe\u65af\u987f<strong>X22<\/strong>\u7684\u5076\u8054\u53cd\u5e94\uff0c\u4e5f\u80fd\u4ee594%\u7684\u6536\u7387\u5f97\u5230\u76f8\u5e94\u7684\u4ea7\u7269\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress8-1533787062.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress2-1533787062.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe5. C-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u5e95\u7269\u9002\u7528\u8303\u56f4\u7684\u8003\u5bdf\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u8fdb\u4e00\u6b65\u5c1d\u8bd5\u542b\u6709\u5bfc\u5411\u57fa\u56e2\u7684\u5e95\u7269\u53c2\u4e0e\u5076\u8054\u53cd\u5e94\u7684\u9002\u7528\u6027\u60c5\u51b5\u3002\u4e3a\u6b64\uff0c\u4ed6\u4eec\u63a2\u7a76\u4e862-\u82ef\u57fa\u5421\u5576\u884d\u751f\u7269\u963f\u624e\u90a3\u97e6\uff08<strong>N1<\/strong>\uff09\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u8fd9\u662f\u4e00\u79cd\u4eba\u7c7b\u514d\u75ab\u7f3a\u9677\u75c5\u6bd2-1\uff08HIV-1\uff09\u7684\u6291\u5236\u5242\uff0c\u53cd\u5e94\u4e5f\u80fd\u4ee580%\u7684\u4ea7\u7387\u5f97\u5230\u4ea7\u7269<strong>B1<\/strong>\u3002\u5176\u5b83\u542b\u6709sp<\/span><span style=\"font-size: 14px;\"><sup>2<\/sup><\/span><span style=\"font-size: 18px;\">\u6742\u5316\u6c2e\u5bfc\u5411\u57fa\u56e2\u7684\u82b3\u9999\u6742\u73af\u5316\u5408\u7269\u4e5f\u90fd\u53d6\u5f97\u4e86\u826f\u597d\u81f3\u4f18\u79c0\u7684\u6536\u7387\u3002\u4f5c\u8005\u8fd8\u5b9e\u73b0\u4e86\u4e24\u79cd\u9ad8\u5ea6\u5b98\u80fd\u5316\u836f\u7269\u4e4b\u95f4\u7684\u5076\u8054\uff08\u56fe6b\uff09\u3002\u963f\u624e\u90a3\u97e6\uff08<strong>N1<\/strong>\uff09\u3001\u5511\u5421\u5766\uff08<strong>N3<\/strong>\uff09\u3001\u6c1f\u897f\u6cee\uff08<strong>N5<\/strong>\uff09\u548c\u78fa\u80fa\u82ef\u54d2\u5511\uff08<strong>N8<\/strong>\uff09\u5206\u522b\u4e0e\u66f2\u7f8e\u66ff\u5c3c\uff08<strong>X23<\/strong>\uff09\u3001\u6c2f\u6c2e\u5e73\uff08<strong>X13<\/strong>\uff09\u3001\u7f9f\u7532\u9999\u8c46\u7d20\u884d\u751f\u7269\uff08<strong>X28<\/strong>\uff09\u548c\u6eb4\u4ee3\u58eb\u7684\u5b81\uff08<strong>X20<\/strong>\uff09\u53cd\u5e94\uff0c\u90fd\u80fd\u4ee5\u6781\u597d\u7684\u4ea7\u7387\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u3002\u800c\u5f53\u4ee5Ru(II)\u50ac\u5316\u5242\u7531<strong>Ru9<\/strong>\u66f4\u6362\u4e3a<strong>Ru7<\/strong>\u548c<strong>Ru8<\/strong>\u53c2\u4e0e\u53cd\u5e94\u65f6\uff0c\u90fd\u4e0d\u80fd\u4ee5\u7406\u60f3\u7684\u4ea7\u7387\u5408\u6210\u76ee\u6807\u4ea7\u7269\uff08\u56fe6b\uff0c\u53f3\u4e0b\uff09\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress8-1533787063.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress7-1533787063.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe6. C-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u5e95\u7269\u9002\u7528\u8303\u56f4\u7684\u8fdb\u4e00\u6b65\u8003\u5bdf\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: center;line-height: 1.75em;\"><span style=\"color: rgb(33, 127, 188);\"><strong><span style=\"font-size: 18px;\">\u603b\u7ed3<\/span><\/strong><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">Igor Larrosa\u6559\u6388\u62a5\u9053\u4e86<em>N<\/em>-\u87af\u5408\u7684\u5e95\u7269\u4e0e\u82b3\u57fa\u5364\u5316\u7269\u6216\u62df\u5364\u5316\u7269\u7684C-H\u952e\u82b3\u57fa\u5316\u8fc7\u7a0b\u4e2dRu(\u2161)\u7269\u79cd\u53d1\u751f\u6c27\u5316\u52a0\u6210\u7684\u4fc3\u8fdb\u56e0\u7d20\uff0c\u786e\u5b9a\u4e86\u948c\u6742\u53cc\u73af\u7269\u79cd\u662f\u6c27\u5316\u52a0\u6210\u6b65\u9aa4\u53d1\u751f\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u3002\u57fa\u4e8e\u8fd9\u4e00\u8ba4\u8bc6\uff0c\u4ed6\u4eec\u8bbe\u8ba1\u4e86\u4e00\u4e2a\u66f4\u9ad8\u6548\u7684\u50ac\u5316\u4f53\u7cfb\uff0c\u80fd\u591f\u5b9e\u73b0\u5bf9\u590d\u6742\u5b98\u80fd\u5316\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\uff0c\u5e76\u53ef\u517c\u5bb9\u5e38\u89c4C-H\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u4e0d\u517c\u5bb9\u7684\u5b98\u80fd\u56e2\u3002\u8be5\u53cd\u5e94\u5e95\u7269\u9002\u7528\u6027\u975e\u5e38\u5e7f\u6cdb\uff0c\u6709\u671b\u6210\u4e3a\u836f\u7269\u53d1\u73b0\u548c\u5f00\u53d1\u7684\u6709\u529b\u5de5\u5177\u3002\u53e6\u5916\uff0c\u4f5c\u8005\u8fd8\u5c06\u6839\u636e\u63d0\u51fa\u7684\u673a\u7406\u8fdb\u4e00\u6b65\u5c06\u8be5\u50ac\u5316\u4f53\u7cfb\u63a8\u5e7f\u5230\u5176\u5b83\u7c7b\u578b\u5e95\u7269\u7684C-H\u952e\u6d3b\u5316\uff0c\u4ece\u800c\u53d1\u73b0\u66f4\u591a\u6709\u4ef7\u503c\u7684\u5316\u5b66\u8f6c\u5316\u3002<\/span><\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09<\/span><\/p>\n<p><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress7-1533787063-1.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Cyclometallated ruthenium catalyst enables late-stage directed arylation of pharmaceuticals<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">Nat. Chem<\/span><\/em><span style=\"font-size: 14px;\">., <strong>2018<\/strong>, <em>10<\/em>, 724, DOI: 10.1038\/s41557-018-0062-3<\/span><\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n<p><span style=\"font-size: 14px;\">Igor Larrosa<\/span><\/p>\n<p><span style=\"font-size: 14px;\">http:\/\/www.x-mol.com\/university\/faculty\/2420<\/span><\/p>\n<p><span style=\"font-size: 14px;\">\u8bfe\u9898\u7ec4\u94fe\u63a5<\/span><\/p>\n<p><span style=\"font-size: 14px;\">https:\/\/personalpages.manchester.ac.uk\/staff\/igor.larrosa\/index.html<\/span><\/p>\n<p><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress4-1533787063.jpeg\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress7-1533787063.png\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"display: inline-block;color: transparent;clear: both;box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;word-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n<p style=\"box-sizing: border-box;\"><br style=\"box-sizing: border-box;\"  \/><\/p>\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\"><span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">\u957f\u6309<\/strong><\/span>\u4e0b\u56fe<strong style=\"box-sizing: border-box;\">\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<p style=\"margin-top: 10px;margin-bottom: 10px;text-align: center;box-sizing: border-box;\">\n<\/section>\n<\/section>\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-bottom: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-bottom: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section style=\"white-space: normal;\">\n<section >\n<section>\n<section>\n<section>\n<section >\n<section>\n<section>\n<p style=\"text-align: center;\"><br  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;word-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 18px;box-sizing: border-box !important;word-wrap: break-word !important;\">\u70b9\u51fb\u201c<span style=\"max-width: 100%;color: rgb(0, 122, 170);\">\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b&nbsp;<strong>\u5316\u5b66 \u2022 \u6750\u6599&nbsp;<\/strong>\u9886\u57df<span style=\"max-width: 100%;background-color: rgb(255, 218, 81);\">\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;word-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 14px;box-sizing: border-box !important;word-wrap: break-word !important;\"><\/span><img     style=\"color: rgb(0, 0, 0);font-size: 14px;line-height: 25.6px;box-sizing: border-box !important;word-wrap: break-word !important;width: auto !important;visibility: visible !important;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/08\/beepress7-1533787063.gif\" alt=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\" title=\"Nat. Chem.\uff1a\u73af\u91d1\u5c5e\u948c\u50ac\u5316\u5242\u53c2\u4e0e\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u82b3\u57fa\u5316\"  \/><\/p>\n<blockquote class='keep-source'>\n<p>\u59cb\u53d1\u4e8e\u5fae\u4fe1\u516c\u4f17\u53f7\uff1a                         X\u4e00MOL\u8d44\u8baf                      <\/p>\n<\/blockquote>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u200d\u200d\u200d \u4ee5\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u6784\u5efa\u8054\u82ef\u7ed3\u6784\u5df2\u7ecf\u6210\u4e3a\u836f\u7269\u8bbe\u8ba1\u7684\u4e3b\u8981\u65b9\u6cd5\u3002\u82b3\u9999\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5728\u86cb\u767d\u8d28-\u914d\u4f53\u8bc6\u522b\u4e2d\u5177\u6709\u5173\u952e\u7684 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":28829,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28828"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=28828"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28828\/revisions"}],"predecessor-version":[{"id":28847,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28828\/revisions\/28847"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/28829"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=28828"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=28828"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=28828"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}