{"id":28902,"date":"2018-08-02T01:00:00","date_gmt":"2018-08-09T03:58:03","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/08\/09\/%e3%80%90%e6%97%a0%e6%9c%ba%e3%80%91%e7%8e%af%e9%87%91%e5%b1%9eiriii%e5%8c%96%e5%90%88%e7%89%a9%e8%a1%a8%e7%8e%b0%e5%87%ba%e8%81%9a%e9%9b%86%e8%af%b1%e5%af%bc%e7%9a%84%e7%94%b5%e5%8c%96%e5%ad%a6\/"},"modified":"2018-08-09T11:58:05","modified_gmt":"2018-08-09T03:58:05","slug":"%e3%80%90%e6%97%a0%e6%9c%ba%e3%80%91%e7%8e%af%e9%87%91%e5%b1%9eiriii%e5%8c%96%e5%90%88%e7%89%a9%e8%a1%a8%e7%8e%b0%e5%87%ba%e8%81%9a%e9%9b%86%e8%af%b1%e5%af%bc%e7%9a%84%e7%94%b5%e5%8c%96%e5%ad%a6","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/28902\/","title":{"rendered":"\u3010\u65e0\u673a\u3011\u73af\u91d1\u5c5eIr(III)\u5316\u5408\u7269\u8868\u73b0\u51fa\u805a\u96c6\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53d1\u5149\u73b0\u8c61"},"content":{"rendered":"
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\u5728[Ir(tpy)(bbbi)]\u7684\u5206\u5b50\u7ed3\u6784\u4e2d\uff0ctpy\u4e0ebbbi<\/span>3-<\/sup><\/span>\u662f\u5e73\u9762\u4e0e\u82b3\u9999\u578b\u914d\u4f53\uff0c\u6709\u5229\u4e8e\u5f62\u6210\u5206\u5b50\u95f4\u7684\u03c0\u2026\u03c0\u5806\u79ef\u3002\u53e6\u5916\uff0c\u5316\u5408\u7269\u4e2d\u672a\u53c2\u4e0e\u914d\u4f4d\u7684\u54aa\u5511\u6c2e\u539f\u5b50\u6709\u5229\u4e8e\u5f62\u6210\u5206\u5b50\u95f4\u7684\u6c22\u952e\u3002<\/span>1<\/sup><\/span>H NMR\u3001TEM\u548cDLS\u7684\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u76f8\u90bb\u7684[Ir(tpy)(bbbi)]\u5206\u5b50\u80fd\u591f\u901a\u8fc7\u03c0\u2026\u03c0<\/span>\u5806\u79ef\u548c\u6c22\u952e\u4f5c\u7528\u5728DMSO-H<\/span>2<\/sub><\/span>O (10\/90, v\/v)\u4e2d\u8fdb\u884c\u8d85\u5206\u5b50\u7ec4\u88c5\uff0c\u5f62\u6210\u7c92\u5f84\u7ea6\u4e3a120 nm\u7684\u7eb3\u7c73\u7c92\u5b50\u3002\u5728DMSO-H<\/span>2<\/sub><\/span>O\u7684\u6df7\u5408\u7269\u4e2d\uff0c\u968f\u7740\u6c34\u7684\u4f53\u79ef\u5206\u6570\u4ece20%\u589e\u52a0\u523098%\uff0c\u5316\u5408\u7269[Ir(tpy)(bbbi)]\u7684ECL\u5f3a\u5ea6\u9010\u6e10\u589e\u52a0\u5230\u6700\u521d\u768439\u500d\uff0c\u6700\u7ec8\u5f3a\u5ea6\u662f\u76f8\u540c\u5b9e\u9a8c\u6761\u4ef6\u4e0b[Ru(bpy)<\/span>3<\/sub><\/span>]<\/span>2+<\/sup><\/span>\u5f3a\u5ea6\u76844.04\u500d\u3002\u8fd9\u4e00\u7814\u7a76\u7ed3\u679c\u8bc1\u660e\u4e86AI-ECL\u73b0\u8c61\u7684\u5b58\u5728\u3002\u5728\u542b\u6709\u4e0d\u540c\u6d53\u5ea6\u7684\u725b\u8840\u9752\u86cb\u767d\uff08BSA\uff09\u7684DMSO-H<\/span>2<\/sub><\/span>O (2\/98, v\/v)\u6eb6\u6db2\u4e2d\uff0c\u8be5\u56e2\u961f\u8fdb\u4e00\u6b65\u63a2\u7d22\u4e86\u5316\u5408\u7269[Ir(tpy)(bbbi)]\u7684ECL\u5f3a\u5ea6\u53d8\u5316\u3002\u4ed6\u4eec\u53d1\u73b0BSA\u4e0e[Ir(tpy)(bbbi)]\u7eb3\u7c73\u7c92\u5b50\u7684\u952e\u5408\u4f5c\u7528\u51cf\u5c11\u4e86\u94f1\u5316\u5408\u7269\u7684\u5206\u5b50\u632f\u52a8\uff0c\u56e0\u6b64\u589e\u52a0\u4e86\u5316\u5408\u7269\u7684ECL\u5f3a\u5ea6\u3002\u8fd9\u4e9b\u7814\u7a76\u4e0d\u4ec5\u6f84\u6e05\u4e86\u5316\u5408\u7269[Ir(tpy)(bbbi)]\u4e2d\u7684AI-ECL\u73b0\u8c61\uff0c\u800c\u4e14\u4e3aECL\u57fa\u4f20\u611f\u5668\u7684\u8bbe\u8ba1\u63d0\u4f9b\u65b0\u7684\u601d\u8def\uff0c\u5373\u6784\u7b51\u5177\u6709AI-ECL\u884c\u4e3a\u7684\u4f20\u611f\u5668\u3002\u8fd9\u4e00\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728<\/span>Inorganic Chemistry <\/strong><\/em><\/span>\u4e0a\uff0c\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u5357\u4eac\u5927\u5b66\u7684\u7814\u7a76\u751f\u9ad8\u592a\u5b9d<\/strong>\u548c\u5f20\u6676\u6676<\/strong>\u3002<\/span><\/p>\n

\"\u3010\u65e0\u673a\u3011\u73af\u91d1\u5c5eIr(III)\u5316\u5408\u7269\u8868\u73b0\u51fa\u805a\u96c6\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53d1\u5149\u73b0\u8c61\"<\/p>\n

\"\u3010\u65e0\u673a\u3011\u73af\u91d1\u5c5eIr(III)\u5316\u5408\u7269\u8868\u73b0\u51fa\u805a\u96c6\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53d1\u5149\u73b0\u8c61\"<\/p>\n


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\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong>Tai-Bao Gao, Jing-Jing Zhang, Run-Qi Yan, Deng-Ke Cao, Dechen Jiang, Deju Ye <\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"\u3010\u65e0\u673a\u3011\u73af\u91d1\u5c5eIr(III)\u5316\u5408\u7269\u8868\u73b0\u51fa\u805a\u96c6\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53d1\u5149\u73b0\u8c61\"<\/p>\n

Aggregation-Induced Electrochemiluminescence from a Cyclometalated Iridium(III) Complex<\/span><\/p>\n

Inorg. Chem.<\/span><\/em>, 2018<\/strong>, 57<\/em>, 4310, DOI: 10.1021\/acs.inorgchem.7b03093<\/span><\/p>\n


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\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n

\u66f9\u767b\u79d1<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/11505<\/span><\/p>\n

\u6c5f\u5fb7\u81e3<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/11521<\/span><\/p>\n

\u53f6\u5fb7\u4e3e<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/49772<\/span><\/p>\n


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\"\u3010\u65e0\u673a\u3011\u73af\u91d1\u5c5eIr(III)\u5316\u5408\u7269\u8868\u73b0\u51fa\u805a\u96c6\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53d1\u5149\u73b0\u8c61\"<\/p>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n


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\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

<\/span>\"\u3010\u65e0\u673a\u3011\u73af\u91d1\u5c5eIr(III)\u5316\u5408\u7269\u8868\u73b0\u51fa\u805a\u96c6\u8bf1\u5bfc\u7684\u7535\u5316\u5b66\u53d1\u5149\u73b0\u8c61\"<\/p>\n

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\u59cb\u53d1\u4e8e\u5fae\u4fe1\u516c\u4f17\u53f7\uff1a X\u4e00MOL\u8d44\u8baf <\/p>\n<\/blockquote>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

\u200d\u200d\u200d \u5510\u672c\u5fe0\u9662\u58eb\u53ca\u5176\u5408\u4f5c\u8005\u57282001\u5e74\u63d0\u51fa\u4e86\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\uff08AIE\uff09\u7684\u6982\u5ff5\uff0c\u5373\u5316\u5408\u7269\u5728\u5206\u5b50\u9694\u79bb\u7684\u72b6\u6001\u4e0d\u53d1\u5149\u6216\u53d1 […]<\/p>\n","protected":false},"author":1,"featured_media":28903,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28902"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=28902"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28902\/revisions"}],"predecessor-version":[{"id":28915,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/28902\/revisions\/28915"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/28903"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=28902"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=28902"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=28902"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}