{"id":48354,"date":"2018-09-25T01:00:00","date_gmt":"2018-09-26T01:48:36","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/26\/%e6%84%8f%e5%a4%96%e5%ae%9e%e7%8e%b0%e7%9a%84%e6%97%a0%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e6%9d%a1%e4%bb%b6%e4%b8%8b%e5%85%89%e5%89%aa%e6%8e%a5%e5%90%88%e6%88%90\/"},"modified":"2018-09-26T09:48:40","modified_gmt":"2018-09-26T01:48:40","slug":"%e6%84%8f%e5%a4%96%e5%ae%9e%e7%8e%b0%e7%9a%84%e6%97%a0%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e6%9d%a1%e4%bb%b6%e4%b8%8b%e5%85%89%e5%89%aa%e6%8e%a5%e5%90%88%e6%88%90","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/48354\/","title":{"rendered":"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;\"><span style=\"line-height: 0px;\">\u200d\u200d<\/span><span style=\"font-size: 18.018px;line-height: 0px;\">\u200d<a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><\/a><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 558px;top: auto;left: auto;right: auto;bottom: auto;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/1-1537926517.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/span><\/a><\/span><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657574730&amp;idx=1&amp;sn=7001a26433acb77dcdd5629f27cd8b20&amp;chksm=80f7769ab780ff8cedab5baefd9bc7a02dd18b2191cd29afb2d190e8ea149564133c9437e7d5&amp;scene=21#wechat_redirect\" target=\"_blank\"><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u8054\u82b3\u57fa\u7ed3\u6784\u662f\u4e00\u79cd\u91cd\u8981\u7684\u836f\u6548\u57fa\u56e2\uff0c\u80fd\u591f\u7ed3\u5408\u591a\u4e2a\u836f\u7269\u53d7\u4f53\uff0c\u6240\u5f62\u6210\u7684\u5316\u5408\u7269\u5177\u6709\u9ad8\u4eb2\u548c\u529b\u548c\u6d3b\u6027\u3002\u5f88\u591a\u6297\u751f\u7d20\u3001\u6297\u708e\u3001\u6b62\u75db\u548c\u6297\u9ad8\u8840\u538b\u7684\u836f\u7269\u4e2d\u53ef\u4ee5\u53d1\u73b0\u8054\u82b3\u57fa\u7ed3\u6784\uff08\u56fe1A\uff09\uff0c\u57fa\u4e8e\u8054\u82b3\u57fa\u5316\u5408\u7269\u7684\u836f\u7269\u6bcf\u5e74\u9500\u552e\u989d\u9884\u8ba1\u5728300\u4ebf\u7f8e\u5143\u4ee5\u4e0a\u3002\u56e0\u6b64\uff0c\u5373\u4f7f\u5408\u6210\u8fc7\u7a0b\u4e2d\u4e00\u4e9b\u5c0f\u7684\u6539\u8fdb\u4e5f\u80fd\u5e26\u6765\u5de8\u5927\u7684\u7ecf\u6d4e\u6548\u76ca\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/1-1537926517-1.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe1. \u8054\u82b3\u57fa\u5316\u5408\u7269\u7684\u91cd\u8981\u610f\u4e49\u4e0e\u5408\u6210\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Angew. Chem. Int. Ed.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u6570\u5341\u5e74\u6765\uff0c\u542b\u6709\u540e\u8fc7\u6e21\u91d1\u5c5e\uff08\u4e3b\u8981\u662f\u94af\uff09\u7684\u50ac\u5316\u5242\u4e00\u76f4\u7528\u4e8e\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\u3002Richard Heck\u3001Ei-ichi Negishi\u548cAkira Suzuki\u8fd8\u66fe\u56e0\u4e3a\u5728\u8fd9\u65b9\u9762\u7684\u91cd\u8981\u8d21\u732e\u83b7\u5f972010\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\uff08\u56fe2\uff09\uff0c\u8be5\u7c7b\u5408\u6210\u65b9\u6cd5\u5df2\u5e7f\u6cdb\u7528\u4e8e\u6709\u673a\u5206\u5b50\u78b3-\u78b3\u952e\u7684\u5f62\u6210\u8fc7\u7a0b\uff0c\u5bf9\u4e8e\u4eba\u7c7b\u793e\u4f1a\u7684\u53d1\u5c55\u5177\u6709\u4e0d\u53ef\u78e8\u706d\u7684\u8d21\u732e\u3002\u4f46\u4e0d\u53ef\u5426\u8ba4\u7684\u662f\uff0c\u8be5\u7c7b\u65b9\u6cd5\u4e5f\u5b58\u5728\u7f3a\u70b9\uff1a\u9700\u8981\u4f7f\u7528\u6709\u673a\u91d1\u5c5e\u914d\u5408\u7269\u4f5c\u4e3a\u50ac\u5316\u5242\uff08\u4e3b\u8981\u662f\u542b\u94af\u7684\u914d\u5408\u7269\uff09\uff0c\u800c\u8be5\u7c7b\u50ac\u5316\u5242\u4ef7\u683c\u6602\u8d35\u3001\u5408\u6210\u6761\u4ef6\u82db\u523b\u3001\u540e\u5904\u7406\u590d\u6742\u3002\u53e6\u5916\uff0c\u6709\u673a\u91d1\u5c5e\u914d\u5408\u7269\u5f88\u96be\u4ece\u76ee\u6807\u4ea7\u7269\u4e2d\u5b8c\u5168\u53bb\u9664\u3002\u4e3a\u4e86\u907f\u514d\u8be5\u7c7b\u65b9\u6cd5\u7684\u7f3a\u70b9\uff0c\u7814\u7a76\u4eba\u5458\u4e5f\u8bbe\u8ba1\u4e86\u5f88\u591a\u4e0d\u5305\u542b\u91d1\u5c5e\u7684\u5316\u5b66\u53cd\u5e94\uff0c\u4f46\u662f\u53cd\u5e94\u6761\u4ef6\u82db\u523b\u3001\u9009\u62e9\u6027\u4e5f\u8f83\u5dee\u3002\u56e0\u6b64\uff0c\u5bfb\u627e\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\u4f9d\u7136\u5341\u5206\u5fc5\u8981\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/9-1537926518.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe2. Richard Heck\u3001Ei-ichi Negishi\u548cAkira Suzuki\u56e0\u5728\u94af\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u9886\u57df\u7684\u91cd\u8981\u8d21\u732e\u83b7\u5f972010\u5e74\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Angew. Chem. Int. Ed.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u8fd1\u65e5\uff0c<strong>\u5fb7\u56fd\u83b1\u5e03\u5c3c\u5179\u7814\u7a76\u9662<\/strong>\u7684<strong>Christian Hertweck<\/strong>\u6559\u6388\u7b49\u4eba\u5728<\/span><span style=\"font-size: 16px;\"><strong><em>Angew. Chem. Int. Ed.&nbsp;<\/em><\/strong><\/span><span style=\"font-size: 18px;\">\u53d1\u8868\u6587\u7ae0\uff0c\u63d0\u51fa<strong>\u5728\u65e0\u8fc7\u6e21\u91d1\u5c5e\u7684\u6761\u4ef6\u4e0b\u5229\u7528\u5149\u526a\u63a5\uff08photosplicing\uff09\u6cd5\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269<\/strong>\u3002\u8be5\u65b9\u6cd5\u5148\u5229\u7528\u78fa\u9170\u80fa\u952e\u5c06\u4e24\u4e2a\u82ef\u57fa\u7247\u6bb5\u7ed3\u5408\uff0c\u7136\u540e\u5728\u7d2b\u5916\u706f\u7167\u5c04\u6761\u4ef6\u4e0b\u6d88\u9664\u78fa\u9170\u80fa\u5f62\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\uff0c\u533a\u57df\u9009\u62e9\u6027\u597d\uff0c\u526f\u4ea7\u7269\uff08\u4e8c\u6c27\u5316\u786b\u3001\u7532\u919b\u548c\u6c28\u6c14\uff09\u4e3a\u6c14\u4f53\uff0c\u6613\u5206\u79bb\uff08\u56fe3\uff09\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/7-1537926518.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe3. \u5149\u526a\u63a5\u6cd5\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\u7684\u53cd\u5e94\u793a\u610f\u56fe\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Angew. Chem. Int. Ed.<\/em><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><br  \/><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/6-1537926518.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">Christian Hertweck\u6559\u6388<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u63d0\u5230\u8be5\u65b9\u6cd5\u5e76\u4e0d\u662f\u9884\u5148\u8bbe\u8ba1\u597d\u7684\uff0c\u800c\u6765\u6e90\u4e8e\u610f\u5916\u53d1\u73b0\u3002\u4ed6\u4eec\u5728\u5408\u6210\u4e00\u79cd\u9176\u6291\u5236\u5242\u7684\u8fc7\u7a0b\u4e2d\uff0c\u5229\u7528\u8584\u5c42\u8272\u8c31\u5206\u6790\u5904\u7406\u526f\u4ea7\u7269\u78fa\u9170\u80fa\uff0c\u5e76\u4f7f\u7528\u7d2b\u5916\u706f\u7167\u5c04\u65f6\u53d1\u73b0\u5f88\u5f3a\u7684\u8367\u5149\uff0c\u7531\u6b64\u610f\u5473\u7740\u4e00\u79cd\u65b0\u7269\u8d28\u7684\u5f62\u6210\u3002\u4ed6\u4eec\u5229\u7528\u9ad8\u5206\u8fa8\u8d28\u8c31\u63a8\u65ad\u51fa\u8be5\u7269\u8d28\u7684\u5206\u5b50\u5f0f\u4e3aC<\/span><span style=\"font-size: 14px;\"><sub>14<\/sub><\/span><span style=\"font-size: 18px;\">H<\/span><span style=\"font-size: 14px;\"><sub>14<\/sub><\/span><span style=\"font-size: 18px;\">O<\/span><span style=\"font-size: 14px;\"><sub>2<\/sub><\/span><span style=\"font-size: 18px;\">\uff0c\u4e0d\u5305\u542b\u786b\u539f\u5b50\u548c\u6c2e\u539f\u5b50\u3002\u63a5\u7740\uff0c\u4f5c\u8005\u91cd\u590d\u8be5\u5b9e\u9a8c\u5e76\u8bc1\u660e\u7d2b\u5916\u706f\u7167\u5c04\u78fa\u9170\u80fa\u7684\u4ea7\u7269\u53ea\u6709\u4e00\u79cd\u8054\u82b3\u57fa\u5316\u5408\u7269\u3002<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u968f\u540e\u4f5c\u8005\u5bf9\u53cd\u5e94\u7684\u6eb6\u5242\u548c\u7d2b\u5916\u706f\u7684\u6ce2\u957f\u8fdb\u884c\u4e86\u4f18\u5316\u3002\u7531\u4e8e\u53cd\u5e94\u7684\u5e95\u7269\u548c\u4ea7\u7269\u90fd\u6709\u5f88\u5f3a\u7684\u7d2b\u5916\u5438\u6536\uff0c\u5f53\u5e95\u7269\u6d53\u5ea6\u8f83\u5927\u6216\u8005\u6db2\u5c42\u8f83\u539a\u65f6\u4f1a\u964d\u4f4e\u8f6c\u5316\u7387\u3002\u4e3a\u4e86\u907f\u514d\u8be5\u7f3a\u70b9\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e00\u5957\u5fae\u6d41\u63a7\u88c5\u7f6e\uff0c\u6b64\u65f6<strong>2a<\/strong>\u5316\u5408\u7269\u7684\u4ea7\u7387\u9ad8\u8fbe92%\uff0c\u4e5f\u8bc1\u660e\u8be5\u53cd\u5e94\u5177\u6709\u826f\u597d\u7684\u533a\u57df\u9009\u62e9\u6027\u3002<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4ee5\u5f80\u7684\u7814\u7a76\u8868\u660e\uff0c\u78fa\u9170\u80fa\u7684S-N\u952e\u53ef\u4ee5\u5728\u5149\u5f15\u53d1\u4e0b\u53d1\u751f\u5747\u88c2\uff0c\u5f62\u6210\u78b3\u4e2d\u5fc3\u81ea\u7531\u57fa\uff0c\u4e0e\u6b64\u540c\u65f6\uff0c\u82b3\u57fa\u78fa\u9170\u80fa\u8fd8\u53ef\u4ee5\u5728\u5149\u5f15\u53d1\u4e0b\u53d1\u751fSmiles\u91cd\u6392\u3002\u4f46\u5149\u7167\u6761\u4ef6\u4e0b\u540c\u65f6\u53d1\u751f\u88c2\u89e3\u4e0e\u91cd\u6392\u7684\u53cd\u5e94\u5c1a\u65e0\u62a5\u9053\uff0c\u53cd\u5e94\u4f53\u7cfb\u4e2d\u4e5f\u65e0\u6cd5\u68c0\u6d4b\u5230\u4e8c\u82b3\u57fa\u81ea\u7531\u57fa\u4ea7\u751f\u3002\u4f5c\u8005\u7531\u6b64\u63d0\u51fa\u5206\u5b50\u5185\u7684\u53cd\u5e94\u673a\u7406\u4ee5\u4f50\u8bc1\u53cd\u5e94\u5177\u6709\u826f\u597d\u7684\u533a\u57df\u9009\u62e9\u6027\uff0c\u53cd\u5e94\u5728\u5149\u5f15\u53d1\u4e0b\u53d1\u751f\u7535\u5b50\u8f6c\u79fb\u6216\u6781\u5316\uff0c\u5e76\u5f62\u6210\u73af\u72b6\u8fc7\u6e21\u6001\uff0c\u4fc3\u8fdb\u4e24\u4e2a\u82b3\u57fa\u7684\u5206\u5b50\u8f68\u9053\u53d1\u751f\u76f8\u4e92\u4f5c\u7528\uff0c\u4e94\u5143\u73af\u4e2d\u95f4\u4f53\u4ee5\u9006[3+2]\u73af\u52a0\u6210\u8fc7\u7a0b\u53d1\u751f\u88c2\u89e3\u5f97\u5230\u5076\u8054\u4ea7\u7269\uff0c\u53e6\u4e00\u5206\u5b50<em>N<\/em>-\u78fa\u9170\u80fa\u884d\u751f\u7684\u7269\u79cd\u5206\u89e3\u4e3a\u7532\u919b\u3001\u4e8c\u6c27\u5316\u786b\u548c\u6c28\u3002<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u53c8\u5206\u522b\u7528\u5948\u6c0f\u8bd5\u5242\uff08potassium tetraiodomercurate(II)\uff09\u548cBrady\u8bd5\u5242\uff082,4-dinitrophenylhydrazine\uff09\u9a8c\u8bc1\u53cd\u5e94\u7684\u526f\u4ea7\u7269\u6c28\u6c14\u548c\u7532\u919b\uff0c\u5229\u7528\u9876\u7a7a\u6c14\u76f8\u8272\u8c31\u6cd5\uff08headspace GC-MS\uff09\u8bc1\u660e\u4e8c\u6c27\u5316\u786b\u7684\u4ea7\u751f\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/8-1537926518.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe4. \u5149\u526a\u63a5\u6cd5\u7684\u53d1\u73b0\u3001\u8bbe\u8ba1\u4e0e\u673a\u7406\u5206\u6790\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Angew. Chem. Int. Ed.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u8be5\u65b9\u6cd5\u80fd\u591f\u5728\u4e0d\u4f7f\u7528\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u60c5\u51b5\u4e0b\u5408\u6210\u4e00\u7cfb\u5217\u5177\u6709\u91cd\u8981\u836f\u7528\u4ef7\u503c\u7684\u8054\u82b3\u57fa\u5316\u5408\u7269\uff0c\u5176\u4e2d\u5305\u62ec\u5e74\u8425\u4e1a\u989d\u8d85\u8fc710\u4ebf\u7f8e\u5143\u7545\u9500\u836f\u7684\u6709\u6548\u6210\u5206\uff0c\u5982\u6297\u9ad8\u8840\u538b\u836f\u3001\u6d88\u708e\u836f\u3001\u7ec6\u80de\u751f\u957f\u6291\u5236\u5242\u3001\u6b62\u75db\u836f\u548c\u6cbb\u7597\u795e\u7ecf\u9000\u884c\u6027\u75be\u75c5\u7684\u6709\u6548\u6210\u5206\uff0c\u8868\u660e\u8be5\u65b9\u6cd5\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/0-1537926519.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe5. \u5229\u7528\u5149\u526a\u63a5\u6cd5\u5408\u6210\u542b\u8054\u82b3\u57fa\u7684\u836f\u7269\u5206\u5b50\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Angew. Chem. Int. Ed.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u5bf9\u4e8e\u8fd9\u4e00\u610f\u5916\u53d1\u73b0\u7684\u7814\u7a76\u6210\u679c\uff0cChristian Hertweck\u6559\u6388\u8bc4\u8bba\u8bf4\uff1a\u201c\u6211\u4eec\u5e76\u6ca1\u6709\u4e13\u95e8\u81f4\u529b\u4e8e\u7814\u7a76\u4e00\u79cd\u65b0\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u4f46\u8fd9\u7684\u786e\u662f\u4e00\u4e2a\u91cd\u5927\u7684\u53d1\u73b0\uff0c\u6211\u4eec\u56e2\u961f\u53d1\u73b0\u4e4b\u540e\u5e76\u7acb\u523b\u610f\u8bc6\u5230\u5b83\u7684\u5de8\u5927\u4ef7\u503c\u3002\u8fd9\u79cd\u53d1\u73b0\u4e0d\u80fd\u4e8b\u5148\u5728\u56fe\u7eb8\u4e0a\u8ba1\u5212\u597d\uff0c\u4e5f\u4e0d\u80fd\u6309\u7167\u56fa\u5b9a\u7684\u5de5\u4f5c\u8ba1\u5212\u6765\u5b9e\u73b0\u3002\u6210\u529f\u7684\u83b7\u5f97\u662f\u56e0\u4e3a\u6709\u4e00\u4e2a\u6d3b\u8dc3\u7684\u5927\u8111\u3001\u4e00\u4e2a\u5145\u6ee1\u6fc0\u60c5\u7684\u56e2\u961f\u548c\u534f\u540c\u5408\u4f5c\u7684\u6c1b\u56f4\uff0c\u518d\u52a0\u4e0a\u4e00\u4e9b\u8fd0\u6c14\u3002\u201d<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: center;line-height: 1.75em;\"><span style=\"color: rgb(33, 127, 188);\"><strong><span style=\"font-size: 18px;\">\u603b\u7ed3<\/span><\/strong><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u5bf9\u4e8e\u8be5\u5de5\u4f5c\u63d0\u5230\u7684\u5149\u526a\u63a5\u6cd5\uff0c\u53cd\u5e94\u9996\u5148\u5f62\u6210\u78fa\u9170\u80fa\u952e\u8fde\u63a5\u4e24\u4e2a\u82ef\u57fa\u7684\u7ed3\u6784\uff0c\u7136\u540e\u5229\u7528\u7d2b\u5916\u5149\u7834\u574f\u78fa\u9170\u80fa\u952e\u5f97\u5230\u8054\u82b3\u57fa\u5316\u5408\u7269\u3002\u5bf9\u4e8eChristian Hertweck\u7684\u8bc4\u8bba\uff0c\u7b14\u8005\u4e5f\u662f\u6df1\u6709\u4f53\u4f1a\u3002\u6211\u4eec\u5e73\u5e38\u505a\u5b9e\u9a8c\u5e94\u8be5\u6562\u60f3\u3001\u6562\u505a\uff0c\u591a\u4e0e\u522b\u4eba\u4ea4\u6d41\u3002\u4e0d\u8981\u5bb3\u6015\u51fa\u73b0\u95ee\u9898\uff0c\u6211\u4eec\u7684\u76ee\u6807\u672c\u6765\u5c31\u662f\u89e3\u51b3\u95ee\u9898\u3002\u5b9e\u9a8c\u4e2d\u5982\u679c\u6709\u610f\u5916\u53d1\u73b0\uff0c\u6df1\u5165\u63a2\u7a76\u6ca1\u51c6\u4f1a\u5f97\u5230\u60ca\u559c\u3002<\/span><\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n<p><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/9-1537926519.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Metal\u2010Free Synthesis of Pharmaceutically Important Biaryls by Photosplicing<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">Angew. Chem. Int. Ed.<\/span><\/em><span style=\"font-size: 14px;\">, <strong>2018<\/strong>, DOI: 10.1002\/anie.201805961<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 14px;\">\u53c2\u8003\u8d44\u6599\uff1a<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 14px;\">1.https:\/\/medizin-aspekte.de\/102080-synthesis-of-pharmaceuticals-with-light\/<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 14px;\">2.https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201107017<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: right;\">\uff08\u672c\u6587\u7531<strong>Sunshine<\/strong>\u4f9b\u7a3f\uff09<\/p>\n<p><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"font-size: 18.018px;\"><\/a><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"font-size: 18.018px;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 558px;top: auto;left: auto;right: auto;bottom: auto;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/9-1537926519-1.jpeg\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/span><\/a><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/2-1537926519.png\" alt=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\" title=\"\u201c\u610f\u5916\u201d\u5b9e\u73b0\u7684\u65e0\u8fc7\u6e21\u91d1\u5c5e\u6761\u4ef6\u4e0b\u201c\u5149\u526a\u63a5\u201d\u5408\u6210\u8054\u82b3\u57fa\u5316\u5408\u7269\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"display: inline-block;color: transparent;clear: both;box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;word-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n<p 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