{"id":48536,"date":"2018-09-23T01:00:00","date_gmt":"2018-09-26T01:49:54","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/26\/nature-chem-%ef%bc%9a%e6%9d%a5%e8%87%aa%e6%b1%bd%e8%bd%a6%e8%ae%be%e8%ae%a1%e7%9a%84%e7%90%86%e5%bf%b5%ef%bc%8c%e8%ae%a9mof%e5%af%b9%e6%b0%b4%e4%b8%8d%e5%86%8d%e6%95%8f%e6%84%9f\/"},"modified":"2018-09-26T09:49:57","modified_gmt":"2018-09-26T01:49:57","slug":"nature-chem-%ef%bc%9a%e6%9d%a5%e8%87%aa%e6%b1%bd%e8%bd%a6%e8%ae%be%e8%ae%a1%e7%9a%84%e7%90%86%e5%bf%b5%ef%bc%8c%e8%ae%a9mof%e5%af%b9%e6%b0%b4%e4%b8%8d%e5%86%8d%e6%95%8f%e6%84%9f","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/48536\/","title":{"rendered":"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;\"><span style=\"line-height: 0px;\">\u200d\u200d<\/span><span style=\"font-size: 18.018px;line-height: 0px;\">\u200d<a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><\/a><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 558px;top: auto;left: auto;right: auto;bottom: auto;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/4-1537926594.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/span><\/a><\/span><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657574730&amp;idx=1&amp;sn=7001a26433acb77dcdd5629f27cd8b20&amp;chksm=80f7769ab780ff8cedab5baefd9bc7a02dd18b2191cd29afb2d190e8ea149564133c9437e7d5&amp;scene=21#wechat_redirect\" target=\"_blank\"><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong><span style=\"font-size: 18px;\">\u91d1\u5c5e\u6709\u673a\u6846\u67b6<\/span><\/strong><span style=\"font-size: 18px;\">\uff08MOF\uff09\u5728\u8fc7\u53bb\u5341\u51e0\u5e74\u4e2d\u4e00\u76f4\u90fd\u662f\u6750\u6599\u7814\u7a76\u4e2d\u7684\u70ed\u95e8\uff0c\u56e0\u4e3a\u5b83\u7684\u5355\u6676\u7ed3\u6784\u3001\u5b54\u53c2\u6570\u4ee5\u53ca\u6027\u80fd\u53ef\u4ee5\u901a\u8fc7\u5bf9\u6709\u673a\u914d\u4f53\u6216\u91d1\u5c5e\u79bb\u5b50\u4ee5\u53ca\u6eb6\u5242\u3001\u5408\u6210\u6761\u4ef6\u7684\u8c03\u8282\u8fdb\u884c\u63a7\u5236\uff0c\u4ece\u800c\u5438\u5f15\u4e86\u4e0d\u540c\u80cc\u666f\u7814\u7a76\u8005\u7684\u5173\u6ce8\u3002MOF\u7684\u6838\u5fc3\u5c5e\u6027\u662f\u9ad8\u5b54\u9699\u7387\u548c\u6bd4\u8868\u9762\u79ef\uff0c\u8fd9\u662f\u6c14\u4f53\u5438\u9644\u3001\u5b58\u50a8\u7b49\u5e94\u7528\u7684\u5173\u952e\u3002\u7136\u800c\uff0cMOF\u7684\u7cbe\u7ec6\u5fae\u89c2\u7ed3\u6784\u5728\u9047\u5230\u6c34\u6c7d\u7b49\u5177\u6709\u4e00\u5b9a\u4eb2\u6838\u6027\u7684\u5438\u9644\u7269\u540e\u5f88\u5bb9\u6613\u88ab\u7834\u574f\u3002\u4e3a\u4e86\u514b\u670d\u8fd9\u4e2a\u7f3a\u70b9\uff0c\u7814\u7a76\u8005\u4eec\u91c7\u53d6\u7684\u63aa\u65bd\u901a\u5e38\u90fd\u662f\u6539\u53d8MOF\u7684\u5316\u5b66\u6210\u5206\uff0c\u7531\u6b64\u6765\u52a0\u5f3aMOF\u4e2d\u8f83\u5f31\u7684\u914d\u4f4d\u952e\uff0c\u5176\u4e2d\u6700\u7ecf\u5178\u7684\u7b56\u7565\u662f\u4f7f\u7528Zr(IV)\u4f5c\u4e3a\u91d1\u5c5e\u79bb\u5b50\u3002\u5728MOF\u5408\u6210\u540e\u8fdb\u884c\u4fee\u9970\u4e5f\u53ef\u4ee5\u63d0\u9ad8\u5b83\u5bf9\u6c34\u6c7d\u7684\u7a33\u5b9a\u6027\uff0c\u4f8b\u5982\u5f15\u5165\u758f\u6c34\u7684\u4fdd\u62a4\u5c42\uff0c\u6216\u8005\u4e0e\u9ad8\u5206\u5b50\u7b49\u6750\u6599\u5171\u6df7\u3002\u4e0d\u8fc7\u8fd9\u4e9b\u529e\u6cd5\u5728\u63d0\u9ad8MOF\u7a33\u5b9a\u6027\u7684\u540c\u65f6\uff0c\u90fd\u4e0d\u53ef\u907f\u514d\u7684\u6539\u53d8\u4e86\u6750\u6599\u672c\u8eab\u7684\u5316\u5b66\u6027\u8d28\u3002<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u5b9e\u9645\u4e0a\uff0c\u8fd9\u4e9b\u63d0\u9ad8MOF\u7a33\u5b9a\u6027\u7684\u7b56\u7565\u76f8\u5f53\u7c7b\u4f3c\u65e9\u671f\u7684\u6c7d\u8f66\u8bbe\u8ba1\u5b89\u5168\u7406\u5ff5\u2014\u2014\u8d8a\u575a\u56fa\u7684\u7ed3\u6784\u8d8a\u80fd\u589e\u52a0\u7a33\u5b9a\u6027\u3002\u57fa\u4e8e\u8fd9\u7c7b\u7406\u5ff5\uff0c\u5728\u4e0a\u4e16\u7eaa50\u5e74\u4ee3\u53ca\u4ee5\u524d\uff0c\u6c7d\u8f66\u8f66\u8eab\u7ed3\u6784\u603b\u662f\u88ab\u8bbe\u8ba1\u5f97\u8d8a\u786c\u8d8a\u597d\u3002\u542c\u8d77\u6765\u5f88\u5408\u7406\u7684\u8bbe\u8ba1\uff0c\u4f46\u5b9e\u9645\u60c5\u51b5\u5374\u662f\u8f66\u7978\u4e2d\u9a7e\u4e58\u8005\u7684\u4f24\u4ea1\u6bd4\u4f8b\u5c45\u9ad8\u4e0d\u4e0b\u3002\u8f66\u4f01\u548c\u8bbe\u8ba1\u8005\u4eec\u5f00\u59cb\u53cd\u601d\uff0c\u5728\u6c7d\u8f66\u53d1\u751f\u610f\u5916\u78b0\u649e\u7684\u65f6\u5019\uff0c\u575a\u56fa\u7684\u8f66\u8eab\u4f1a\u77ac\u95f4\u5c06\u80fd\u91cf\u5b8c\u5168\u4f20\u9012\u7ed9\u9a7e\u9a76\u5458\u548c\u4e58\u5ba2\uff0c\u8ba9\u4eba\u4f53\u627f\u53d7\u5de8\u5927\u4f5c\u7528\u529b\u800c\u4ea7\u751f\u4e25\u91cd\u4f24\u5bb3\u3002\u4e8e\u662f\u5954\u9a70\u516c\u53f8\u7684\u5de5\u7a0b\u5e08B\u00e9la Bar\u00e9nyi\u5728\u4e0a\u4e16\u7eaa50\u5e74\u4ee3\u63d0\u51fa\u4e86\u201c\u6e83\u7f29\u533a\uff08crumple zones\uff09\u201d\u7684\u8bbe\u8ba1\u7406\u5ff5\uff0c\u5373\u5728\u6c7d\u8f66\u4e58\u5458\u8231\u524d\u540e\u8bbe\u7f6e\u53ef\u6298\u53e0\u7684\u6e83\u7f29\u533a\uff0c\u5728\u78b0\u649e\u65f6\u901a\u8fc7\u6e83\u7f29\u53d8\u5f62\u6765\u5c3d\u53ef\u80fd\u591a\u5730\u5438\u6536\u80fd\u91cf\u8d77\u5230\u7f13\u51b2\u4f5c\u7528\uff0c\u6700\u5927\u9650\u5ea6\u5730\u4fdd\u62a4\u8f66\u5185\u9a7e\u4e58\u8005\u3002\u901a\u8fc7\u6e83\u7f29\u533a\u7684\u201c\u727a\u7272\u201d\uff0c\u6c7d\u8f66\u7684\u5b89\u5168\u6027\u80fd\u7684\u786e\u5927\u5927\u63d0\u9ad8\uff0c\u5982\u4eca\u6e83\u7f29\u533a\u7684\u7406\u5ff5\u5df2\u7ecf\u6210\u4e3a\u6c7d\u8f66\u5b89\u5168\u6280\u672f\u7684\u57fa\u7840\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/7-1537926594.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u6c7d\u8f66\u4e2d\u7684\u6e83\u7f29\u533a\u3002\u56fe\u7247\u6765\u6e90\u4e8e\u7f51\u7edc<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u518d\u56de\u5230MOF\u6750\u6599\uff0c\u8fd1\u671f\u4e00\u4e2a\u7531<strong>\u82f1\u56fd\u5723\u5b89\u5fb7\u9c81\u65af\u5927\u5b66Russell E. Morris<\/strong>\u6559\u6388\u9886\u5bfc\u7684\u7814\u7a76\u56e2\u961f<strong>\u63d0\u51fa\u7c7b\u4f3c\u6c7d\u8f66\u201c\u6e83\u7f29\u533a\u201d\u7684\u673a\u5236\u6765\u63d0\u9ad8MOF\u7684\u6c34\u89e3\u7a33\u5b9a\u6027<\/strong>\u3002\u4ed6\u4eec\u5408\u6210\u7684\u4e00\u79cd\u94dc\u57faMOF\uff08STAM-17-OEt\uff09\u91d1\u5c5e\u4e2d\u5fc3\u7684\u914d\u4f4d\u73af\u5883\u4e2d\u5b58\u5728\u975e\u7ed3\u6784\u6027\u7684\u5f31\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\uff0c\u5728\u63a5\u89e6\u6c34\u5206\u5b50\u65f6\uff0c\u8fd9\u4e9b\u5f31\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u4f5c\u4e3a\u201c\u6e83\u7f29\u533a\u201d\u88ab\u7834\u574f\uff0c\u4f46MOF\u7684\u6846\u67b6\u7ed3\u6784\u8fd8\u53ef\u4fdd\u6301\u7a33\u5b9a\u3002\u76f8\u5173\u8bba\u6587\u53d1\u8868\u4e8e<em><strong>Nature Chemistry<\/strong><\/em> \u6742\u5fd7\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/2-1537926595.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">Russell E. Morris\u6559\u6388\u3002\u56fe\u7247\u6765\u6e90\uff1aUniversity of St Andrews<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">HKUST-1\u662f\u4e00\u79cd\u88ab\u5e7f\u6cdb\u7814\u7a76\u7684MOF\u6750\u6599\uff0c\u5b83\u7531\u94dc\u79bb\u5b50\u548c\u5747\u4e09\u82ef\u7532\u9178\u7ec4\u6210\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u5e76\u4e14\u5bf9\u6c28\u6c14\u548c\u786b\u5316\u6c22\u7b49\u6709\u5bb3\u6c14\u4f53\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u9009\u62e9\u6027\uff0c\u56e0\u800c\u6709\u671b\u7528\u4e8e\u4ece\u7a7a\u6c14\u4e2d\u5438\u9644\u8fd9\u7c7b\u6709\u5bb3\u6c14\u4f53\uff0c\u4f46\u5374\u9762\u4e34\u5bf9\u7a7a\u6c14\u4e2d\u7684\u6c34\u6c7d\u7684\u7a33\u5b9a\u6027\u4e0d\u8db3\u7684\u91cd\u5927\u6311\u6218\u3002\u4f5c\u8005\u57fa\u4e8e5-\u4e59\u6c27\u57fa-\u95f4\u82ef\u4e8c\u7532\u9178\u916f\u548c\u94dc\u79bb\u5b50\u5408\u6210\u7684STAM-17-OEt\uff0c\u5c3d\u7ba1\u5316\u5b66\u7ec4\u6210\u4e0eHKUST-1\u76f8\u5f53\u76f8\u4f3c\uff0c\u4f46\u7a33\u5b9a\u6027\u5374\u5f97\u5230\u4e86\u6781\u5927\u7684\u63d0\u9ad8\uff0c\u5373\u4fbf\u5728\u6c34\u4e2d\u653e\u7f6e1\u5e74\u540e\u7ed3\u6784\u4f9d\u7136\u53ef\u4fdd\u6301\u5b8c\u6574\uff0c\u800cHKUST-1\u76f8\u540c\u6761\u4ef6\u4e0b\u575a\u6301\u4e0d\u8fc71\u5929\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/8-1537926595.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">STAM-17-OEt\u548cHKUST-1\u4e2d\u90fd\u8fd8\u6709\u7c7b\u4f3c\u6868\u8f6e\u7684\u4e8c\u805a\u7ed3\u6784\uff08Cu\uff0c\u84dd\uff1bO\uff0c\u7ea2\uff1bC\uff0c\u9ed1\uff09\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u53d1\u73b0\uff0cSTAM-17-OEt\u5728\u6c34\u5408\u548c\u8131\u6c34\u7684\u72b6\u6001\u4e0b\u8868\u73b0\u51fa\u975e\u5e38\u4e0d\u540c\u7684\u6676\u4f53\u7ed3\u6784\u3002\u5982\u4e0b\u56fe\u6240\u793a\uff0c\u5c3d\u7ba1\u4e24\u8005\u90fd\u53ef\u4ee5\u8ba4\u4e3a\u662f\u5177\u6709\u7247\u72b6\u7ed3\u6784\uff0c\u4e5f\u90fd\u5c5e\u4e8e\u4e09\u65b9\u6676\u7cfb\uff0c\u4f46\u662f\u7a7a\u95f4\u7fa4\u3001\u6676\u80de\u53c2\u6570\u90fd\u53d1\u751f\u4e86\u53d8\u5316\u3002\u5728\u6c34\u5408\u72b6\u6001\u4e0b\uff0cMOF\u6676\u4f53\u4e2d\u6240\u6709\u94dc\u79bb\u5b50\u90fd\u662f\u7b49\u4ef7\u7684\uff0c\u5e76\u4e14\u90fd\u4e0e\u4e00\u4e2a\u6c34\u5206\u5b50\u53d1\u751f\u4e86\u914d\u4f4d\u3002\u901a\u5e38\u800c\u8a00\uff0c\u5728\u8131\u6c34\u540eMOF\u4e2d\u94dc\u79bb\u5b50\u5c06\u53d8\u4e3a\u914d\u4f4d\u4e0d\u9971\u548c\u7684\u72b6\u6001\u3002\u4f46\u5b9e\u9645\u4e0a\uff0c\u5728\u8131\u6c34\u7684STAM-17-OEt\u4e2d\uff0c\u7fa7\u57fa\u6c27\u53d8\u6210\u4e86\u6865\u914d\u4f53\uff0c\u5f25\u8865\u4e86\u6c34\u5206\u5b50\u8131\u79bb\u9020\u6210\u7684\u7a7a\u4f4d\u3002\u8fd9\u4f7f\u5f97\u6676\u4f53\u7ed3\u6784\u6574\u4f53\u51fa\u73b0\u4e86\u626d\u66f2\uff0c\u94dc\u79bb\u5b50\u4e0d\u518d\u7b49\u4ef7\uff0c\u5728\u4e0b\u56fe\u5de6\u4fa7\u7684\u94dc\u79bb\u5b50\uff08\u7c89\u8272\u548c\u7eff\u8272\uff09\u5904\u5728\u4e0d\u540c\u7684\u914d\u4f4d\u73af\u5883\u4e2d\u3002\u9700\u8981\u6307\u51fa\uff0c\u8131\u6c34\u9020\u6210\u7684\u7ed3\u6784\u6539\u53d8\u662f\u53ef\u9006\u7684\uff0c\u53ea\u662f\u8fd9\u4e2a\u8fc7\u7a0b\u5fc5\u7136\u9700\u8981\u6d88\u8017\u80fd\u91cf\u3002\u4f5c\u8005\u8ba4\u4e3a\uff0c\u5728STAM-17-OEt\u4e2d\uff0c\u8fd9\u91cc\u6240\u9700\u8981\u7684\u80fd\u91cf\u6b63\u662f\u6765\u6e90\u4e8e\u6c34\u5206\u5b50\u5728MOF\u4e2d\u5438\u9644\u91ca\u653e\u7684\u70ed\u91cf\u3002\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u8ba1\u7b97\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u8fd9\u4e00\u731c\u6d4b\uff0c\u8fd9\u79cd\u8131\u6c34\u8fc7\u7a0b\u4e2d\u53d1\u751f\u7684\u6676\u4f53\u7ed3\u6784\u6539\u53d8\u4f7f\u5f97\u4f53\u7cfb\u7684\u80fd\u91cf\u4e0b\u964d\u4e862.4 kJ\/mol\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/2-1537926595-1.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u8131\u6c34\uff08\u5de6\u4fa7\uff09\u548c\u6c34\u5408\uff08\u53f3\u4fa7\uff09\u7684STAM-17-OEt\u7684\u6676\u4f53\u7ed3\u6784\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u8fdb\u4e00\u6b65\u6bd4\u8f83\u4e86STAM-17-OEt\u548cHKUST-1\u5bf9\u6c34\u7684\u7a33\u5b9a\u6027\u3002\u8131\u6c34\u7684HKUST-1\u66b4\u9732\u5728\u6f6e\u6e7f\u73af\u5883\u4e0b\uff0c\u5728\u7ecf\u5386\u6700\u521d\u5bf9\u6c34\u84b8\u6c14\u7684\u5feb\u901f\u5438\u9644\u540e\uff0c\u8fd8\u4f1a\u518d\u7f13\u6162\u5438\u9644\u4e00\u4e9b\u6c34\u5206\u5b50\u8fbe\u5230\u9971\u548c\uff0c\u4f46\u572820\u5c0f\u65f6\u5de6\u53f3\u5c31\u4f1a\u5f00\u59cb\u4e0b\u964d\uff08\u4e0b\u56fea\uff0c\u84dd\u8272\uff09\u3002\u7ed3\u5408\u7ea2\u5916\uff08\u4e0b\u56feb\uff09\uff0c\u53ef\u4ee5\u53d1\u73b0\u8fd9\u662f\u56e0\u4e3aHKUST-1\u7684\u5316\u5b66\u7ed3\u6784\u5df2\u7ecf\u53d7\u5230\u4e86\u7834\u574f\u3002\u76f8\u53cd\u7684\uff0cSTAM-17-OEt\u5f88\u5feb\u8fbe\u5230\u9971\u548c\u5438\u9644\uff0c\u5e76\u4e14\u81f3\u5c11\u57285\u5929\u65f6\u95f4\u5185\u7ef4\u6301\u4e0d\u53d8\uff08\u4e0b\u56fea\uff0c\u7eff\u8272\uff09\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0c\u7ea2\u5916\u7ed3\u6784\u5206\u6790\u4e5f\u9a8c\u8bc1\u5316\u5b66\u7ec4\u6210\u6ca1\u6709\u53d1\u751f\u663e\u8457\u6539\u53d8\uff08\u4e0b\u56fec\uff09\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/3-1537926596.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">STAM-17-OEt\u548cHKUST-1\u5bf9\u6c34\u7684\u7a33\u5b9a\u6027\u6bd4\u8f83\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><br  \/><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u524d\u9762\u63d0\u5230HKUST-1\u7531\u4e8e\u5177\u6709\u8f83\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u548c\u914d\u4f4d\u4e0d\u9971\u548c\u94dc\uff0c\u56e0\u800c\u6709\u671b\u7528\u4e8e\u5438\u9644\u7c7b\u4f3c\u6c28\u6c14\u3001\u786b\u5316\u6c22\u7b49\u6709\u5bb3\u6c14\u4f53\u3002\u4f46\u662f\uff0c\u771f\u5b9e\u73af\u5883\u4e2d\u8fd9\u4e9b\u6c14\u4f53\u5f80\u5f80\u6df7\u6709\u6c14\u6001\u6c34\u5206\u5b50\uff0c\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0cHKUST-1\u5bf9\u6c34\u5206\u5b50\u7684\u654f\u611f\u6027\u5c31\u6210\u4e3a\u4e00\u4e2a\u91cd\u8981\u7684\u77ed\u677f\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5728\u5e72\u71e5\u73af\u5883\u6216\u8005\u8f83\u77ed\u65f6\u95f4\u7684\u6f6e\u6e7f\u73af\u5883\u4e0b\uff0cHKUST-1\u8868\u73b0\u51fa\u6bd4STAM-17-OEt\u66f4\u597d\u7684\u6c28\u6c14\u5438\u9644\u80fd\u529b\uff0c\u4f46\u662f\u968f\u7740\u65f6\u95f4\u7684\u63a8\u79fb\uff0cHKUST-1\u7684\u5438\u9644\u80fd\u529b\u51fa\u73b0\u4e0b\u6ed1\uff08\u4e0b\u56fea\uff0c\u84dd\u8272\uff09\uff0c\u540c\u65f6\u7ed3\u6784\u4e5f\u53d1\u751f\u4e86\u663e\u8457\u7684\u53d8\u5316\uff08\u4e0b\u56feb\uff09\u3002\u800cSTAM-17-OEt\u5219\u80fd\u7ef4\u6301\u5316\u5b66\u7ed3\u6784\uff08\u4e0b\u56fec\uff09\u548c\u826f\u597d\u7684\u5438\u9644\u6027\u80fd\uff08\u4e0b\u56fea\uff0c\u7eff\u8272\uff09\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/1-1537926596.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">STAM-17-OEt\u548cHKUST-1\u5728\u4e0d\u540c\u73af\u5883\u4e0b\u5438\u9644\u6c28\u7684\u6bd4\u8f83\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u8ba4\u4e3aSTAM-17-OEt\u8fd9\u79cd\u4e0d\u540c\u5bfb\u5e38\u7684\u7a33\u5b9a\u6027\u5f88\u53ef\u80fd\u548c\u6c34\u5408\uff08\u8131\u6c34\uff09\u8fc7\u7a0b\u4e2d\u4f34\u968f\u7684\u7ed3\u6784\u8f6c\u53d8\u6709\u5173\u3002\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u201c\u6e83\u7f29\u533a\u201d\u673a\u5236\u5c06\u4e24\u79cd\u73b0\u8c61\u8054\u7cfb\u8d77\u6765\u3002\u5728HKUST-1\u4e2d\uff0c\u6c34\u5206\u5b50\u548c\u94dc\u79bb\u5b50\u7684\u914d\u4f4d\u91ca\u653e\u7684\u80fd\u91cf\u65e0\u5904\u53ef\u53bb\uff0c\u53ea\u80fd\u901a\u8fc7\u7834\u574f\u94dc\u79bb\u5b50\u548c\u7fa7\u57fa\u7684\u914d\u4f4d\u4f20\u9012\u51fa\u53bb\uff0c\u4ece\u800c\u5bfc\u81f4\u6750\u6599\u7684\u964d\u89e3\u3002\u800c\u5728STAM-17-OEt\u4e2d\uff0c\u6c34\u5206\u5b50\u548c\u94dc\u79bb\u5b50\u7684\u914d\u4f4d\u91ca\u653e\u7684\u80fd\u91cf\u88ab\u7528\u4e8e\u7834\u574f\u539f\u6709\u7684\u94dc\u6c27\u914d\u4f4d\uff08\u8f83\u5f31\uff09\uff0c\u4ee5\u53ca\u4ea7\u751f\u4e86\u7ed3\u6784\u7684\u626d\u8f6c\uff0c\u4e0d\u81f3\u4e8e\u7834\u574f\u7ed3\u6784\u6027\u7684\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/10-1537926596.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u8131\u6c34\u7684STAM-17-OEt\u548cHKUST-1\u4e0e\u6c34\u914d\u4f4d\u8fc7\u7a0b\u7684\u6bd4\u8f83\u3002\u56fe\u7247\u6765\u6e90\uff1a<em>Nat. Chem.<\/em><\/span><\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n<p><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/0-1537926597.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Hydrolytic stability in hemilabile metal\u2013organic frameworks<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">Nat. Chem.<\/span><\/em><span style=\"font-size: 14px;\">, <strong>2018<\/strong>, DOI: 10.1038\/s41557-018-0104-x<\/span><\/p>\n<p style=\"line-height: normal;\"><span style=\"font-size: 14px;\"><br  \/><\/span><\/p>\n<p><span style=\"font-size: 14px;\">\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n<p><span style=\"font-size: 14px;\">Russell E. Morris<\/span><\/p>\n<p><span style=\"font-size: 14px;\">http:\/\/www.x-mol.com\/university\/faculty\/3285<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: right;\">\uff08\u672c\u6587\u7531<strong>\u8377\u5858\u6708<\/strong>\u4f9b\u7a3f\uff09<\/p>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"font-size: 18.018px;\"><\/a><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"font-size: 18.018px;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 558px;top: auto;left: auto;right: auto;bottom: auto;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/3-1537926597.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/span><\/a><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/7-1537926597.png\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"display: inline-block;color: transparent;clear: both;box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;word-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n<p style=\"box-sizing: border-box;\"><br style=\"box-sizing: border-box;\"  \/><\/p>\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\"><span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">\u957f\u6309<\/strong><\/span>\u4e0b\u56fe<strong style=\"box-sizing: border-box;\">\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<p style=\"margin-top: 10px;margin-bottom: 10px;text-align: center;box-sizing: border-box;\"><img class=\"\"     style=\"vertical-align: middle;box-sizing: border-box;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/3-1537926597-1.jpeg\" alt=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\" title=\"Nature Chem.\uff1a\u6765\u81ea\u6c7d\u8f66\u8bbe\u8ba1\u7684\u7406\u5ff5\uff0c\u8ba9MOF\u5bf9\u6c34\u4e0d\u518d\u654f\u611f\"  \/><\/p>\n<\/section>\n<\/section>\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-bottom: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-bottom: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section style=\"white-space: normal;\">\n<section >\n<section>\n<section>\n<section>\n<section >\n<section>\n<section>\n<p style=\"text-align: center;\"><br  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;word-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 18px;box-sizing: border-box !important;word-wrap: break-word !important;\">\u70b9\u51fb\u201c<span style=\"max-width: 100%;color: rgb(0, 122, 170);\">\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b&nbsp;<strong>\u5316\u5b66 \u2022 \u6750\u6599&nbsp;<\/strong>\u9886\u57df<span style=\"max-width: 100%;background-color: rgb(255, 218, 81);\">\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;overflow-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 14px;box-sizing: border-box !important;word-wrap: break-word !important;\"><\/span><\/p>\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u200d\u200d\u200d \u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u5728\u8fc7\u53bb\u5341\u51e0\u5e74\u4e2d\u4e00\u76f4\u90fd\u662f\u6750\u6599\u7814\u7a76\u4e2d\u7684\u70ed\u95e8\uff0c\u56e0\u4e3a\u5b83\u7684\u5355\u6676\u7ed3\u6784\u3001\u5b54\u53c2\u6570\u4ee5\u53ca\u6027\u80fd\u53ef\u4ee5\u901a\u8fc7 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