{"id":48641,"date":"2018-09-22T01:00:00","date_gmt":"2018-09-26T01:51:09","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/26\/%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91pd%e5%82%ac%e5%8c%96%e9%85%9a%e4%b8%8e%e8%b4%ab%e7%94%b5%e5%ad%90%e7%83%af%e7%83%83%e7%9a%84%e7%9b%b4%e6%8e%a5%e4%ba%a4%e5%8f%89%e8%84%b1%e6%b0%a2%e5%81%b6%e8%81%94\/"},"modified":"2018-09-26T09:51:14","modified_gmt":"2018-09-26T01:51:14","slug":"%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91pd%e5%82%ac%e5%8c%96%e9%85%9a%e4%b8%8e%e8%b4%ab%e7%94%b5%e5%ad%90%e7%83%af%e7%83%83%e7%9a%84%e7%9b%b4%e6%8e%a5%e4%ba%a4%e5%8f%89%e8%84%b1%e6%b0%a2%e5%81%b6%e8%81%94","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/48641\/","title":{"rendered":"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;\"><span style=\"line-height: 0px;\">\u200d\u200d<\/span><span style=\"font-size: 18.018px;line-height: 0px;\">\u200d<a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><\/a><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 558px;top: auto;left: auto;right: auto;bottom: auto;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/9-1537926670.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/span><\/a><\/span><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657574730&amp;idx=1&amp;sn=7001a26433acb77dcdd5629f27cd8b20&amp;chksm=80f7769ab780ff8cedab5baefd9bc7a02dd18b2191cd29afb2d190e8ea149564133c9437e7d5&amp;scene=21#wechat_redirect\" target=\"_blank\"><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\u662f\u836f\u7269\u548c\u529f\u80fd\u6750\u6599\u4e2d\u91cd\u8981\u7684\u7ed3\u6784\u5355\u5143\u4e4b\u4e00\u3002\u5c3d\u7ba1\u76ee\u524d\u4eba\u4eec\u5df2\u7ecf\u53d1\u5c55\u4e86\u591a\u79cd\u65b9\u6cd5\u5408\u6210\u915a\u6c27\u70ef\u57fa\u919a\u7c7b\u5316\u5408\u7269\uff0c\u4f46\u901a\u8fc7\u91d1\u5c5e\u50ac\u5316C-H\u952e\u6d3b\u5316\u7b56\u7565\u76f4\u63a5\u5b9e\u73b0\u915a\u548c\u4e19\u70ef\u9178\u916f\u7c7b\u884d\u751f\u7269\u7684\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u5236\u5907\u76ee\u6807\u5316\u5408\u7269\uff0c\u4ecd\u7136\u662f\u539f\u5b50\u7ecf\u6d4e\u3001\u526f\u4ea7\u7269\u5c11\u4e14\u65e0\u9700\u9884\u5148\u5bf9\u5e95\u7269\u8fdb\u884c\u9884\u5b98\u80fd\u5316\u7684\u7406\u60f3\u65b9\u6cd5\u3002\u57fa\u4e8e\u915a\u5e95\u7269\u5206\u5b50\u7ed3\u6784\u7684\u7279\u70b9\uff08\u5982\u8f83\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\u548c\u8f83\u5f3a\u7684\u914d\u4f4d\u80fd\u529b\uff09\uff0c\u901a\u8fc7C-H\u952e\u6d3b\u5316\u7b56\u7565\u5b9e\u73b0\u915a\u7f9f\u57fa\u4e0e\u4e19\u70ef\u9178\u916f\u7c7b\u884d\u751f\u7269\u7684\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u5408\u6210\u70ef\u57fa\u919a\u7c7b\u5316\u5408\u7269\u4ecd\u5177\u6709\u6781\u5927\u5730\u6311\u6218\u3002<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong><span style=\"font-size: 18px;\">\u897f\u5357\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662<\/span><\/strong><span style=\"font-size: 18px;\">\u7684<strong>\u8521\u6842\u946b<\/strong>\u526f\u6559\u6388\u8bfe\u9898\u7ec4\u57fa\u4e8e\u4e4b\u524d\u94dc\u50ac\u5316\u6c2e\u6742\u73af\u70ef\u57fa\u5316\u53cd\u5e94\u7684\u7814\u7a76\uff08<em>J. Org. Chem<\/em>., <strong>2016<\/strong>, <em>81<\/em>, 8806\uff09\uff0c\u6700\u8fd1\u62a5\u9053\u4e86<strong>Pd\u50ac\u5316\u915a\u4e0e\u4e19\u70ef\u9178\u916f\u7c7b\u5316\u5408\u7269\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\uff0c\u4ee5\u6c27\u6c14\u4f5c\u4e3a\u552f\u4e00\u7684\u6c27\u5316\u5242\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u915a\u7684\u76f4\u63a5\u70ef\u57fa\u5316<\/strong>\u3002\u4f5c\u8005\u4ee5Pd(OAc)<\/span><span style=\"font-size: 14px;\"><sub>2<\/sub><\/span><span style=\"font-size: 18px;\">\u4f5c\u4e3a\u50ac\u5316\u5242\u3001\u56db\u4e01\u57fa\u6eb4\u5316\u94f5\uff08TBAB\uff09\u4f5c\u4e3a\u6dfb\u52a0\u5242\uff0c\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u5f97\u5230\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\u3002\u8be5\u65b9\u6cd5\u5177\u6709\u5f88\u597d\u7684\u7acb\u4f53\u9009\u62e9\u6027\uff08\u6240\u5f97\u4ea7\u7269\u5168\u90e8\u4e3a<em>E&nbsp;<\/em>\u5f0f\u7ed3\u6784\uff09\u3001\u8f83\u5e7f\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\uff0832\u79cd\u5e95\u7269\uff09\u548c\u8f83\u9ad8\u7684\u5206\u79bb\u6536\u7387\uff08\u6700\u9ad8\u8fbe84%\uff09\u3002\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728<\/span><span style=\"font-size: 16px;\"><em><strong>Chem. Commun.&nbsp;<\/strong><\/em><\/span><span style=\"font-size: 18px;\">\u4e0a\uff0c\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u897f\u5357\u5927\u5b66\u7684\u7855\u58eb\u7814\u7a76\u751f<strong>\u5434\u4e91\u5f6c<\/strong>\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/2-1537926670.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4f5c\u8005\u5728\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u53d1\u73b0\uff1a\u5bf9\u4e8e\u915a\u7c7b\u5e95\u7269\uff0c\u7535\u5b50\u6548\u5e94\u548c\u4f4d\u963b\u6548\u5e94\u5747\u5bf9\u4ea7\u7269\u7684\u6536\u7387\u5177\u6709\u5f88\u5927\u5f71\u54cd\uff1b\u5bf9\u4e8e\u4e19\u70ef\u9178\u916f\u7c7b\u5e95\u7269\uff0c\u867d\u7136\u53cc\u952e\u7684<em>\u03b1<\/em>\u6216<em>\u03b2<\/em>\u53d6\u4ee3\u57fa\u5bf9\u53cd\u5e94\u5f71\u54cd\u5f88\u5927\uff0c\u4f46\u4e0d\u540c\u916f\u5b98\u80fd\u56e2\u4fee\u9970\u7684\u5e95\u7269\u5747\u80fd\u83b7\u5f97\u8f83\u597d\u7684\u6536\u7387\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u8fd8\u53d1\u73b0\u4e59\u57fa\u4e59\u70ef\u57fa\u916e\u4ee5\u53ca\u5929\u7136\u4ea7\u7269\u96cc\u916e\u4e5f\u80fd\u5f88\u597d\u5730\u9002\u7528\u4e8e\u8be5\u53cd\u5e94\uff08\u5206\u79bb\u6536\u7387\u5206\u522b\u4e3a83%\u548c82%\uff09\u3002\u82c4\u9187\u4e5f\u9002\u7528\u4e8e\u8be5\u4f53\u7cfb\uff0c\u4f46\u4ec5\u5f97\u523012%\u7684\u5206\u79bb\u6536\u7387\uff08<strong>\u88681<\/strong>\uff09\u3002<\/span><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/9-1537926671.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: left;\"><span style=\"text-align: justify;font-size: 16px;color: rgb(136, 136, 136);\">\u88681<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u6839\u636e\u5b9e\u9a8c\u7ed3\u679c\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406\u3002\u9996\u5148\u4ed6\u4eec\u8bbe\u8ba1\u4e86\u5411\u53cd\u5e94\u4f53\u7cfb\u4e2d\u52a0\u5165TEMPO (2,2,6,6-\u56db\u7532\u57fa\u54cc\u5576\u6c27\u5316\u7269) \u6216\u6297\u574f\u8840\u9178\u7684\u80cc\u666f\u5b9e\u9a8c\uff08<strong>\u53cd\u5e94\u5f0f1<\/strong>\uff09\uff0c\u6392\u9664\u4e86\u81ea\u7531\u57fa\u53cd\u5e94\u5386\u7a0b\uff1b\u968f\u540e\u53c8\u901a\u8fc73-\u82ef\u6c27\u57fa\u4e19\u9178\u7532\u916f\u5728\u6807\u51c6\u6761\u4ef6\u4e0b\u672a\u5f97\u5230\u76f8\u5e94\u76ee\u6807\u4ea7\u7269\u7684\u80cc\u666f\u5b9e\u9a8c\uff08<strong>\u53cd\u5e94\u5f0f2<\/strong>\uff09\uff0c\u6392\u9664\u4e86\u915a\u4e0e\u70ef\u916f\u7ecf\u5386\u5206\u5b50\u95f4\u7684\u6c27\u6742Michael\u52a0\u6210\/\u5206\u5b50\u5185<em>\u03b1<\/em>\uff0c<em>\u03b2<\/em>-\u8131\u6c22\u7684\u4e32\u8054\u8fc7\u7a0b\uff1b\u4ed6\u4eec\u8fdb\u4e00\u6b65\u8003\u5bdf\u8fc7\u91cfTBAB\u7684\u4f5c\u7528\uff08<strong>\u56fe1<\/strong>\uff09\uff0c\u8fc7\u91cf\u7684TBAB\u53ef\u8c03\u63a7\u5e95\u7269\u915a\u4e0e\u94af\u50ac\u5316\u5242\u7684\u5f3a\u914d\u4f4d\u80fd\u529b\uff0c\u907f\u514d\u50ac\u5316\u5242\u5931\u6d3b\u3002\u53cd\u5e94\u7684\u53ef\u80fd\u673a\u7406\u662f\uff1aPd(OAc<span style=\"text-align: justify;font-size: 18px;\">)<\/span><span style=\"text-align: justify;font-size: 14px;\"><sub>2<\/sub><\/span>\u5148\u4e0e\u70ef\u70c3\u914d\u4f4d\u5f97\u5230\u6d3b\u6027\u94af\u7269\u79cd<strong>I<\/strong>\uff1b\u7edc\u5408\u7269<strong>I<\/strong>\u53d7\u5230\u82ef\u915a\u4eb2\u6838\u8fdb\u653b\u5f97\u5230\u4e2d\u95f4\u4f53<strong>II<\/strong>\uff0c\u8be5\u53cd\u5e94\u4e3a\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u4e2d\u7684\u7b2c\u56db\u7c7b\u57fa\u5143\u53cd\u5e94(\u4e0e\u91d1\u5c5e\u952e\u5408\u7684\u914d\u4f53\u53d1\u751f\u53cd\u5e94)\uff1b\u968f\u540e\u5728\u78b1\u7684\u4f5c\u7528\u4e0b\u6d88\u9664\u8d28\u5b50\u5e76\u8fdb\u884c\u987a\u5f0f\u7684<em>\u03b2<\/em>-H\u6d88\u9664\u5f97\u5230\u76ee\u6807\u5316\u5408\u7269\uff0c\u5e76\u91ca\u653e\u51faHPd<\/span><span style=\"font-size: 14px;\"><sup>II<\/sup><\/span><span style=\"font-size: 18px;\">X\u7269\u79cd\uff0c\u5728\u78b1\u7684\u4f5c\u7528\u4e0bP<span style=\"text-align: justify;font-size: 18px;\">d<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>II<\/sup><\/span>-H\u7269\u79cd\u8fdb\u4e00\u6b65\u8fd8\u539f\u6d88\u9664\u4e3aPd<\/span><span style=\"font-size: 14px;\"><sup>0<\/sup><\/span><span style=\"font-size: 18px;\">\u7269\u79cd\uff1b\u800cP<span style=\"text-align: justify;font-size: 18px;\">d<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>0<\/sup><\/span>\u7269\u79cd\u5728\u6c27\u6c14\u7684\u4f5c\u7528\u4e0b\u53c8\u53ef\u4ee5\u6c27\u5316\u4e3aP<span style=\"text-align: justify;font-size: 18px;\">d<\/span><span style=\"text-align: justify;font-size: 14px;\"><sup>II<\/sup><\/span>\u7269\u79cd\uff0c\u4ece\u800c\u5b9e\u73b0\u94af\u50ac\u5316\u5242\u7684\u5faa\u73af\uff08<strong>\u8868 2<\/strong>\uff09\u3002\u5728\u8be5\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u76ee\u6807\u4ea7\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u4e3b\u8981\u53d7\u5230\u4e2d\u95f4\u4f53<strong>II<\/strong>\u7684\u63a7\u5236\u3002<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong><span style=\"font-size: 18px;\">\u53cd\u5e94\u5f0f1<\/span><\/strong><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/9-1537926672.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: normal;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong><span style=\"font-size: 18px;\">\u53cd\u5e94\u5f0f2<\/span><\/strong><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/10-1537926672.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p><br  \/><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/0-1537926672.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/5-1537926673.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;\"><span style=\"text-align: justify;font-size: 16px;color: rgb(136, 136, 136);\">\u56fe 1<\/span><\/p>\n<p><span style=\"font-size: 18px;text-align: justify;\"><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><br  \/><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/9-1537926673.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u88682<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u8be5\u8bfe\u9898\u7ec4\u57fa\u4e8eC-H\u952e\u6d3b\u5316\u7b56\u7565\uff0c\u53d1\u5c55\u4e86Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u53cd\u5e94\uff0c\u4e00\u6b65\u6784\u5efaC(sp<\/span><span style=\"font-size: 14px;\"><sup>2<\/sup><\/span><span style=\"font-size: 18px;\">)-O\u952e\u3002\u8be5\u53cd\u5e94\u5177\u6709\u6761\u4ef6\u6e29\u548c\u3001\u540e\u5904\u7406\u7b80\u5355\u3001\u539f\u6599\u5ec9\u4ef7\u6613\u5f97\u548c\u6c27\u6c14\u4f5c\u4e3a\u552f\u4e00\u7ecf\u6d4e\u7684\u6c27\u5316\u5242\u7b49\u4f18\u70b9\uff1b\u8be5\u53cd\u5e94\u4e5f\u5177\u6709\u8f83\u9ad8\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u53ef\u6709\u6548\u5730\u5f97\u5230\u591a\u79cd\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\uff08\u5305\u62ec\u5929\u7136\u4ea7\u7269\u96cc\u916e\u7684\u70ef\u57fa\u919a\u884d\u751f\u7269\uff09\uff0c\u4e3a\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u65b0\u9896\u7684\u65b9\u6cd5\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u5317\u4eac\u5206\u5b50\u79d1\u5b66\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5f00\u653e\u8bfe\u9898\u57fa\u91d1\uff08BNLMS 20140130\uff09\u548c\u4e2d\u592e\u9ad8\u6821\u57fa\u672c\u79d1\u7814\u4e1a\u52a1\u8d39\u4e13\u9879\u8d44\u91d1\uff08XDJK 2017B015\uff09\u7b49\u7684\u5927\u529b\u652f\u6301\u3002<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong><span style=\"font-size: 16px;\">\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong><span style=\"font-size: 16px;\">Yun-Bin Wu, Dan Xie, Zhong-Lin Zang, Cheng-He Zhoua and Gui-Xin Cai<\/span><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n<p><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/10-1537926673.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Palladium-catalyzed aerobic regio- and stereo-selective olefination reactions of phenols and acrylates <em>via<\/em> direct dehydrogenative C(sp<\/span><span style=\"font-size: 12px;\"><sup>2<\/sup><\/span><span style=\"font-size: 14px;\">)\u2013O cross-coupling<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">Chem. Commun<\/span><\/em><span style=\"font-size: 14px;\">., <strong>2018<\/strong>, <em>54<\/em>, 4437, DOI: 10.1039\/C8CC01226A<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: center;line-height: 1.75em;\"><strong><span style=\"font-size: 18px;\">\u8521\u6842\u946b\u535a\u58eb\u7b80\u4ecb<\/span><\/strong><\/p>\n<p style=\"text-align: center;line-height: normal;\"><strong><span style=\"font-size: 18px;\"><br  \/><\/span><\/strong><\/p>\n<p style=\"text-align: center;\"><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/2-1537926673.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u8521\u6842\u946b\uff0c\u897f\u5357\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u526f\u6559\u6388\u3001\u7855\u58eb\u751f\u5bfc\u5e08\uff1b2009\u5e74\u4e8e\u5317\u4eac\u5927\u5b66\u53d6\u5f97\u6709\u673a\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff08\u535a\u58eb\u5bfc\u5e08\uff1a\u65bd\u7ae0\u6770\u6559\u6388\uff09\uff0c2009\u5e74\u81f32011\u5e74\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u82cf\u5dde\u7eb3\u7c73\u6280\u672f\u4e0e\u7eb3\u7c73\u4eff\u751f\u7814\u7a76\u6240\u5de5\u4f5c\uff0c2011\u5e7411\u6708\u8d77\u5c31\u804c\u4e8e\u897f\u5357\u5927\u5b66\uff1b\u76ee\u524d\u7814\u7a76\u9886\u57df\u4e4b\u4e00\u662f\u6709\u673a\u65b9\u6cd5\u5b66\u7814\u7a76\uff08\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5076\u8054\u53cd\u5e94\u4e0e\u7eff\u8272\u5408\u6210\uff09\uff0c\u53e6\u4e00\u7814\u7a76\u9886\u57df\u662f\u4e0e\u897f\u5357\u5927\u5b66\u5468\u6210\u5408\u6559\u6388\u5408\u4f5c\u4ece\u4e8b\u836f\u7269\u5316\u5b66\u7814\u7a76\uff08\u53d1\u5c55\u542b\u6c2e\u6742\u73af\u5316\u5408\u7269\u7684\u9ad8\u6548\u5408\u6210\u53ca\u5176\u751f\u7269\u6d3b\u6027\u8bc4\u4ef7\uff09\uff1b\u76ee\u524d\u5df2\u5728<em>J. Am. Chem. Soc.\u3001Org. Lett.\u3001Chem. Commun.\u3001J. Org. Chem.\u3001Org. Biomol. Chem.\u3001Sci. Rep.\u3001Eur. J. Med. Chem.\u3001Bioorg. Med.\u3001Chem. Lett.<\/em>\u548c\u300a\u4e2d\u56fd\u79d1\u5b66\uff1a\u5316\u5b66\u300b\u7b49\u53d1\u8868\u4e8c\u5341\u591a\u7bc7\u8bba\u6587\uff0c\u4f5c\u4e3a\u7b2c\u4e00\u53d1\u660e\u4eba\u83b7\u6388\u6743\u4e13\u52292\u9879\uff1b\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u5317\u4eac\u5206\u5b50\u79d1\u5b66\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u5f00\u653e\u8bfe\u9898\u548c\u4e2d\u592e\u9ad8\u6821\u57fa\u672c\u79d1\u7814\u4e1a\u52a1\u8d39\u4e13\u9879\u8d44\u91d1\u7b49\u9879\u76ee\u51715\u9879\u3002<\/span><\/p>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"font-size: 18.018px;\"><\/a><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"font-size: 18.018px;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 558px;top: auto;left: auto;right: auto;bottom: auto;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/2-1537926673-1.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/span><\/a><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/7-1537926674.png\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"display: inline-block;color: transparent;clear: both;box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;word-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n<p style=\"box-sizing: border-box;\"><br style=\"box-sizing: border-box;\"  \/><\/p>\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\"><span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">\u957f\u6309<\/strong><\/span>\u4e0b\u56fe<strong style=\"box-sizing: border-box;\">\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<p style=\"margin-top: 10px;margin-bottom: 10px;text-align: center;box-sizing: border-box;\"><img class=\"\"     style=\"vertical-align: middle;box-sizing: border-box;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/09\/8-1537926674.jpeg\" alt=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\" title=\"\u3010\u6709\u673a\u3011Pd\u50ac\u5316\u915a\u4e0e\u8d2b\u7535\u5b50\u70ef\u70c3\u7684\u76f4\u63a5\u4ea4\u53c9\u8131\u6c22\u5076\u8054\u6784\u5efaE-\u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\"  \/><\/p>\n<\/section>\n<\/section>\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-bottom: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-bottom: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section style=\"white-space: normal;\">\n<section >\n<section>\n<section>\n<section>\n<section >\n<section>\n<section>\n<p style=\"text-align: center;\"><br  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;word-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 18px;box-sizing: border-box !important;word-wrap: break-word !important;\">\u70b9\u51fb\u201c<span style=\"max-width: 100%;color: rgb(0, 122, 170);\">\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b&nbsp;<strong>\u5316\u5b66 \u2022 \u6750\u6599&nbsp;<\/strong>\u9886\u57df<span style=\"max-width: 100%;background-color: rgb(255, 218, 81);\">\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;overflow-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 14px;box-sizing: border-box !important;word-wrap: break-word !important;\"><\/span><\/p>\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u200d\u200d\u200d \u70ef\u57fa\u915a\u919a\u7c7b\u5316\u5408\u7269\u662f\u836f\u7269\u548c\u529f\u80fd\u6750\u6599\u4e2d\u91cd\u8981\u7684\u7ed3\u6784\u5355\u5143\u4e4b\u4e00\u3002\u5c3d\u7ba1\u76ee\u524d\u4eba\u4eec\u5df2\u7ecf\u53d1\u5c55\u4e86\u591a\u79cd\u65b9\u6cd5\u5408\u6210\u915a\u6c27\u70ef\u57fa\u919a\u7c7b\u5316 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":48642,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48641"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=48641"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48641\/revisions"}],"predecessor-version":[{"id":48656,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48641\/revisions\/48656"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/48642"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=48641"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=48641"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=48641"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}