{"id":48893,"date":"2018-09-18T01:00:00","date_gmt":"2018-09-26T01:52:55","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/26\/nat-energy%ef%bc%9a%e4%bb%a5%e8%8a%b4%e4%b8%ba%e7%ab%af%e5%9f%ba%e7%9a%84%e7%a9%ba%e7%a9%b4%e4%bc%a0%e8%be%93%e6%9d%90%e6%96%99%ef%bc%8c%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5\/"},"modified":"2018-09-26T09:52:58","modified_gmt":"2018-09-26T01:52:58","slug":"nat-energy%ef%bc%9a%e4%bb%a5%e8%8a%b4%e4%b8%ba%e7%ab%af%e5%9f%ba%e7%9a%84%e7%a9%ba%e7%a9%b4%e4%bc%a0%e8%be%93%e6%9d%90%e6%96%99%ef%bc%8c%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/48893\/","title":{"rendered":"Nat. Energy\uff1a\u4ee5\u82b4\u4e3a\u7aef\u57fa\u7684\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u521b\u65b0\u9ad8"},"content":{"rendered":"
\n

\u200d\u200d<\/span>\u200d<\/a>\"Nat.<\/span><\/a><\/span><\/a><\/p>\n


<\/p>\n

\u5728\u8fc7\u53bb\u51e0\u5e74\u4e2d\uff0c\u6709\u673a-\u65e0\u673a\u6df7\u5408\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/strong>\uff08PSC\uff09\u7531\u4e8e\u826f\u597d\u7684\u5149\u7269\u7406\u7279\u6027\u3001\u8f83\u4f4e\u5236\u9020\u6210\u672c\u4ee5\u53ca\u8f83\u9ad8\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\uff08PCE\uff09\u7b49\u4f18\u70b9\uff0c\u5f15\u8d77\u56fd\u5185\u5916\u79d1\u5b66\u5bb6\u7684\u5e7f\u6cdb\u5173\u6ce8\u548c\u7814\u7a76\uff0c\u6587\u732e\u62a5\u9053\u7684PCE\u5df2\u7ecf\u8d85\u8fc722%\u3002\u76ee\u524d\u5e38\u7528\u7684\u9ad8\u6548PSC\u662f\u5305\u542bn-\u578b\u4ecb\u5b54\u7ed3\u6784TiO<\/span>2<\/sub><\/span>\u548cp-\u578bspiro-OMeTAD\uff08\u6216\u8005PTAA\uff09\u7684\u5668\u4ef6\u7ed3\u6784\u3002\u5149\u5438\u6536\u5c42\u4e00\u822c\u9009\u7528FA-\u9633\u79bb\u5b50\u9499\u949b\u77ff\u6750\u6599\u3002\u4e3a\u4e86\u63d0\u9ad8\u5668\u4ef6\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027\uff0c\u5728\u9499\u949b\u77ff\u6750\u6599\u4e2d\u5f15\u5165\u4e86Cs\u6216\u8005Rb\u3002\u7136\u800c\uff0c\u9664\u4e86\u9499\u949b\u77ff\u5c42\u4e4b\u5916\uff0c\u754c\u9762\u6750\u6599\u5904\u7684\u80fd\u91cf\u635f\u5931\u662f\u9650\u5236\u5668\u4ef6\u5f00\u8def\u7535\u538b\uff08V<\/span>oc<\/sub><\/span>\uff09\u7684\u91cd\u8981\u56e0\u7d20\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u9009\u7528\u5177\u6709\u5408\u9002\u80fd\u7ea7\u4ee5\u53ca\u7535\u8377\u4f20\u8f93\u80fd\u529b\u7684\u754c\u9762\u4f20\u8f93\u6750\u6599\u6765\u589e\u5927\u5668\u4ef6\u7684\u5185\u5efa\u7535\u52bf\u548c\u63d0\u9ad8V<\/span>oc<\/sub><\/span>\uff0c\u662f\u589e\u5927PSC\u5668\u4ef6\u6548\u7387\u7684\u6709\u6548\u9014\u5f84\u3002<\/span><\/p>\n


<\/p>\n

\u6700\u8fd1\uff0c\u97e9\u56fd\u5316\u5b66\u6280\u672f\u7814\u7a76\u6240<\/strong>\uff08KRICT\uff09\u7684Jangwon Seo<\/strong>\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u4e2a\u4ee5\u82b4\u4e3a\u7ec8\u7aef\u7684\u5177\u6709\u9ad8\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u7684\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\uff08HTM\uff09DM<\/strong>\uff08\u56fe1\uff09\u3002\u4ed6\u4eec\u5c06\u8be5\u6750\u6599\u5e94\u7528\u5230\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u4e2d\u5f97\u5230\u4e86\u6700\u9ad823.2%\u7684\u5668\u4ef6\u6548\u7387\uff0c\u7a33\u5b9a\u5c0f\u9762\u79ef\u5668\u4ef6\uff08\u7ea60.094 cm<\/span>2<\/sup><\/span>\uff09\u6548\u7387\u53ef\u8fbe22.85%\uff0c\u5927\u9762\u79ef\u5668\u4ef6\uff08\u7ea61 cm<\/span>2<\/sup><\/span>\uff09\u6548\u7387\u53ef\u8fbe21.7%\u3002\u4f5c\u8005\u8fd8\u53d1\u73b0\u8be5\u5668\u4ef6\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u572860 \u2103\u4e0b500 h\u4ecd\u80fd\u4fdd\u630195%\u7684\u5668\u4ef6\u6548\u7387\u3002<\/span><\/p>\n

\"Nat.<\/p>\n

\u56fe1. HTM\u7684\u5149\u5b66\u3001\u7535\u5316\u5b66\u4ee5\u53ca\u70ed\u6027\u80fd\u3002\u56fe\u7247\u6765\u6e90\uff1aNat. Energy<\/em><\/span><\/p>\n


<\/p>\n

\u4e3a\u4e86\u8bc4\u4f30DM\u4f5c\u4e3a\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u7684\u80fd\u529b\uff0c\u4f5c\u8005\u5236\u5907\u4e86bl-TiO<\/span>2<\/sub><\/span> \/ mp-TiO<\/span>2<\/sub><\/span> \/ (FAPbI<\/span>3<\/sub><\/span>)<\/span>0.95<\/sub><\/span>(MAPbBr<\/span>3<\/sub><\/span>)<\/span>0.05<\/sub><\/span> \/ HTM \/ Au\u5668\u4ef6\uff0c\u5668\u4ef6\u7684SEM\u5256\u9762\u56fe\u5982\u56fe2a\u6240\u793a\u3002DM\u4f5cHTM\u65f6\uff0c\u6700\u597d\u7684\u5668\u4ef6\u6548\u7387\u662f23.2%\uff08\u56fe2b\uff09\uff0c\u6b63\u53cd\u626b\u4ec5\u6709\u5f88\u8f7b\u5fae\u7684\u8fdf\u6ede\u73b0\u8c61\u3002\u6b64\u5916\u4f5c\u8005\u8fd8\u5236\u5907\u4e86\u5927\u9762\u79ef\u5668\u4ef6\uff080.991 cm<\/span>2<\/sup><\/span>\uff09\uff0c\u5668\u4ef6\u6027\u80fd\u4f18\u826f\uff08\u56fe2c\uff09\u3002\u4f5c\u8005\u8ba4\u8bc1\u7684\u5927\u9762\u79ef\u5668\u4ef6\uff081 \u00d7 1 cm<\/span>2<\/sup><\/span>\uff09\u6548\u7387\u9ad8\u8fbe20.9%\uff0c\u8fd9\u662f\u76ee\u524d\u62a5\u9053\u7684\u6700\u9ad8\u6548\u7387\u3002<\/span><\/p>\n

\"Nat.<\/p>\n

\u56fe2. DM\u4f5c\u4e3aHTMs\u65f6\u7684\u5668\u4ef6\u6027\u80fd\u3002\u56fe\u7247\u6765\u6e90\uff1aNat. Energy<\/em><\/span><\/p>\n


<\/p>\n

\u4f5c\u8005\u901a\u8fc7\u4e0d\u65ad\u8c03\u8282\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e2d\u6dfb\u52a0\u5242\u7684\u91cf\uff0c\u5f97\u5230\u4e86\u6700\u4f18\u5668\u4ef6\u6027\u80fd22.3%\uff08\u89c1\u56fe3a\uff09\uff0c\u4e0d\u540c\u6dfb\u52a0\u5242\uff0c\u5668\u4ef6\u6548\u7387\u5206\u5e03\u5982\u56fe2e\u3002\u4ece\u5668\u4ef6\u7684\u80fd\u7ea7\u56fe\uff08\u56fe3b\uff09\u53ef\u4ee5\u770b\u51fa\u4e0espiro-OMeTAD\u76f8\u6bd4\uff0cDM\u5177\u6709\u66f4\u6df1\u7684HOMO\u80fd\u7ea7\uff08\u7ea60.0 5eV\uff09\uff0c\u8fd9\u4e0e\u56fe3c\u4e2dV<\/span>oc<\/sub><\/span>\u7684\u5206\u5e03\u8d8b\u52bf\u662f\u4e00\u81f4\u7684\uff0c\u8fd9\u8bf4\u660e\u5f53\u7528DM\u53d6\u4ee3spiro-OMeTAD\u65f6\u5668\u4ef6\u53ef\u4ee5\u83b7\u5f97\u66f4\u9ad8\u7684\u5185\u5efa\u7535\u52bf\u3002<\/span><\/p>\n

\"Nat.<\/p>\n

\u56fe3. \u4e0d\u540cHTMs\u7684\u9499\u949b\u77ff\u7535\u6c60\u7684\u5668\u4ef6\u7ed3\u6784\u4ee5\u53ca\u5668\u4ef6\u6027\u80fd\u3002\u56fe\u7247\u6765\u6e90\uff1aNat. Energy<\/em><\/span><\/p>\n


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\u4e3a\u4e86\u9a8c\u8bc1DM\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u4f5c\u8005\u505a\u4e86\u4e00\u7cfb\u5217\u6d4b\u8bd5\uff08\u56fe4\uff09\u3002\u4f5c\u8005\u5206\u522b\u5bf9\u7eafDM\u548c\u52a0\u5165\u6dfb\u52a0\u5242\u7684DM\u8fdb\u884c\u4e86DSC\u626b\u63cf\uff08\u56fe4a\uff09\uff0c\u53d1\u73b0\u52a0\u5165\u6dfb\u52a0\u5242\u540e\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08T<\/span>g<\/sub><\/span>\uff09\u7531161 \u2103\u4e0b\u964d\u523090 \u2103\u3002\u636e\u6587\u732e\u62a5\u9053spiro-OMeTAD\u4e5f\u8868\u73b0\u51fa\u76f8\u4f3c\u7684\u884c\u4e3a\uff0c\u52a0\u5165\u6dfb\u52a0\u5242\u540eT<\/span>g<\/sub><\/span>\u7531120 \u2103\u4e0b\u964d\u523050 \u2103\uff0c\u56e0\u6b64\u57fa\u4e8espiro-OMeTAD\u7684\u5668\u4ef6\u753160 \u2103\u52a0\u70ed\u523080 \u2103\u65f6\u6548\u7387\u6025\u5267\u4e0b\u964d\uff08\u56fe4b\uff09\u3002\u800cDM\u5668\u4ef6\u867d\u7136\u52a0\u70ed\u523080 \u2103\u540e\u6709\u8f7b\u5fae\u8870\u51cf\uff0c\u4f46\u662f\u8868\u73b0\u51fa\u4e86\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002\u572860 \u2103\u4e0b\u52a0\u70ed500 h\u540e\uff0c\u5668\u4ef6\u6548\u7387\u4ecd\u80fd\u4fdd\u630195%\uff08\u56fe4c\uff09\u3002<\/span><\/p>\n

\"Nat.<\/p>\n

\u56fe4. \u5668\u4ef6\u7684\u70ed\u548c\u5149\u4f0f\u7a33\u5b9a\u6027\u3002\u56fe\u7247\u6765\u6e90\uff1aNat. Energy<\/em><\/span><\/p>\n


<\/p>\n

\u4e3a\u4e86\u5b9e\u73b0\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u5546\u4e1a\u5316\u5e94\u7528\uff0c\u9ad8\u6548\u7387\u4ee5\u53ca\u957f\u671f\u7684\u7a33\u5b9a\u6027\u90fd\u4e0d\u53ef\u7f3a\u5c11\u3002\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u4f5c\u8005\u901a\u8fc7\u5f15\u5165\u82b4\u7aef\u57fa\uff0c\u5bf9spiro-OMeTAD\u8fdb\u884c\u4e86\u6709\u6548\u7684\u4fee\u9970\uff0c\u660e\u663e\u63d0\u9ad8\u4e86\u70ed\u7a33\u5b9a\u6027\u3002\u4f46\u662f\u8fd9\u4e2a\u6750\u6599\u4ecd\u7136\u6ca1\u6709\u6446\u8131\u6dfb\u52a0\u5242\uff0c\u6211\u4eec\u90fd\u77e5\u9053\uff0c\u8c03\u63a7HTM\u4e2d\u6dfb\u52a0\u5242\u7684\u91cf\u4e0d\u5229\u4e8e\u5546\u4e1a\u5316\u5927\u9762\u79ef\u751f\u4ea7\uff0c\u6b64\u5916\u6dfb\u52a0\u5242\u5bf9\u5668\u4ef6\u957f\u671f\u7684\u7a33\u5b9a\u6027\u4e5f\u6709\u5f71\u54cd\u3002\u4f46\u65e0\u8bba\u5982\u4f55\uff0c\u8fd9\u4e00\u7814\u7a76\u4f7f\u5f97\u6211\u4eec\u5728\u9499\u949b\u77ff\u7535\u6c60\u5546\u4e1a\u5316\u5e94\u7528\u7684\u9053\u8def\u4e0a\u53c8\u524d\u8fdb\u4e86\u4e00\u6b65\u3002<\/span><\/p>\n


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\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"Nat.<\/p>\n

A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells<\/span><\/p>\n

Nat. Energy<\/span><\/em>, 2018<\/strong>, 3<\/em>, 682, DOI: 10.1038\/s41560-018-0200-6<\/span><\/p>\n


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<\/a>\"Nat.<\/span><\/a><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n


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\"Nat.<\/p>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n


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\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\"Nat.<\/p>\n<\/section>\n<\/section>\n

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\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

<\/span><\/p>\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"

\u200d\u200d\u200d \u5728\u8fc7\u53bb\u51e0\u5e74\u4e2d\uff0c\u6709\u673a-\u65e0\u673a\u6df7\u5408\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7531\u4e8e\u826f\u597d\u7684\u5149\u7269\u7406\u7279\u6027\u3001\u8f83\u4f4e\u5236\u9020\u6210\u672c\u4ee5\u53ca\u8f83\u9ad8\u7684\u80fd\u91cf […]<\/p>\n","protected":false},"author":1,"featured_media":48894,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48893"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=48893"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48893\/revisions"}],"predecessor-version":[{"id":48904,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48893\/revisions\/48904"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/48894"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=48893"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=48893"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=48893"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}