{"id":48915,"date":"2018-09-18T01:00:00","date_gmt":"2018-09-26T01:53:05","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/26\/%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91%e8%b0%a2%e5%8a%b2%e3%80%81%e6%9c%b1%e6%88%90%e5%bb%ba%e5%9b%a2%e9%98%9f%e5%9c%a8%e5%8f%8c%e6%a0%b8%e9%94%b0%e5%82%ac%e5%8c%96%e7%82%94%e7%83%83%e9%80%89%e6%8b%a9\/"},"modified":"2018-09-26T09:53:11","modified_gmt":"2018-09-26T01:53:11","slug":"%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91%e8%b0%a2%e5%8a%b2%e3%80%81%e6%9c%b1%e6%88%90%e5%bb%ba%e5%9b%a2%e9%98%9f%e5%9c%a8%e5%8f%8c%e6%a0%b8%e9%94%b0%e5%82%ac%e5%8c%96%e7%82%94%e7%83%83%e9%80%89%e6%8b%a9","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/48915\/","title":{"rendered":"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"
\n

\u200d\u200d<\/span>\u200d<\/a>\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/span><\/a><\/span><\/a><\/p>\n


<\/p>\n

\u5171\u8f6d\u70ef\u7094\u662f\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5929\u7136\u4ea7\u7269\u53ca\u751f\u7269\u6d3b\u6027\u5206\u5b50\u4e2d\u7684\u7ed3\u6784\u5355\u5143\uff0c\u4e5f\u662f\u6709\u673a\u5408\u6210\u4e2d\u91cd\u8981\u7684\u5408\u6210\u780c\u5757\u3002\u7136\u800c\uff0c\u4fbf\u6377\u5e76\u5177\u6709\u9009\u62e9\u6027\u7684\u5408\u6210\u7b56\u7565\u4e00\u76f4\u662f\u6709\u673a\u5408\u6210\u9886\u57df\u7684\u4e00\u5927\u96be\u9898\u3002\u5c31\u4f20\u7edf\u5de5\u827a\u800c\u8a00\uff0c\u7094\u70c3\u7684\u4e8c\u805a\u53cd\u5e94\u3001\u7094\u70c3\u4e0e\u70ef\u70c3\u884d\u751f\u7269\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u867d\u7136\u53ef\u4ee5\u5f97\u5230\u5171\u8f6d\u70ef\u7094\uff0c\u4f46\u5bb9\u6613\u4f34\u968f\u4e00\u7cfb\u5217\u5f02\u6784\u4f53\u7684\u6df7\u5408\u7269\u3002\u56e0\u800c\uff0c\u53d1\u5c55\u5177\u6709\u533a\u57df\u3001\u7acb\u4f53\u9009\u62e9\u6027\u7684\u5171\u8f6d\u70ef\u7094\u5408\u6210\u65b9\u6cd5\u6709\u7740\u91cd\u8981\u610f\u4e49\u3002\u9530\u662f\u5730\u58f3\u4e2d\u542b\u91cf\u6392\u7b2c\u4e09\u4f4d\u7684\u8fc7\u6e21\u91d1\u5c5e\uff0c\u5176\u5ec9\u4ef7\u548c\u4f4e\u6bd2\u7684\u7279\u70b9\u8fd1\u5e74\u6765\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u9886\u57df\u9887\u53d7\u5173\u6ce8\u3002\u4f46\u7531\u4e8e\u5176\u8f83\u4f4e\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u9530\u50ac\u5316\u53c2\u4e0e\u7684\u8bb8\u591a\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u7684\u57fa\u672c\u79d1\u5b66\u95ee\u9898\u4ecd\u5c5e\u4e8e\u7a7a\u767d\u9886\u57df\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n


<\/p>\n

\u6700\u8fd1\uff0c\u5357\u4eac\u5927\u5b66<\/strong>\u8c22\u52b2\u3001\u6731\u6210\u5efa<\/strong>\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u53cc\u6838\u9530\u50ac\u5316\u5b9e\u73b0\u4e86\u975e\u5bf9\u79f0\u5171\u8f6d\u4e8c\u7094\u7684\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53cd\u5e94<\/strong>\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u5728Angew. Chem. Int. Ed.<\/strong><\/em>\uff0c2015\u7ea7\u535a\u58eb\u751f\u71d5\u4e2d\u98de<\/strong>\u662f\u8be5\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u8c22\u52b2<\/strong>\u526f\u6559\u6388\u4e3a\u8be5\u6587\u7684\u901a\u8baf\u4f5c\u8005\u3002<\/span><\/p>\n


<\/p>\n

\u975e\u5bf9\u79f0\u5171\u8f6d\u4e8c\u7094\u9009\u62e9\u6027\u6c22\u82b3\u5316<\/span><\/strong><\/p>\n


<\/p>\n

\u82b3\u57fa\u787c\u9178\u5177\u6709\u7279\u5f02\u7684\u53cd\u5e94\u6d3b\u6027\u3001\u7a33\u5b9a\u6027\u3001\u6613\u5f97\u6027\u3001\u6613\u64cd\u4f5c\u6027\uff0c\u662f\u4e00\u7c7b\u975e\u5e38\u91cd\u8981\u5e76\u6709\u7740\u5e7f\u6cdb\u5408\u6210\u5e94\u7528\u7684\u82b3\u57fa\u6e90\u3002\u7531\u4e8e\u975e\u87af\u5408\u7684\u591a\u7fb0\u57fa\u82b3\u57faMn\u5316\u5408\u7269\u6d3b\u6027\u975e\u5e38\u9ad8\uff0c\u5bb9\u6613\u53d1\u751f\u5206\u5b50\u5185\u7684\u8fc1\u79fb\u91cd\u6392\u53cd\u5e94\uff1b\u800c\u9ad8\u4ef7Mn\u50ac\u5316\u5242\u5bb9\u6613\u4e0e\u82b3\u57fa\u787c\u9178\u53d1\u751f\u5355\u7535\u5b50\u6c27\u5316\u5f62\u6210\u76f8\u5e94\u7684\u82b3\u57fa\u81ea\u7531\u57fa\u3002\u56e0\u6b64\uff0cMn\u50ac\u5316\u7684\u82b3\u57fa\u787c\u9178\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u4ecd\u7136\u662fMn\u50ac\u5316\u9886\u57df\u7684\u4e00\u5927\u6311\u6218\u3002\u8c22\u52b2\u3001\u6731\u6210\u5efa\u7814\u7a76\u56e2\u961f\u63d0\u51fa\u4e86\u901a\u8fc7\u53cc\u6838Mn\u50ac\u5316\u4ea7\u751f\u66f4\u9ad8\u6d3b\u6027\u7684\u82b3\u57fa\u9530\u7269\u79cd\uff0c\u76f4\u63a5\u4e0e1,3-\u5171\u8f6d\u4e8c\u7094\u914d\u4f4d\uff0c\u5b9e\u73b0\u4e86\u533a\u57df\u3001\u7acb\u4f53\u548c\u5316\u5b66\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53cd\u5e94\uff0c\u6210\u529f\u5b8c\u6210\u4e86(Z)-\u6784\u578b\u5171\u8f6d\u7094\u70ef\u7684\u5236\u5907\uff08Scheme 1\uff09\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

Scheme 1<\/span><\/p>\n


<\/p>\n

\u9996\u5148\uff0c\u4f5c\u8005\u8003\u5bdf\u4e86\u51e0\u4e2a\u5e26\u6709\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u53d6\u4ee31,3-\u5171\u8f6d\u4e8c\u7094\u6765\u7814\u7a76\u5e95\u7269\u7c7b\u578b\u7684\u9002\u7528\u6027\uff0c\u53d1\u73b0\u4e8c\u7094\u91871c<\/strong>\u53ca\u4e8c\u7094\u919a1d<\/strong>\u53ef\u4ee5\u5728\u03b2-\u78b3\u4e0a\u8fdb\u884c\u82b3\u57fa\u5316\u53cd\u5e94\uff0c\u5f97\u5230\u52a0\u6c22\u82b3\u6784\u5316\u4ea7\u72693c<\/strong>\u548c3d<\/strong>\uff0c\u5176\u5b83\u53d6\u4ee3\u57fa\u7684\u4e8c\u7094\u5219\u4e0d\u80fd\u8fdb\u884c\u53cd\u5e94\u3002\u7528Mn(CO)<\/span>5<\/sub><\/span>Br\u4f5c\u4e3a\u50ac\u5316\u5242\u53ea\u80fd\u5f97\u5230\u75d5\u91cf\u4ea7\u7269\uff0c\u53ef\u4ee5\u770b\u51fa\uff0cMn<\/span>2<\/sub><\/span>(CO)<\/span>8<\/sub><\/span>Br2 <\/sub><\/span>\u662f\u6bd4Mn(CO)<\/span>5<\/sub><\/span>Br\u66f4\u6709\u6548\u7684\u50ac\u5316\u5242\uff08Scheme 2\uff09\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

Scheme 2<\/span><\/p>\n


<\/p>\n

\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u4ee5\u4e8c\u7094\u91871c<\/strong>\u548c\u5bf9\u7532\u57fa\u82ef\u787c\u91782a<\/strong>\u4f5c\u4e3a\u6a21\u677f\u53cd\u5e94\u8fdb\u884c\u4e86\u6761\u4ef6\u7684\u7b5b\u9009\u4e0e\u4f18\u5316\uff0c\u7528Mn<\/span>2<\/sub><\/span>(CO)<\/span>8<\/sub><\/span>Br2<\/sub><\/span><\/span>\u4f5c\u4e3a\u50ac\u5316\u5242\uff0cNaOAc\u4f5c\u4e3a\u78b1\uff0c\u6b63\u5df1\u70f7\u4f5c\u4e3a\u6eb6\u5242\uff0c\u572890 \u00b0C\u7684\u6761\u4ef6\u4e0b\u6700\u7ec8\u4ee5 89 %\u7684\u6536\u7387\u5f97\u5230\u4e86\u5355\u4e00\u533a\u57df\u3001\u7acb\u4f53\u548c\u5316\u5b66\u9009\u62e9\u6027\u7684(Z)-\u6784\u578b\u52a0\u6c22\u82b3\u6784\u5316\u4ea7\u7269\u3002Pd(OAc)2<\/sub><\/span>\u548c[RhCl(COD)]<\/span>2<\/sub><\/span>\u5747\u4e0d\u80fd\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff0c\u4e5f\u8bc1\u660e\u4e86Mn<\/span>2<\/sub><\/span>(CO)<\/span>8<\/sub><\/span>Br2<\/sub><\/span><\/span>\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u4f18\u8d8a\u6027\uff08Table 1\uff09\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n


<\/p>\n

\u968f\u540e\uff0c\u4f5c\u8005\u5bf9\u53cd\u5e94\u7684\u9002\u7528\u6027\u8fdb\u884c\u4e86\u8003\u5bdf\uff0c\u53d1\u73b0\u8be5\u53cd\u5e94\u5177\u6709\u5e7f\u6cdb\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u3002\u5404\u79cd\u82ef\u57fa\u3001\u70f7\u57fa\u548c\u6742\u82b3\u57fa\u7b49\u53d6\u4ee3\u7684\u4e8c\u7094\u9187\u90fd\u53ef\u4ee5\u5f88\u597d\u53c2\u4e0e\u53cd\u5e94\u3002\u8fde\u6709\u4e8c\u8302\u94c1\u7684\u4e8c\u7094\u9187\u4e5f\u53ef\u4ee5\u9002\u7528\u4e8e\u8be5\u53cd\u5e94\uff0c\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7535\u5b50\u6027\u8d28\uff0c\u6240\u5f97\u7684\u4e8c\u8302\u94c1\u57fa\u70ef\u53ef\u80fd\u5728\u6750\u6599\u79d1\u5b66\u4e2d\u5177\u6709\u4e00\u5b9a\u7684\u5e94\u7528\u3002\u53cc\u70f7\u57fa\u4e8c\u7094\u9187\u4e0d\u53d7\u5176\u7a7a\u95f4\u548c\u7535\u5b50\u6548\u5e94\u5f71\u54cd\uff0c\u90fd\u53ef\u4ee5\u987a\u5229\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u3002\u5f53\u542b\u6709\u70ef\u70c3\u548c\u6742\u82b3\u57fa\u7684\u4e8c\u7094\u9187\u8fdb\u884c\u53cd\u5e94\u65f6\uff0c\u53cd\u5e94\u4e5f\u53ef\u4ee5\u987a\u5229\u8fdb\u884c\u800c\u4e0d\u4f1a\u6539\u53d8\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027\u30021, 4-\u4e8c\u7094-3-\u9187\u8fdb\u884c\u53cd\u5e94\u65f6\u4e5f\u4e0d\u53d7\u5f71\u54cd\uff0c\u540c\u65f6\u4e8c\u7094\u919a\u4e5f\u53ef\u4ee5\u6709\u6548\u7684\u8fdb\u884c\u53cd\u5e94\u3002\u4e00\u7cfb\u5217\u5438\u7535\u5b50\u548c\u7ed9\u7535\u5b50\u7684\u90bb\u3001\u95f4\u3001\u5bf9\u4f4d\u53d6\u4ee3\u7684\u82b3\u57fa\u787c\u9178\u548c\u544b\u5583\u3001\u567b\u5429\u3001\u55b9\u5549\u3001\u5421\u5576\u7b49\u53d6\u4ee3\u7684\u6742\u82b3\u57fa\u787c\u9178\u5747\u5177\u6709\u5f88\u597d\u7684\u517c\u5bb9\u6027\uff0c\u5e76\u4ee5\u8f83\u4f18\u4ea7\u7387\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff08Scheme 3\uff09\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

Scheme 3<\/span><\/p>\n


<\/p>\n

\u8be5\u53cd\u5e94\u540c\u6837\u53ef\u4ee5\u9002\u7528\u4e8e\u514b\u7ea7\u53cd\u5e94\u4e14\u4ea7\u7387\u4e0d\u53d7\u5f71\u54cd\uff0c\u4e3a\u540e\u7eed\u5de5\u4e1a\u5316\u751f\u4ea7\u63d0\u4f9b\u4e00\u79cd\u53ef\u80fd\u3002\u53cd\u5e94\u4ea7\u7269\u4e5f\u53ef\u4ee5\u8fdb\u884c\u591a\u6837\u5316\u8f6c\u5316\uff0c\u5feb\u901f\u4ee5\u9ad8\u4ea7\u7387\u8f6c\u5316\u6210\u5bf9\u5e94\u7684\u916f\u3001\u919b\u3001\u5171\u8f6d\u4e8c\u70ef\u7b49\u5176\u5b83\u6709\u7528\u7684\u5316\u5408\u7269\uff08Scheme 4\uff09\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

Scheme 4<\/span><\/p>\n


<\/p>\n

\u57fa\u4e8e\u5b9e\u9a8c\u73b0\u8c61\u548c\u4e00\u7cfb\u5217\u673a\u7406\u7814\u7a76\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u53ef\u80fd\u7684\u673a\u7406\u3002\u9996\u5148\uff0c\u5728NaOAc\u5b58\u5728\u4e0b\uff0cMn<\/span>2<\/sub><\/span>(CO)<\/span>8<\/sub><\/span>Br2<\/sub><\/span><\/span>\u50ac\u5316\u5242\u5f62\u6210\u6d3b\u6027Mn(I)\u7269\u79cd18<\/strong>\uff0c\u7136\u540e\u4e0e\u82b3\u57fa\u787c\u91782a<\/strong>\u8fdb\u884c\u8f6c\u91d1\u5c5e\u5316\uff0c\u751f\u6210Ar-Mn\u4e2d\u95f4\u4f5319<\/strong>\uff0c\u9ad8\u6d3b\u6027\u7a7a\u914d\u4f4d\u7684Ar-Mn\u4e2d\u95f4\u4f5319<\/strong>\u548c1c<\/strong>\u914d\u4f4d\u5f62\u6210\u590d\u5408\u726920<\/strong>\uff0c1c<\/strong>\u4e2d\u7684\u7f9f\u57fa\u4e0eAr-Mn\u4e2d\u7684\u82b3\u57fa\u4e4b\u95f4\u7684\u5f31O-H…\u03c0\u76f8\u4e92\u4f5c\u7528\u4fc3\u8fdb\u03b2-C\u9009\u62e9\u6027\uff0c\u5c06\u90bb\u8fd1\u7f9f\u57fa\u7684\u7094\u70c3\u987a\u5f0f\u63d2\u5165\u5230Ar-Mn\u03c3\u952e\u53ef\u4ee5\u5f97\u5230\u4e2d\u95f4\u4f5321<\/strong>\uff0c\u7094\u57fa\u53ef\u4ee5\u901a\u8fc7\u5171\u8f6d\u6548\u5e94\u7a33\u5b9a\u8be5\u4e2d\u95f4\u4f53\u3002\u6700\u540e\uff0c\u5728\u4e09\u82b3\u57fa\u73af\u787c\u6c27\u70f7\u7269\u79cd\u5f62\u6210\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684H<\/span>2<\/sub><\/span>O\u4e0e\u4e2d\u95f4\u4f5321<\/strong>\u8d28\u5b50\u53bb\u91d1\u5c5e\u5316\u91cd\u65b0\u751f\u6210\u6d3b\u6027Mn(I)\u7269\u79cd18<\/strong>\u548c\u5171\u8f6d\u7094\u70ef3c<\/strong>\uff0c\u7136\u540e\u53cd\u5e94\u5faa\u73af\u8fdb\u884c\uff08Scheme 5\uff09\u3002<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

Scheme 5<\/span><\/p>\n


<\/p>\n

\u603b\u7ed3<\/span><\/strong><\/span><\/p>\n


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\u8c22\u52b2\u8bfe\u9898\u7ec4\u5df2\u7ecf\u53d1\u5c55\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u975e\u5bf9\u79f0\u5171\u8f6d\u4e8c\u7094\u7684\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53cd\u5e94\uff0c\u8be5\u65b9\u6cd5\u4e3a(Z)-\u6784\u578b\u5171\u8f6d\u70ef\u7094\u7684\u6a21\u5757\u5316\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u901a\u7528\u7b56\u7565\uff0c\u4e14\u5177\u6709\u64cd\u4f5c\u7b80\u5355\u3001\u5b98\u80fd\u56e2\u76f8\u5bb9\u6027\u597d\u7b49\u7279\u70b9\uff0c\u5bf9\u5404\u79cd\u91cd\u8981\u7684\u5b98\u80fd\u56e2\u90fd\u5177\u6709\u5f88\u597d\u7684\u8010\u53d7\u6027\u3002\u800c\u4e14\uff0c\u4f4e\u4ef7\u9530\u53c2\u4e0e\u7684\u8f6c\u91d1\u5c5e\u4f5c\u7528\u88ab\u8bc1\u5b9e\uff0c\u8bfe\u9898\u7ec4\u6210\u529f\u5f97\u5230\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u5355\u6676\u7ed3\u6784\u9a8c\u8bc1\u3002\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\uff0c\u4e00\u79cd\u57fa\u4e8e\u201cO-H…\u03c0 interaction\u201d\u7684\u65b0\u578b\u5b9a\u4f4d\u7b56\u7565\u88ab\u9996\u6b21\u5e94\u7528\u5230Mn\u50ac\u5316\u4f53\u7cfb\u4e2d\u3002<\/span><\/p>\n


<\/p>\n

\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong>Zhongfei Yan, Xiang-Ai Yuan, Yue Zhao, Chengjian Zhu, Jin Xie<\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

Selective Hydroarylation of 1,3-Diynes Using a Dimeric Manganese Catalyst: Modular Synthesis of Z<\/em>-Enynes<\/span><\/p>\n

Angew. Chem. Int. Ed.<\/span><\/em>, 2018<\/strong>, DOI: 10.1002\/anie.201807851<\/span><\/p>\n


<\/span><\/p>\n

\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n

\u8c22\u52b2<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/49884<\/span><\/p>\n

\u6731\u6210\u5efa<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/49885<\/span><\/p>\n


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\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n


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\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\"\u3010\u6709\u673a\u3011\u8c22\u52b2\u3001\u6731\u6210\u5efa\u56e2\u961f\u5728\u53cc\u6838\u9530\u50ac\u5316\u7094\u70c3\u9009\u62e9\u6027\u6c22\u82b3\u5316\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\"<\/p>\n<\/section>\n<\/section>\n

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\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

<\/span><\/p>\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"

\u200d\u200d\u200d \u5171\u8f6d\u70ef\u7094\u662f\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5929\u7136\u4ea7\u7269\u53ca\u751f\u7269\u6d3b\u6027\u5206\u5b50\u4e2d\u7684\u7ed3\u6784\u5355\u5143\uff0c\u4e5f\u662f\u6709\u673a\u5408\u6210\u4e2d\u91cd\u8981\u7684\u5408\u6210\u780c\u5757\u3002\u7136\u800c\uff0c\u4fbf\u6377\u5e76\u5177\u6709 […]<\/p>\n","protected":false},"author":1,"featured_media":48916,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48915"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=48915"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48915\/revisions"}],"predecessor-version":[{"id":48930,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/48915\/revisions\/48930"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/48916"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=48915"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=48915"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=48915"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}