{"id":54685,"date":"2018-09-28T01:00:00","date_gmt":"2018-09-30T01:58:01","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/30\/re2o7%e5%82%ac%e5%8c%96%e7%9a%84%e5%8f%8c%e5%88%86%e5%ad%90%e8%84%b1%e6%b0%b4%e5%82%85%e5%85%8b%e5%8f%8d%e5%ba%94\/"},"modified":"2018-09-30T09:58:06","modified_gmt":"2018-09-30T01:58:06","slug":"re2o7%e5%82%ac%e5%8c%96%e7%9a%84%e5%8f%8c%e5%88%86%e5%ad%90%e8%84%b1%e6%b0%b4%e5%82%85%e5%85%8b%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/54685\/","title":{"rendered":"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94"},"content":{"rendered":"
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\u200d\u200d<\/span>\u200d<\/a>\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/span><\/a><\/span><\/a><\/p>\n


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\u6700\u8fd1\uff0c\u7f8e\u56fd\u5339\u5179\u5821\u5927\u5b66<\/strong>\u7684Paul E. Floreancig<\/strong>\u6559\u6388\u548c\u534e\u4e2d\u79d1\u6280\u5927\u5b66<\/strong>\u7684\u8c22\u6709\u4f1f<\/strong>\u6559\u6388\u5408\u4f5c\uff0c\u57fa\u4e8e\u4ee5\u5f80\u53d1\u5c55\u7684Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u50ac\u5316\u70ef\u4e19\u9187\u8f6c\u4f4d\u53cd\u5e94\u7684\u5de5\u4f5c\uff0c\u62a5\u9053\u4e86\u5728Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u50ac\u5316\u6761\u4ef6\u4e0b\uff0c\u82c4\u57fa\u7532\u9187\u53d1\u751f\u6eb6\u5242\u89e3\u5f62\u6210\u76f8\u5e94\u7684\u82c4\u57fa\u6b63\u79bb\u5b50\uff0c\u968f\u540e\u8fdb\u884cFriedel-Crafts\u70f7\u57fa\u5316\u53cd\u5e94\u5f97\u5230\u4e8c\u82b3\u57fa\u7532\u70f7<\/strong>\u3002\u53cd\u5e94\u7684\u50ac\u5316\u5242\u8d1f\u8f7d\u91cf\u4f4e\u3001\u5e95\u7269\u9002\u7528\u8303\u56f4\u5e7f\u3002\u9ad8\u94fc\u9178\u916f\u53ef\u4f5c\u4e3a\u826f\u597d\u7684\u79bb\u53bb\u57fa\u56e2\u4fc3\u8fdb\u53cd\u5e94\u53d1\u751f\uff0cHFIP\u7684\u6781\u6027\u548c\u5bf9\u6c34\u7684\u675f\u7f1a\u4f5c\u7528\u5728\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u53d1\u6325\u7740\u91cd\u8981\u7684\u89d2\u8272\u3002\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728Chemical Science <\/strong><\/em>\u4e0a\u3002<\/span><\/p>\n


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\u4f5c\u8005\u9996\u5148\u9009\u62e94-\u6c1f\u82c4\u57fa\u7532\u9187\uff081<\/strong>\uff09\u4f5c\u4e3a\u6a21\u677f\u5e95\u7269\u5bf9\u8be5\u53cd\u5e94\u8fdb\u884c\u521d\u6b65\u7684\u5c1d\u8bd5\uff0c\u572810% (w\/w) Re2<\/sub><\/span>O7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u7684\u50ac\u5316\u4e0b\uff0c\u53cd\u5e94\u4ee5HFIP\u4f5c\u4e3a\u6eb6\u5242\uff0c\u5bf9\u4e8c\u7532\u82ef\u4f5c\u4e3a\u4eb2\u6838\u8bd5\u5242\uff0c\u4ee589%\u7684\u6536\u7387\u5f97\u5230\u4ea7\u72693<\/strong>\u3002\u4f5c\u8005\u6700\u7ec8\u9009\u62e9Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u4e3b\u8981\u662f\u8003\u8651\u5230\u5f53\u50ac\u5316\u5242\u7528\u91cf\u5f88\u4f4e\u65f6\u6613\u4e8e\u51c6\u786e\u79f0\u91cf\uff08\u56fe1\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe1. Re<\/span><\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u4ecb\u5bfc\u7684\u8131\u6c34Friedel-Crafts\u53cd\u5e94\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


<\/p>\n

\u4f5c\u8005\u4f7f\u75281%\u7684Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5bf9\u4e8c\u7532\u82ef\u4f5c\u4e3a\u4eb2\u6838\u8bd5\u5242\uff0c\u8003\u5bdf\u4e0d\u540c\u7f3a\u7535\u5b50\u82c4\u57fa\u7532\u9187\u7684\u5e95\u7269\u9002\u7528\u6027\u3002\u4ece\u7ed3\u679c\u53ef\u4ee5\u770b\u51fa\uff0c\u53cd\u5e94\u57fa\u672c\u4e0a\u90fd\u80fd\u4ee5\u826f\u597d\u7684\u4ea7\u7387\u5f97\u5230\u5085\u514b\u70f7\u57fa\u5316\u4ea7\u7269\u3002\u7136\u800c\u5bf9\u4e8e\u5bf9\u6c30\u57fa\u82c4\u57fa\u7532\u9187\u9700\u8981\u4f7f\u7528\u6676\u4f53Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u4f5c\u8005\u63a8\u6d4bSiO<\/span>2<\/sub><\/span>\u53ef\u80fd\u4f1a\u964d\u4f4e\u50ac\u5316\u5242\u7684\u6d3b\u6027\uff08\u56fe2\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe2. \u5e95\u7269\u9002\u7528\u8303\u56f4\u7684\u8003\u5bdf\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


<\/p>\n

\u4f5c\u8005\u901a\u8fc7\u8fdb\u4e00\u6b65\u7684\u5b9e\u9a8c\u53d1\u73b0Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u4f5c\u4e3a\u50ac\u5316\u5242\u8868\u73b0\u51fa\u7684\u6d3b\u6027\u786e\u5b9e\u8981\u4f4e\u4e8e\u6676\u4f53Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\uff0cRe<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u662f\u901a\u8fc7Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u548cSiO<\/span>2<\/sub><\/span>\u6df7\u5408\u4e8e\u4e59\u919a\u4e2d\uff0c\u968f\u540e\u51cf\u538b\u9664\u53bb\u6eb6\u5242\u5236\u5907\u7684\uff0c\u56de\u6536\u7684\u50ac\u5316\u5242\u7528\u4e8e\u8be5\u53cd\u5e94\u8868\u73b0\u51fa\u8f83\u5dee\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u7531\u6b64\u6697\u793a\u50ac\u5316\u6d3b\u6027\u6765\u6e90\u4e8eSiO<\/span>2<\/sub><\/span>\u8868\u9762\u8d1f\u8f7d\u7684Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u3002\u4f5c\u8005\u8fd8\u8bbe\u8ba1\u4e86\u7b80\u5355\u7684\u9a8c\u8bc1\u5b9e\u9a8c\uff0c\u5c06Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u60ac\u6d6e\u4e8eHFIP\u4e2d\uff0c\u4e8e80 \u2103\u6405\u62cc0.5\u5c0f\u65f6\uff0c\u8fc7\u6ee4\u9664\u53bbSiO<\/span>2<\/sub><\/span>\u540e\u5c06\u5316\u5408\u72691<\/strong>\u548c2<\/strong>\u52a0\u5165\u5230\u6ee4\u6db2\u4e2d\uff0c\u53cd\u5e94\u4ee582%\u7684\u4ea7\u7387\u5f97\u5230\u76f8\u5e94\u7684\u4ea7\u7269\u3002\u4f5c\u8005\u63a8\u6d4bRe<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u4e0e\u6676\u4f53Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u7684\u6d3b\u6027\u5dee\u5f02\u6e90\u4e8eRe<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u5728SiO<\/span>2<\/sub><\/span>\u8868\u9762\u7684\u4e0d\u5b8c\u5168\u91ca\u653e\u6216SiO<\/span>2<\/sub><\/span>\u7684\u8868\u9762\u518d\u5438\u9644\uff0c\u7531\u6b64\u964d\u4f4e\u4e86\u4f53\u7cfb\u4e2dRe<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u7684\u6d53\u5ea6\uff08\u56fe3\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe3. \u9a8c\u8bc1\u5b9e\u9a8c\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


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\u4f5c\u8005\u63a5\u7740\u56fa\u5b9a\u4e94\u6c1f\u82c4\u57fa\u7532\u9187\u4f5c\u4e3a\u975e\u6d3b\u5316\u5e95\u7269\uff0c\u8003\u5bdf\u4e0d\u540c\u82b3\u9999\u70c3\u4eb2\u6838\u8bd5\u5242\u7684\u6d3b\u6027\u5dee\u5f02\u3002\u4ece\u56fe4\u53ef\u4ee5\u770b\u51fa\uff0c\u4e0d\u540c\u5e95\u7269\u53c2\u4e0e\u53cd\u5e94\u7684\u6d3b\u6027\u5dee\u5f02\u5f88\u660e\u663e\uff0c\u6d3b\u6027\u8d8a\u9ad8\u53cd\u5e94\u65f6\u95f4\u8d8a\u77ed\u3002\u6b64\u5916\uff0c\u5bf9\u4e8e\u542b\u591a\u4e2a\u53cd\u5e94\u4f4d\u70b9\u7684\u82b3\u9999\u70c3\uff0c\u57fa\u672c\u4e0a\u5f97\u5230\u7684\u662f\u4e0d\u540c\u6bd4\u4f8b\u7684\u6df7\u5408\u7269\uff08\u56fe4\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe4. \u82b3\u9999\u70c3\u4eb2\u6838\u6d3b\u6027\u7684\u6bd4\u8f83\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


<\/p>\n

\u4f5c\u8005\u8fd8\u8003\u5bdf\u4e86\u9664\u5bcc\u7535\u5b50\u82b3\u9999\u70c3\u5916\u66f4\u591a\u7684\u82b3\u9999\u70c3\u4eb2\u6838\u8bd5\u5242\uff0c\u7f3a\u7535\u5b50\u82b3\u9999\u70c3\u53c2\u4e0e\u53cd\u5e94\u7684\u4ea7\u7387\u8981\u4f4e\u5f88\u591a\uff0c\u591a\u53cd\u5e94\u4f4d\u70b9\u7684\u5e95\u7269\u53c2\u4e0e\u53cd\u5e94\u5f80\u5f80\u5f97\u5230\u4e0d\u540c\u6bd4\u4f8b\u7684\u6df7\u5408\u7269\uff08\u56fe5\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe5. \u4eb2\u6838\u8bd5\u5242\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


<\/p>\n

\u4f5c\u8005\u63a5\u7740\u8003\u5bdf\u4e0d\u540c\u6d3b\u6027\u7684\u5e95\u7269\u4e0e\u50ac\u5316\u5242\u8d1f\u8f7d\u91cf\u7684\u5173\u7cfb\uff0c\u5bf9\u4e8e\u5e95\u726929<\/strong>\u548c44<\/strong>\uff0c\u50ac\u5316\u5242\u7684\u8d1f\u8f7d\u91cf\u964d\u4f4e\u81f30.1%\uff0c\u53cd\u5e94\u65f6\u95f4\u9700\u8981\u5ef6\u957f\uff0c\u4ea7\u7387\u4e5f\u51fa\u73b0\u4e86\u4e0d\u540c\u7a0b\u5ea6\u7684\u4e0b\u964d\uff1b\u800c\u4f7f\u7528\u6d3b\u6027\u8f83\u9ad8\u7684\u5e95\u726945<\/strong>\u548c46<\/strong>\uff0c\u5373\u4f7f\u50ac\u5316\u5242\u7684\u8d1f\u8f7d\u91cf\u964d\u52300.0033 mol%\uff0c\u53cd\u5e94\u4f9d\u7136\u80fd\u4ee587%\u7684\u4ea7\u7387\u5f97\u5230\u4ea7\u726947<\/strong>\uff08\u56fe6\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe6. \u50ac\u5316\u5242\u8d1f\u8f7d\u91cf\u7684\u8003\u5bdf\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


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\u4f5c\u8005\u8fdb\u4e00\u6b65\u8003\u5bdf\u4e86\u4e0d\u540c\u6eb6\u5242\u5bf9\u53cd\u5e94\u7ed3\u679c\u7684\u5f71\u54cd\uff0c\u4e0d\u7ba1\u662f\u53cd\u5e94\u7684\u9009\u62e9\u6027\u8fd8\u662f\u4ea7\u7387\uff0c\u4f7f\u7528HFIP\u4f5c\u4e3a\u6eb6\u5242\u90fd\u5f97\u5230\u4e86\u6700\u597d\u7684\u7ed3\u679c\uff08\u56fe7\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe7. \u6eb6\u5242\u6548\u5e94\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


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\u5173\u4e8e\u79bb\u53bb\u57fa\u56e2\u5bf9\u53cd\u5e94\u7ed3\u679c\u7684\u5f71\u54cd\uff0c\u4f5c\u8005\u53d1\u73b0\u4e0d\u7ba1\u662f\u82c4\u57fa\u6c2f\u8fd8\u662f\u82c4\u57fa\u6eb4\uff0c\u6574\u4f53\u8868\u73b0\u90fd\u5dee\u4e8eRe<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u50ac\u5316\u82c4\u57fa\u7532\u9187\u7684\u5085\u514b\u70f7\u57fa\u5316\u53cd\u5e94\uff08\u56fe8\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe8. \u4e0d\u540c\u79bb\u53bb\u57fa\u56e2\u7684\u6bd4\u8f83\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


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\u4f5c\u8005\u8fd8\u5bf9\u4e0d\u540c\u7684\u50ac\u5316\u6d3b\u6027\u7269\u79cd\u8fdb\u884c\u52a8\u529b\u5b66\u7814\u7a76\u3002\u5b9e\u9a8c\u8868\u660e\uff0c1 mol%\u7684Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u300110 mol%\u7684TfOH\u548c2 mol%\u7684HOReO<\/span>3<\/sub><\/span>\u53c2\u4e0e\u53cd\u5e94\u8868\u73b0\u51fa\u76f8\u4f3c\u7684\u8f6c\u5316\u901f\u7387\u3002TfOH\u7684\u7528\u91cf\u964d\u4f4e\u52302 mol%\u65f6\u53cd\u5e94\u901f\u7387\u751a\u81f3\u6bd4Re2<\/sub><\/span>O7<\/sub><\/span>\u2022SiO<\/span>2<\/sub><\/span>\u8fd8\u4f4e\uff0c\u7531\u6b64\u8bf4\u660e\u5bf9\u7532\u82ef\u78fa\u9178\u4e0d\u80fd\u6709\u6548\u5730\u4fc3\u8fdb\u8be5\u53cd\u5e94\uff0c\u4f53\u7cfb\u5e76\u975e\u7ecf\u5386\u4e86\u7b80\u5355\u7684HFIP\u4fc3\u8fdb\u7684\u9178\u6027\u589e\u5f3a\u6548\u5e94\uff08\u56fe9\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe9. \u50ac\u5316\u5242\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u7814\u7a76\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


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\u4f5c\u8005\u8fd8\u63a2\u7a76\u4e86HOReO<\/span>3<\/sub><\/span>\u3001Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u548cTfOH\u4ecb\u5bfc\u7684\u5c06\u918b\u9178\u916f54<\/strong>\u8f6c\u5316\u4e3a11<\/strong>\u7684\u8fc7\u7a0b\u3002TfOH\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\uff0c\u7136\u800c\u6bd4\u76f8\u5e94\u918753<\/strong>\u7684\u53cd\u5e94\u901f\u7387\u6162\u3002\u4f5c\u8005\u8ba4\u4e3a\u5f62\u6210\u7684\u918b\u9178\u9694\u79bb\u6548\u7387\u8981\u5dee\u4e8e\u6c34\uff0c\u4ece\u800c\u5bfc\u81f4\u4e2d\u95f4\u4f53\u82c4\u57fa\u6b63\u79bb\u5b50\u7684\u53cd\u5e94\u6d53\u5ea6\u8f83\u4f4e\u3002\u800cHOReO<\/span>3<\/sub><\/span>\u3001Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u5728\u76f8\u540c\u7684\u65f6\u95f4\u548c\u53cd\u5e94\u6e29\u5ea6\u4e0b\u53c2\u4e0e\u53cd\u5e94\u7684\u8f6c\u5316\u7387\u8981\u4f4e\u4e8e5%\u3002\u8fd9\u4e00\u7ed3\u679c\u540c\u6837\u4e0e\u6eb6\u5242\u4f5c\u4e3a\u4ecb\u8d28\u7684\u9178\u6027\u589e\u5f3a\u6548\u5e94\u4e0d\u543b\u5408\uff0c\u56e0\u4e3aRe<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u50ac\u5316\u5242\u4fc3\u8fdb\u9187\u79bb\u5b50\u5316\u7684\u901f\u7387\u4e0eTfOH\u57fa\u672c\u76f8\u540c\uff08\u56fe10\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe10. \u918b\u9178\u916f\u79bb\u5b50\u5316\u53cd\u5e94\u7684\u7814\u7a76\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


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\u4f5c\u8005\u63a5\u7740\u9009\u62e9\u53cc\u5b98\u80fd\u5316\u7684\u5e95\u726955<\/strong>\u4e0e\u5e95\u72692<\/strong>\u53cd\u5e94\u8fdb\u884c\u7814\u7a76\uff0c\u7531\u6b64\u652f\u6301Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u50ac\u5316\u7684\u53cd\u5e94\u5e76\u975e\u7ecf\u5386\u4e86\u7b80\u5355\u7684\u9187\u8d28\u5b50\u5316\u4e0e\u6eb6\u5242\u4fc3\u8fdb\u7684\u9178\u6027\u589e\u5f3a\u8fc7\u7a0b\uff0c\u9ad8\u94fc\u9178\u916f\u4f5c\u4e3a\u53cd\u5e94\u4e2d\u95f4\u4f53\u540c\u6837\u5bf9\u8be5\u53cd\u5e94\u5177\u6709\u91cd\u8981\u5f71\u54cd\uff0cHFIP\u5bf9\u9ad8\u94fc\u9178\u916f\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u82c4\u57fa\u6b63\u79bb\u5b50\u5177\u6709\u4fc3\u8fdb\u4f5c\u7528\u3002\uff08\u56fe11\uff09\u3002<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

\u56fe11. \u53cc\u5b98\u80fd\u5316\u5e95\u7269\u7684\u7814\u7a76\u3002\u56fe\u7247\u6765\u6e90\uff1aChem. Sci.<\/em><\/span><\/p>\n


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\u603b\u7ed3<\/span><\/strong><\/span><\/p>\n


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Paul E. Floreancig\u6559\u6388\u548c\u8c22\u6709\u4f1f\u6559\u6388\u7b49\u4eba\u62a5\u9053\u4e86Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>\u50ac\u5316\u82c4\u57fa\u7532\u9187\u4e0e\u82b3\u9999\u70c3\u7684Friedel-Crafts\u53cd\u5e94\uff0c\u7531\u6b64\u9ad8\u6548\u5408\u6210\u4e8c\u82b3\u57fa\u7532\u70f7\u7c7b\u4ea7\u7269\u3002HFIP\u4f5c\u4e3a\u6eb6\u5242\u5bf9\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u3001\u964d\u4f4e\u82c4\u57fa\u7532\u9187\u7f9f\u57fa\u7684\u4eb2\u6838\u6027\u5177\u6709\u91cd\u8981\u4f5c\u7528\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u53cd\u5e94\u5e76\u975e\u7ecf\u5386\u7684\u7b80\u5355\u7684\u7f9f\u57fa\u8d28\u5b50\u5316\u8fc7\u7a0b\uff0c\u9ad8\u94fc\u9178\u916f\u6216\u8d28\u5b50\u5316\u7684\u9ad8\u94fc\u9178\u916f\u662f\u53cd\u5e94\u7684\u91cd\u8981\u4e2d\u95f4\u4f53\u3002<\/span><\/p>\n


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\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

Diarylmethane Synthesis through Re<\/span>2<\/sub><\/span>O<\/span>7<\/sub><\/span>-Catalyzed Bimolecular Dehydrative Friedel-Crafts Reactions<\/span><\/p>\n

Qi Qin, Youwei Xie, Paul E. Floreancig<\/span><\/p>\n

Chem. Sci.<\/span><\/em>, 2018<\/strong>, DOI: 10.1039\/C8SC03570A<\/span><\/p>\n


<\/span><\/p>\n

\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n

Paul E. Floreancig<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/1719<\/span><\/p>\n


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\u5173\u4e8eChemical Science<\/em>\uff1a<\/strong><\/p>\n


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\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u7efc\u5408\u6027\u65d7\u8230\u671f\u520a\uff0c\u6700\u65b0\u5f71\u54cd\u56e0\u5b50\u4e3a9.063\u3002\u53d1\u8868\u5316\u5b66\u9886\u57df\u6700\u524d\u6cbf\u3001\u6700\u91cd\u8981\u3001\u6700\u5177\u6311\u6218\u6027\u7684\u9ad8\u5f71\u54cd\u529b\u7814\u7a76\u6210\u679c\u3002Chemical Science<\/em> \u662f\u5316\u5b66\u9886\u57df\u4e2d\u5f71\u54cd\u529b\u6700\u5927\u7684\u5f00\u653e\u83b7\u53d6\u671f\u520a\uff08open access\uff09\uff0c\u6240\u6709\u6587\u7ae0\u5747\u53ef\u514d\u8d39\u9605\u8bfb\u3002<\/p>\n


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\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n

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\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n


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\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\"Re2O7\u50ac\u5316\u7684\u53cc\u5206\u5b50\u8131\u6c34\u5085\u514b\u53cd\u5e94\"<\/p>\n<\/section>\n<\/section>\n

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\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

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\u200d\u200d\u200d 2007\u5e74\uff0c\u7f8e\u56fd\u5316\u5b66\u4f1a\u7eff\u8272\u5316\u5b66\u7814\u7a76\u6240\u7684\u4e00\u4efd\u62a5\u544a\u5c06\u7f9f\u57fa\u6d3b\u5316\u7684\u4eb2\u6838\u53d6\u4ee3\u8fc7\u7a0b\u5b9a\u4e49\u4e3a\u5e38\u7528\u7684\u53cd\u5e94\uff0c\u4f46\u9700\u8981\u5728\u5176\u4ed6\u8bd5 […]<\/p>\n","protected":false},"author":1,"featured_media":54686,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/54685"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=54685"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/54685\/revisions"}],"predecessor-version":[{"id":54703,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/54685\/revisions\/54703"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/54686"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=54685"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=54685"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=54685"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}