{"id":54772,"date":"2018-09-27T01:00:00","date_gmt":"2018-09-30T01:58:40","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/30\/%e5%85%89%e8%af%b1%e5%af%bc%e7%83%b7%e5%9f%ba%e8%83%ba%e7%9a%84%e8%84%b1%e6%b0%a8%e7%a1%bc%e5%8c%96%e5%8f%8d%e5%ba%94\/"},"modified":"2018-09-30T09:58:44","modified_gmt":"2018-09-30T01:58:44","slug":"%e5%85%89%e8%af%b1%e5%af%bc%e7%83%b7%e5%9f%ba%e8%83%ba%e7%9a%84%e8%84%b1%e6%b0%a8%e7%a1%bc%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/54772\/","title":{"rendered":"\u5149\u8bf1\u5bfc\u70f7\u57fa\u80fa\u7684\u8131\u6c28\u787c\u5316\u53cd\u5e94"},"content":{"rendered":"
\n

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<\/p>\n

\u6700\u8fd1\uff0cVarinder K. Aggarwal<\/strong>\u6559\u6388\u8bfe\u9898\u7ec4\u53c8\u5728<\/span>J. Am. Chem. Soc.<\/em><\/strong><\/span>\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u62a5\u9053\u4e86\u53ef\u89c1\u5149\u4fc3\u8fdb\u4e0b\u4f2f\u70f7\u57fa\u80fa\u7684\u8131\u6c28\u787c\u5316\u53cd\u5e94<\/strong>\uff0cN<\/em>-\u70f7\u57fa\u5421\u5576\u76d04<\/strong>\u4e0eB<\/span>2<\/sub><\/span>cat<\/span>2<\/sub><\/span>\u5f62\u6210\u7ed9\u4f53-\u53d7\u4f53\u590d\u5408\u7269\uff0c\u5728\u5149\u8bf1\u5bfc\u4e0b\u53d1\u751f\u5355\u7535\u5b50\u8f6c\u79fb\u4e0e\u88c2\u89e3\uff0c\u5f62\u6210\u78b3\u4e2d\u5fc3\u81ea\u7531\u57fa\uff0c\u968f\u540e\u53d1\u751f\u787c\u5316\u3002\u8be5\u53cd\u5e94\u64cd\u4f5c\u7b80\u4fbf\uff0c\u53ef\u4ee5\u5728\u6e29\u548c\u3001\u65e0\u50ac\u5316\u5242\u548c\u65e0\u6dfb\u52a0\u5242\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u662f\u975e\u6d3b\u5316C(sp<\/span>3<\/sup><\/span>)-N\u952e\u787c\u5316\u53cd\u5e94\u7684\u9996\u4f8b\u62a5\u9053\u3002<\/span><\/p>\n

\"\u5149\u8bf1\u5bfc\u70f7\u57fa\u80fa\u7684\u8131\u6c28\u787c\u5316\u53cd\u5e94\"<\/p>\n

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<\/p>\n

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\"\u5149\u8bf1\u5bfc\u70f7\u57fa\u80fa\u7684\u8131\u6c28\u787c\u5316\u53cd\u5e94\"<\/p>\n

\u56fe2. \u53cd\u5e94\u6761\u4ef6\u7684\u7b5b\u9009\u3002\u56fe\u7247\u6765\u6e90\uff1aJ. Am. Chem. Soc.<\/em><\/span><\/p>\n


<\/p>\n

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\"\u5149\u8bf1\u5bfc\u70f7\u57fa\u80fa\u7684\u8131\u6c28\u787c\u5316\u53cd\u5e94\"<\/p>\n

\u56fe4. \u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u3002\u56fe\u7247\u6765\u6e90\uff1aJ. Am. Chem. Soc.<\/em><\/span><\/p>\n


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\"\u5149\u8bf1\u5bfc\u70f7\u57fa\u80fa\u7684\u8131\u6c28\u787c\u5316\u53cd\u5e94\"<\/p>\n

\u56fe5. \u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406\u3002\u56fe\u7247\u6765\u6e90\uff1aJ. Am. Chem. Soc.<\/em><\/span><\/p>\n


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\u603b\u7ed3<\/span><\/strong><\/span><\/p>\n


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Varinder K. Aggarwal\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u9996\u4f8b\u975e\u6d3b\u5316\u8102\u80aa\u4f2f\u80fa\u7684\u8131\u6c28\u787c\u5316\u53cd\u5e94\u3002N<\/em>-\u70f7\u57fa\u5421\u5576\u76d0\u4e0eB<\/span>2<\/sub><\/span>cat<\/span>2<\/sub><\/span>\u4e4b\u95f4\u5f62\u6210\u7535\u5b50\u7ed9\u4f53-\u53d7\u4f53\u590d\u5408\u7269\uff0c\u5728\u5149\u8bf1\u5bfc\u4e0b\u53d1\u751f\u5355\u7535\u5b50\u8f6c\u79fb\u548c\u88c2\u89e3\uff0c\u5f62\u6210\u78b3\u4e2d\u5fc3\u81ea\u7531\u57fa\uff0c\u968f\u540e\u53d1\u751f\u787c\u5316\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u3002\u53cd\u5e94\u7684\u5173\u952e\u5728\u4e8e\u5bcc\u7535\u5b50\u7684\u82b3\u9999\u4e8c\u9187\u513f\u8336\u915a\u914d\u4f4d\u7684\u787c\u7269\u79cd\u80fd\u4e0e\u8d2b\u7535\u5b50\u7684\u5421\u5576\u76d0\u6709\u6548\u5f62\u6210\u7ed9\u4f53-\u53d7\u4f53\u590d\u5408\u7269\u3002\u5404\u79cd\u6613\u5f97\u7684\u70f7\u57fa\u80fa\u90fd\u80fd\u6709\u6548\u5730\u8f6c\u5316\u4e3a\u5177\u6709\u5e94\u7528\u4ef7\u503c\u7684\u70f7\u57fa\u787c\u9178\u916f\u3002\u8be5\u53cd\u5e94\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u597d\uff0c\u53ef\u4ee5\u5bf9\u590d\u6742\u5929\u7136\u4ea7\u7269\u8fdb\u884c\u8131\u6c28\u787c\u5316\uff0c\u6709\u671b\u5728\u5408\u6210\u5177\u6709\u91cd\u8981\u751f\u7269\u6d3b\u6027\u7684\u542b\u787c\u5316\u5408\u7269\u4e2d\u5f97\u5230\u5e7f\u6cdb\u7684\u5e94\u7528\u3002<\/span><\/p>\n


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\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

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Photoinduced Deaminative Borylation of Alkylamines<\/span><\/p>\n

J. Am. Chem. Soc.<\/span><\/em>, 2018<\/strong>. 140<\/em>, 10700, DOI: 10.1021\/jacs.8b07103<\/span><\/p>\n


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\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n

Varinder K. Aggarwal<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/3205<\/span><\/p>\n


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