{"id":54796,"date":"2018-09-27T01:00:00","date_gmt":"2018-09-30T01:58:52","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/09\/30\/%e3%80%90%e7%bb%bc%e8%bf%b0%e3%80%91%e9%82%bb%e8%8b%af%e7%a2%b3%e9%86%8c%e3%80%81%e9%82%bb%e4%ba%9a%e7%94%b2%e5%9f%ba%e8%8b%af%e9%86%8c%e3%80%81%e6%b0%ae%e6%9d%82%e9%82%bb%e4%ba%9a%e7%94%b2%e5%9f%ba\/"},"modified":"2018-09-30T09:58:54","modified_gmt":"2018-09-30T01:58:54","slug":"%e3%80%90%e7%bb%bc%e8%bf%b0%e3%80%91%e9%82%bb%e8%8b%af%e7%a2%b3%e9%86%8c%e3%80%81%e9%82%bb%e4%ba%9a%e7%94%b2%e5%9f%ba%e8%8b%af%e9%86%8c%e3%80%81%e6%b0%ae%e6%9d%82%e9%82%bb%e4%ba%9a%e7%94%b2%e5%9f%ba","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/54796\/","title":{"rendered":"\u3010\u7efc\u8ff0\u3011\u90bb\u82ef\u78b3\u918c\u3001\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u3001\u6c2e\u6742\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u53c2\u4e0e\u7684Diels\u2013Alder\u53cd\u5e94\u53ca\u5176\u5728\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"
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\u534e\u4e1c\u5e08\u8303\u5927\u5b66<\/span><\/strong>\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u7684\u9ad8\u6813\u864e<\/strong>\u8bfe\u9898\u7ec4\u4e00\u76f4\u81f4\u529b\u4e8e\u6d3b\u6027\u5929\u7136\u4ea7\u7269\u7684\u5168\u5408\u6210\u7814\u7a76\u3002\u8fd1\u5e74\u6765\uff0c\u8be5\u8bfe\u9898\u7ec4\u5728\u5bf9\u5149\u4fc3\u8fdb\u7684\u70ef\u9187\u5316photoenolization Diels\u2013Alder\uff08PEDA\uff09\u53cd\u5e94\u53ca\u5176\u5728\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528\u65b9\u9762\u5c55\u5f00\u4e86\u6df1\u5165\u3001\u7cfb\u7edf\u7684\u7814\u7a76\uff0c\u89e3\u51b3\u4e86\u8be5\u9886\u57df\u957f\u671f\u672a\u80fd\u7a81\u7834\u7684\u6311\u6218\u6027\u79d1\u5b66\u95ee\u9898\uff0c\u5e76\u53d6\u5f97\u4e86\u4e00\u5b9a\u7684\u6807\u5fd7\u6027\u7814\u7a76\u6210\u679c\uff08Nat. Commun.<\/em>, 2017<\/strong>, 8<\/em>, 622\uff09\u3002\u76ee\u524d\uff0c\u8be5\u8bfe\u9898\u7ec4\u6b63\u4e13\u6ce8\u4e8e\u62d3\u5c55\u5206\u5b50\u95f4\u3001\u5206\u5b50\u5185\u7684PEDA\u53cd\u5e94\u53ca\u5929\u7136\u4ea7\u7269\u7684\u5408\u6210\u5e94\u7528\uff0c\u540c\u65f6\u5bf9\u6b64\u53cd\u5e94\u7684\u5bf9\u6620\u9009\u62e9\u6027\u63a7\u5236\u95ee\u9898\u4e5f\u8fdb\u884c\u6df1\u5165\u8003\u5bdf\uff0c\u5e76\u5747\u5df2\u53d6\u5f97\u4e00\u5b9a\u7684\u7814\u7a76\u7ed3\u679c\u3002<\/span><\/p>\n

\"\u3010\u7efc\u8ff0\u3011\u90bb\u82ef\u78b3\u918c\u3001\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u3001\u6c2e\u6742\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u53c2\u4e0e\u7684Diels\u2013Alder\u53cd\u5e94\u53ca\u5176\u5728\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528\"<\/p>\n


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\u57fa\u4e8e\u5728\u8fd9\u4e00\u9886\u57df\u7684\u6df1\u5165\u7814\u7a76\uff0c\u8fd1\u671f\uff0c\u8be5\u56e2\u961f\u5e94\u9080\u5728\u56fd\u9645\u6743\u5a01\u7efc\u8ff0\u671f\u520a<\/span>Chemical Society Reviews<\/strong><\/em><\/span>\u4e0a\u53d1\u8868\u6587\u7ae0\u201c<\/span>Recent advances in the application of Diels\u2013Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total synthesis<\/em><\/span>\u201d\uff0c\u7cfb\u7edf\u7efc\u8ff0\u4e86\u90bb\u82ef\u78b3\u918c\u3001\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u3001\u6c2e\u6742\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u53c2\u4e0e\u7684Diels\u2013Alder\u53cd\u5e94\u53ca\u5176\u5728\u5929\u7136\u4ea7\u7269\u5408\u6210\u5e94\u7528\u9886\u57df\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55<\/strong>\uff0c\u4e3b\u8981\u4f9d\u636e\u4e0a\u8ff0\u4e09\u79cd\u539f\u4f4d\u751f\u6210\u7684\u6d3b\u6027\u4e2d\u95f4\u4f53\u8fdb\u884c\u5206\u7c7b\uff0c\u5206\u522b\u5f52\u7eb3\u603b\u7ed3\u4e86\u5404\u4e2a\u4e2d\u95f4\u4f53\u7684\u5386\u53f2\u80cc\u666f\u3001\u5f62\u6210\u65b9\u6cd5\u3001\u6700\u65b0\u65b9\u6cd5\u5b66\u8fdb\u5c55\u4ee5\u53ca\u5929\u7136\u4ea7\u7269\u5168\u5408\u6210\u7684\u5e94\u7528\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4f5c\u8005\u5bf9\u4e00\u4e9b\u53cd\u5e94\u7684\u673a\u7406\u4e5f\u8fdb\u884c\u4e86\u8be6\u5c3d\u5730\u9610\u91ca\u3002\u5c3d\u7ba1\u8fc7\u53bb\u51e0\u5341\u5e74\uff0c\u8fd9\u4e09\u79cd\u6d3b\u6027\u4e2d\u95f4\u4f53\u53c2\u4e0e\u7684Diels\u2013Alder\u53cd\u5e94\u5e94\u7528\u76f8\u5bf9\u5e7f\u6cdb\uff0c\u4f46\u76f8\u6bd4\u4e8e\u81ea\u7531\u57fa\u3001\u78b3\u6b63\u79bb\u5b50\u548c\u5361\u5bbe\u7b49\u4f20\u7edf\u77ac\u65f6\u6d3b\u6027\u7269\u79cd\u7684\u5e94\u7528\u7a0b\u5ea6\u4ecd\u5b58\u5728\u5f88\u5927\u7684\u5dee\u8ddd\uff0c\u6709\u8bb8\u591a\u65b9\u9762\u9700\u8981\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\uff0c\u4f8b\u5982\u6c2e\u6742\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u76ee\u524d\u5e94\u7528\u8f83\u7a84\u3001\u90bb\u82ef\u78b3\u918c\u548c\u6c2e\u6742\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u5bf9\u6620\u9009\u62e9\u6027\u7814\u7a76\u8f83\u5c11\u3001\u4e09\u7c7b\u4e2d\u95f4\u4f53\u53c2\u4e0e\u4e0d\u5bf9\u79f0\u50ac\u5316\u5408\u6210\u5929\u7136\u4ea7\u7269\u76f8\u5bf9\u4e8e\u5e95\u7269\u63a7\u5236\u5408\u6210\u7684\u4f8b\u5b50\u8f83\u5c11\u7b49\u7b49\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u5bf9\u8be5\u9886\u57df\u7684\u53d1\u5c55\u65b9\u5411\u548c\u524d\u666f\u8fdb\u884c\u4e86\u5c55\u671b\uff0c\u4ee5\u4e0a\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u79d1\u6280\u90e8\u201c973\u201d\u8ba1\u5212\u7b49\u8d44\u52a9\u7684\u652f\u6301\uff0c\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u4e3a\u8be5\u8bba\u6587\u7684\u552f\u4e00\u901a\u8baf\u5355\u4f4d\u3002<\/span><\/p>\n


<\/p>\n

\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong>Baochao Yang, Shuanhu Gao<\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"\u3010\u7efc\u8ff0\u3011\u90bb\u82ef\u78b3\u918c\u3001\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u3001\u6c2e\u6742\u90bb\u4e9a\u7532\u57fa\u82ef\u918c\u53c2\u4e0e\u7684Diels\u2013Alder\u53cd\u5e94\u53ca\u5176\u5728\u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528\"<\/p>\n

Recent advances in the application of Diels\u2013Alder reactions involving <\/span>o<\/em>-quinodimethanes, aza-<\/span>o<\/em>-quinone methides and <\/span>o<\/em>-quinone methides in natural product total synthesis<\/span><\/p>\n

Chem. Soc. Rev.<\/span><\/em>, 2018<\/strong>, DOI: 10.1039\/C8CS00274F<\/span><\/p>\n


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\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n

\u9ad8\u6813\u864e<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/10566<\/span><\/p>\n


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\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n


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\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

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