{"id":84710,"date":"2019-04-17T00:00:50","date_gmt":"2019-04-17T03:15:18","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/84710\/"},"modified":"2019-04-17T11:15:20","modified_gmt":"2019-04-17T03:15:20","slug":"3b050ee9c4","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/84710\/","title":{"rendered":"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;text-align: center;\"><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657607803&amp;idx=2&amp;sn=0ae58a9d5ee3da4d5b7e6428662d19f8&amp;chksm=80f7c9abb78040bd88223e7ce0e1ff884b265e03a57b28d9a8bbb273b7dc8ebf92414828b4a1&amp;scene=21#wechat_redirect\" target=\"_blank\"  ><span style=\"top: auto;left: auto;margin: 0px;right: auto;bottom: auto;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;margin: 0px;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 556px;top: auto;left: auto;right: auto;bottom: auto;margin: 0px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/6-1555470918.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/span><\/span><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u901a\u8fc7\u9ad8\u6d3b\u6027\u7684\u70ef\u9187\u5316\u5e95\u7269\u6765\u8fdb\u884c\u78b3-\u78b3\u952e\u7684\u6784\u7b51\u662f\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\u5e38\u7528\u7684\u601d\u8def\u3002\u800c\u5728\u8be5\u53cd\u5e94\u7c7b\u578b\u7684\u7814\u7a76\u8fdb\u5c55\u4e2d\uff0c\u5229\u7528\u70ef\u9187\u91d1\u5c5e\u5316\u7269\u548c\u5364\u4ee3\u70ef\u70c3\u4ea4\u53c9\u5076\u8054\uff08\u56fe1<strong>A<\/strong>\uff09\u8fdb\u884c\u03b1-\u70ef\u57fa\u5316\u53cd\u5e94\u53ef\u4ee5\u83b7\u5f97\u975e\u5e38\u6709\u7528\u7684\u03b2,\u03b3-\u70ef\u916e\u7ed3\u6784\u3002Saeguasa\u548cKende\u901a\u8fc7Pd\u50ac\u5316\u975e\u6d3b\u5316\u70ef\u70c3\u548c\u70ef\u9187\u7845\u919a\u7684\u5076\u8054\u540c\u6837\u80fd\u6784\u7b51\u8be5\u7ed3\u6784\uff08\u56fe1<strong>B<\/strong>\uff09\u3002\u4f46\u5df2\u6709\u7684\u8fd9\u4e9b\u65b9\u6cd5\u90fd\u9700\u8981\u5bf9\u5e95\u7269\u8fdb\u884c\u9884\u5b98\u80fd\u5316\uff0c\u56e0\u6b64\u53d1\u5c55\u4e00\u79cd\u53ef\u4ee5\u76f4\u63a5\u5b9e\u73b0\u975e\u5b98\u80fd\u5316\u70ef\u70c3\u548c\u916e\u7684\u5076\u8054\u65b9\u6cd5\u5341\u5206\u5fc5\u8981\uff08\u56fe1<strong>C<\/strong>\uff09\u3002\u901a\u8fc7\u8fd9\u79cd\u65b9\u6cd5\u6784\u7b51\u5168\u5408\u6210\u4e2d\u5e38\u51fa\u73b0\u7684\u78b3\u73af\uff0c\u6709\u673a\u5316\u5b66\u5bb6\u53ef\u4ee5\u5229\u7528\u66f4\u4e3a\u5e7f\u6cdb\u7684\u5e95\u7269\u524d\u4f53\u4ee5\u53ca\u62e5\u6709\u66f4\u9ad8\u7684\u6b65\u9aa4\u7ecf\u6d4e\u6027\uff0c\u5927\u5927\u63d0\u9ad8\u4e86\u03b1-\u70ef\u57fa\u5316\u53cd\u5e94\u7684\u5b9e\u7528\u6027\u3002<\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong>\u7f8e\u56fd\u8036\u9c81\u5927\u5b66<\/strong>\u5316\u5b66\u7cfb\u7684<strong>Timothy&nbsp;R.&nbsp;Newhouse<\/strong>\u6559\u6388\u57fa\u4e8e\u4e4b\u524d\u7684Pd\u50ac\u5316\u7fb0\u57fa\u53bb\u6c22\u5316\u5de5\u4f5c\uff0c\u53d1\u73b0\u70ef\u4e19\u57fa\u524d\u4f53\u53ef\u4ee5\u4f5c\u4e3a\u6c27\u5316\u5242\u4fc3\u8fdb\u03b2-\u6c22\u6d88\u9664\u53cd\u5e94\uff0c\u731c\u6d4b\u70ef\u4e19\u57fa-\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u80fd\u591f\u4fc3\u8fdb\u53bb\u6c22\u73af\u70ef\u57fa\u5316\u53cd\u5e94\u3002\u57fa\u4e8eNi\u50ac\u5316\u5242\u53ef\u4fc3\u8fdb\u8fc1\u79fb\u63d2\u5165\u8fc7\u7a0b\uff0c\u4e14\u80fd\u6709\u6548\u6291\u5236Tsuji-Trost\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\u7684\u7279\u6027\uff0c\u4ed6\u4eec\u8bbe\u8ba1\u4e86\u70ef\u4e19\u57fa-Ni\u50ac\u5316\u5242\u6765\u8fdb\u884c\u8be5\u53cd\u5e94\uff0c\u5e76\u63d0\u51fa\u4e86\u8be5\u53cd\u5e94\u7684\u53cd\u5e94\u673a\u7406\uff08\u56fe1C\uff09\uff1a\u9996\u5148\u662f\u901a\u8fc7\u5e95\u72691\u53bb\u8d28\u5b50\u5316\u7136\u540e\u4e0e\u70ef\u4e19\u57faNi\u7269\u79cd\u53d1\u751f\u8f6c\u91d1\u5c5e\u5316\uff0c\u751f\u6210\u70ef\u4e19\u57fa-Ni\u7684\u70ef\u9187\u5316\u72694\uff0c\u518d\u53d1\u751f\u70ef\u9187\u78b3\u5bf9\u70ef\u57fa\u7684\u8fc1\u79fb\u63d2\u5165\u5f62\u6210\u70f7\u57fa\u954d\u7269\u79cd5\uff0c\u8fdb\u800c\u53d1\u751f\u03b2-\u6c22\u6d88\u9664\u751f\u6210\u76ee\u6807\u4ea7\u72692\u3002Ni(0)\u5728\u70ef\u4e19\u57fa\u524d\u4f53\u7684\u6c27\u5316\u52a0\u6210\u4e0b\u751f\u6210\u50ac\u5316\u5242\u6d3b\u6027\u7269\u79cd3\uff0c\u7531\u6b64\u5b8c\u6210\u50ac\u5316\u5faa\u73af\u3002\u4f7f\u7528Ni\u50ac\u5316\u5242\u4e5f\u53ef\u4f7f\u50ac\u5316\u5242\u7684\u6210\u672c\u8fdb\u4e00\u6b65\u964d\u4f4e\uff0c\u4e0e\u6b64\u540c\u65f6\uff0cNewhouse\u6559\u6388\u6839\u636e\u8be5\u70ef\u4e19\u57fa-Ni\u50ac\u5316\u5242\u7684\u50ac\u5316\u7279\u6027\u8bbe\u8ba1\u4e86\u916e\u7684\u03b1,\u03b2-\u53bb\u6c22\u5316\u53cd\u5e94\u3002<\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/1-1555470918.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe1.&nbsp;\u7814\u7a76\u80cc\u666f\u4ee5\u53ca\u672c\u6587\u7684\u5de5\u4f5c\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u8fd1\u65e5\uff0c\u8be5\u8bfe\u9898\u7ec4\u5728<strong><em>J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc.<\/em><\/strong>\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u62a5\u9053\u4e86<strong>\u70ef\u4e19\u57fa-Ni\u50ac\u5316\u7fb0\u57fa\u5316\u5408\u7269\u7684\u03b1,\u03b2-\u53bb\u6c22\u5316\u53cd\u5e94\u4ee5\u53ca\u6c27\u5316\u578b\u916e\u7684\u73af\u70ef\u57fa\u5316\u53cd\u5e94\uff0c<\/strong>\u53ef\u79f0\u201c\u4e00\u7bad\u53cc\u96d5\u201d\uff0c\u8fd9\u662f\u9996\u4f8b\u7b2c\u4e00\u884c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7fb0\u57fa\u5316\u5408\u7269\u7684\u03b1,\u03b2-\u53bb\u6c22\u5316\u53cd\u5e94\u3002\u5176\u4e2d\uff0cNi\u50ac\u5316\u7684\u03b1,\u03b2-\u53bb\u6c22\u5316\u53cd\u5e94\u76f8\u6bd4\u4e8e\u4f20\u7edf\u7684Pd\u50ac\u5316\u8fc7\u7a0b\u5177\u6709\u66f4\u5e7f\u7684\u5e95\u7269\u9002\u7528\u6027\u4ee5\u53ca\u66f4\u597d\u7684\u7ecf\u6d4e\u6027\uff1b\u6c27\u5316\u578b\u916e\u7684\u73af\u70ef\u57fa\u5316\u53cd\u5e94\u5219\u63d0\u4f9b\u4e86\u4e00\u79cd\u5229\u7528\u975e\u6d3b\u5316\u916e\u6784\u5efa\u7a20\u5408\u3001\u6865\u8fde\u4ee5\u53ca\u87ba\u73af\u53cc\u73af\u70ef\u916e\u7684\u65b9\u6cd5\uff0c\u5177\u6709\u8f83\u597d\u7684\u5e95\u7269\u9002\u7528\u6027\uff0c\u76f8\u6bd4\u4e8e\u4e4b\u524d\u7684\u9884\u5b98\u80fd\u5316\u7b56\u7565\u5177\u6709\u66f4\u597d\u7684\u7ecf\u6d4e\u6027\u3002<\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u5728\u6761\u4ef6\u7b5b\u9009\u4e2d\uff08\u56fe2\uff09\uff0c\u4f5c\u8005\u8003\u5bdf\u4e86\u4e0d\u540c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u4ee5\u53ca\u78b1\u5bf9\u53cd\u5e94\u7684\u5f71\u54cd\uff0c\u53d1\u73b0Ni\u50ac\u5316\u5242\uff08NiBr<span style=\"font-size: 14px;\"><sub>2<\/sub><\/span>(dme)\uff09\u3001\u5927\u4f4d\u963b\u78b1\uff08LiCyan\uff09\u548cZnBr<span style=\"font-size: 14px;\"><sub>2<\/sub><\/span>\u6df7\u5408\u5177\u6709\u6700\u597d\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f5c\u8005\u5728\u5e95\u7269\u9002\u7528\u8303\u56f4\u7684\u62d3\u5c55\uff08\u56fe3\uff09\u4e2d\uff0c\u4e0d\u4ec5\u8bc1\u660e\u4e86\u5404\u79cd\u53d6\u4ee3\u57fa\u4fee\u9970\u7684\u8102\u80aa\u916e\u3001\u916f\u3001\u8148\u3001\u548c\u9170\u80fa\u5e95\u7269\u90fd\u5177\u6709\u826f\u597d\u7684\u4ea7\u7387\u548cZ\/E\u9009\u62e9\u6027\uff0c\u73af\u916e\u3001\u916f\u3001\u9170\u80fa\u7b49\u7c7b\u578b\u7684\u5e95\u7269\u5728Zn(TMP)<span style=\"font-size: 14px;\"><sub>2<\/sub><\/span>\u7684\u4f5c\u7528\u4e0b\u4e5f\u80fd\u53d6\u5f97\u826f\u597d\u7684\u4ea7\u7387\u3002<\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/9-1555470919.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe2.&nbsp;\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/10-1555470919.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe3.&nbsp;\u7fb0\u57fa\u5316\u5408\u7269\u03b1,\u03b2-\u53bb\u6c22\u5316\u53cd\u5e94\u7684\u5e95\u7269\u62d3\u5c55\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u4f5c\u8005\u8fd8\u4ee5\u51e0\u4e4e\u76f8\u540c\u7684\u53cd\u5e94\u6761\u4ef6\u5bf9\u916e\u7684\u6c27\u5316\u578b\u73af\u70ef\u57fa\u5316\u53cd\u5e94\u8fdb\u884c\u5e95\u7269\u9002\u7528\u8303\u56f4\u7684\u8003\u5bdf\uff08\u56fe4\uff09\uff0c\u53ea\u6539\u53d8\u78b1\u548c\u6dfb\u52a0\u5242\uff08Zn(TMP)<span style=\"font-size: 14px;\"><sub>2<\/sub><\/span>\u4f5c\u4e3a\u78b1\uff0cZnBr<span style=\"font-size: 14px;\"><sub>2<\/sub><\/span>\u4f5c\u4e3a\u6dfb\u52a0\u5242\uff09\u3002\u4ed6\u4eec\u53d1\u73b0\u4f7f\u7528ZnBr<span style=\"font-size: 14px;\"><sub>2<\/sub><\/span>\u6dfb\u52a0\u5242\u662f\u63d0\u9ad8\u53cd\u5e94\u6548\u7387\u4ee5\u53ca\u6269\u5c55\u5e95\u7269\u9002\u7528\u8303\u56f4\u7684\u5173\u952e\u3002\u5728\u5e95\u7269\u62d3\u5c55\u4e2d\uff0c\u4f5c\u8005\u8bc1\u660e\u4e86\u8be5\u53cd\u5e94\u53ef\u9009\u62e9\u6027\u5408\u6210\u516d\u5143\u73af\uff0c\u4e0d\u540c\u4e8e\u4e4b\u524d\u62a5\u9053\u7684Pd\u50ac\u5316\u53cd\u5e94\u7684\u4e94\u5143\u73af\u9009\u62e9\u6027\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u4e0d\u4ec5\u8bc1\u5b9e\u4e86\u8be5\u4f53\u7cfb\u53ef\u5b9e\u73b0\u70ef\u57fa\u548c\u7fb0\u57fa\u03b1\u4f4d\u4e0d\u540c\u5b98\u80fd\u5316\u7684\u87ba\u73af\u4e0e\u7a20\u73af\u5e95\u7269\u7684\u9ad8\u6548\u50ac\u5316\u8f6c\u5316\uff0c\u4e5f\u8bc1\u660e\u5bf9\u4e8e\u6784\u7b51\u5929\u7136\u4ea7\u7269\u4e2d\u5e38\u51fa\u73b0\u7684\u6865\u73af\u6838\u5fc3\u9aa8\u67b6\u4e5f\u5177\u6709\u5f88\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u4f5c\u8005\u8fdb\u884c\u5e95\u7269\u62d3\u5c55\u65f6\uff0c\u5f97\u5230\u7684\u4ea7\u7269\u5747\u4e3a\u5916\u578b\u7684\u987a\u5f0f\u73af\u5316\u4ea7\u7269\uff0c\u6ca1\u6709\u53d1\u73b0\u70ef\u57fa\u5f02\u6784\u5316\u4ea7\u7269\uff0c\u8fd9\u79cd\u8f83\u9ad8\u7684\u9009\u62e9\u6027\u76f8\u5bf9\u4e8e\u4ee5\u5f80Pd\u50ac\u5316\u7684\u540c\u7c7b\u53cd\u5e94\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u4f18\u52bf\u3002<\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/3-1555470919.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe4.&nbsp;\u6c27\u5316\u578b\u916e\u73af\u70ef\u57fa\u5316\u53cd\u5e94\u7684\u5e95\u7269\u62d3\u5c55\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u4e3a\u4e86\u4e86\u89e3\u8be5\u53cd\u5e94\u4e2d\u78b3-\u78b3\u952e\u5f62\u6210\u7684\u50ac\u5316\u673a\u5236\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u5bf9\u7167\u5b9e\u9a8c\u3002\u5728\u6ca1\u6709Ni\u50ac\u5316\u5242\u7684\u53c2\u4e0e\u4e0b\uff0c\u53cd\u5e94\u6ca1\u6709\u53d1\u751f\u03b2-\u6c22\u6d88\u9664\uff0c\u4f46\u5f97\u5230\u4e86\u4ea7\u7387\u8f83\u4f4e\u7684\u73af\u5316\u4ea7\u7269<strong>12<\/strong>\uff08\u56fe5<strong>b<\/strong>\uff09\uff0c\u8bf4\u660e\u70ef\u9187\u5316\u950c\u53ef\u80fd\u662f\u6784\u7b51\u78b3-\u78b3\u952e\u7684\u524d\u4f53\u3002\u5728\u5148\u52a0\u5165Zn\u76d0\u3001\u518d\u52a0\u5165Ni\u50ac\u5316\u5242\u7684\u5206\u6b65\u53cd\u5e94\u4e2d\uff08\u56fe5<strong>c<\/strong>\uff09\uff0c\u4f5c\u8005\u5f97\u5230\u4e86\u76ee\u6807\u4ea7\u7269<strong>2i<\/strong>\uff0c\u4f46\u4ea7\u7387\u8f83\u4f4e\u3002\u5728\u70ef\u9187\u5316\u954d\u4e3a\u4e2d\u95f4\u4f53\u7684\u53cd\u5e94\u4e2d\uff08\u56fe5<strong>d<\/strong>\uff09\uff0c\u4f5c\u8005\u4e5f\u4ec5\u5f97\u5230\u4e86\u8f83\u4f4e\u4ea7\u7387\u7684\u76ee\u6807\u4ea7\u7269<strong>2i<\/strong>\uff0c\u8bf4\u660e\u53cd\u5e94\u53ef\u80fd\u7ecf\u5386\u4e86\u70ef\u9187\u5316\u950c\u4fc3\u8fdb\u7684\u73af\u5316\u8fc7\u7a0b\uff0c\u968f\u540e\u518d\u8fdb\u884cNi\u50ac\u5316\u7684\u03b2-\u6c22\u6d88\u9664\u53cd\u5e94\uff0c\u4f46\u4e5f\u65e0\u6cd5\u6392\u9664\u70ef\u9187\u5316\u954d\u7684\u8fc1\u79fb\u63d2\u5165\u8fc7\u7a0b\u3002<\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/7-1555470920.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe5.&nbsp;\u5bf9\u7167\u5b9e\u9a8c\u548c\u673a\u7406\u7814\u7a76\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: center;line-height: 1.75em;\"><span style=\"color: rgb(33, 127, 188);\"><strong>\u603b\u7ed3<\/strong><\/span><\/p>\n<p style=\"line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">Timothy&nbsp;R.&nbsp;Newhouse\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7\u5de7\u5999\u4f7f\u7528\u70ef\u4e19\u57fa\u524d\u4f53\u4f5c\u4e3a\u6c27\u5316\u5242\uff0c\u5229\u7528\u70ef\u4e19\u57faNi\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u4e00\u7bad\u53cc\u96d5\uff0c\u5b8c\u6210\u4e86\u7fb0\u57fa\u5316\u5408\u7269\u7684\u03b1,\u03b2-\u53bb\u6c22\u5316\u53cd\u5e94\u4ee5\u53ca\u916e\u7684\u6c27\u5316\u578b\u73af\u70ef\u57fa\u5316\u53cd\u5e94\u3002\u8be5\u5de5\u4f5c\u4f7f\u7528\u66f4\u4e3a\u5ec9\u4ef7\u7684\u7b2c\u4e00\u884c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5728\u50ac\u5316\u6027\u80fd\u4e0a\u6218\u80dc\u4e86\u4ee5\u5f80Pd\u50ac\u5316\u7684\u540c\u7c7b\u53cd\u5e94\uff0c\u5177\u6709\u66f4\u5e7f\u6cdb\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\uff0c\u5c55\u73b0\u4e86\u9ad8\u6548\u6784\u7b51\u5929\u7136\u4ea7\u7269\u5173\u952e\u9aa8\u67b6\u7684\u6f5c\u80fd\u3002<\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n<p><img class=\"rich_pages\"       style=\"text-align: left;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/4-1555470920.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Allyl-Nickel Catalysis Enables Carbonyl Dehydrogenation and Oxidative Cycloalkenylation of Ketones<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc<\/span><\/em><span style=\"font-size: 14px;\">.,&nbsp;<strong>2019<\/strong>,&nbsp;<em>141<\/em>,&nbsp;5669,&nbsp;DOI:&nbsp;10.1021\/jacs.9b02552<\/span><\/p>\n<p style=\"line-height: normal;\"><span style=\"font-size: 14px;\"><br  \/><\/span><\/p>\n<p><span style=\"font-size: 13px;\">\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n<p><span style=\"font-size: 13px;\">Timothy R. Newhouse<\/span><\/p>\n<p><span style=\"font-size: 13px;\">https:<\/span><span style=\"font-size: 13px;\">\/\/www.x-mol.com\/university\/faculty\/1301<\/span><\/p>\n<p><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657608573&amp;idx=2&amp;sn=f2abf3b8761e88b92582e8dbb250d794&amp;chksm=80f7caadb78043bb6946c8de55a3263838240f4675f42a90bd1069a9fd16c028f5dfd5745b96&amp;scene=21#wechat_redirect\" target=\"_blank\"  ><span style=\"top: auto;left: auto;margin: 0px;right: auto;bottom: auto;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;margin: 0px;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 556px;top: auto;left: auto;right: auto;bottom: auto;margin: 0px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/3-1555470920.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/span><\/span><\/a><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/1-1555470920.png\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;overflow-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/p>\n<p style=\"box-sizing: border-box;\"><br style=\"box-sizing: border-box;\"  \/><\/p>\n<p style=\"box-sizing: border-box;\"><span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">\u957f\u6309<\/strong><\/span>\u4e0b\u56fe<strong style=\"box-sizing: border-box;\">\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/p>\n<\/section>\n<\/section>\n<\/section>\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<p style=\"margin-top: 10px;margin-bottom: 10px;text-align: center;box-sizing: border-box;\"><img class=\"\"     style=\"vertical-align: middle;box-sizing: border-box;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/10-1555470920.jpeg\" alt=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\" title=\"\u70ef\u4e19\u57faNi\u50ac\u5316\u5242\u4e00\u7bad\u53cc\u96d5\uff1a\u65e0\u9700\u9884\u5b98\u80fd\u5316\u7684\u53bb\u6c22\u5316\u548c\u73af\u70ef\u57fa\u5316\"  \/><\/p>\n<\/section>\n<\/section>\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-bottom: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-bottom: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section style=\"white-space: normal;\">\n<section >\n<section>\n<section>\n<section>\n<section >\n<section>\n<section>\n<p style=\"text-align: center;\"><br  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;overflow-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 17px;box-sizing: border-box !important;overflow-wrap: break-word !important;\">\u70b9\u51fb\u201c<span style=\"max-width: 100%;color: rgb(0, 122, 170);\">\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b&nbsp;<strong>\u5316\u5b66 \u2022 \u6750\u6599&nbsp;<\/strong>\u9886\u57df<span style=\"max-width: 100%;background-color: rgb(255, 218, 81);\">\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;overflow-wrap: break-word !important;\">\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u901a\u8fc7\u9ad8\u6d3b\u6027\u7684\u70ef\u9187\u5316\u5e95\u7269\u6765\u8fdb\u884c\u78b3-\u78b3\u952e\u7684\u6784\u7b51\u662f\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\u5e38\u7528\u7684\u601d\u8def\u3002\u800c\u5728\u8be5\u53cd\u5e94\u7c7b\u578b\u7684\u7814\u7a76\u8fdb\u5c55\u4e2d\uff0c\u5229\u7528\u70ef\u9187\u91d1\u5c5e 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