{"id":84916,"date":"2019-04-15T00:00:50","date_gmt":"2019-04-17T03:16:47","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/84916\/"},"modified":"2019-04-17T11:16:49","modified_gmt":"2019-04-17T03:16:49","slug":"048e866653","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/84916\/","title":{"rendered":"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;text-align: center;\"><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657607646&amp;idx=1&amp;sn=4009dd55313cfa41a0c52b1c5b182c89&amp;chksm=80f7f60eb7807f18d3c08c8685345ef026bd555af384275d9c6807b97133a8c4b1e1b7c31f55&amp;scene=21#wechat_redirect\" target=\"_blank\"  ><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;right: auto;bottom: auto;\"><img class=\"\"           style=\"height: 116px;top: auto;left: auto;right: auto;bottom: auto;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/9-1555471007.jpeg\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/span><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong>\u91d1\u5c5e\u6709\u673a\u6846\u67b6<\/strong>\uff08MOF\uff09\u662f\u5f53\u524d\u6750\u6599\u9886\u57df\u7684\u4e00\u4e2a\u7814\u7a76\u70ed\u95e8\uff0c\u5230\u76ee\u524d\u4e3a\u6b62\u6709\u5f62\u5f62\u8272\u8272\u8fd16\u4e07\u79cdMOF\u88ab\u62a5\u9053\uff0c\u5b83\u4eec\u5728\u6c14\u4f53\u5438\u9644\u548c\u5206\u79bb\u4ee5\u53ca\u50ac\u5316\u65b9\u9762\u7684\u6f5c\u529b\u88ab\u5e7f\u6cdb\u770b\u597d\u3002\u4f17\u6240\u5468\u77e5\uff0cMOF\u662f\u7ed3\u6784\u6709\u5e8f\u7684\u6676\u4f53\u6750\u6599\uff0c\u4e0d\u8fc7\u968f\u7740\u7814\u7a76\u7684\u6df1\u5165\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u4eba\u8ba4\u8bc6\u5230\u8fd9\u79cd\u201c\u8f6f\u6676\u4f53\u201d\u6750\u6599\u5bb6\u65cf\u5176\u4ed6\u4e0d\u5bfb\u5e38\u7684\u7269\u7406\u6027\u8d28\u4e5f\u503c\u5f97\u91cd\u89c6\uff0c\u4f8b\u5982\u7f3a\u9677\u3001\u6846\u67b6\u67d4\u6027\u548c\u65e0\u5e8f\u6027\u3002\u5728\u5916\u90e8\u4f5c\u7528\u4e0b\uff0cMOF\u4f1a\u8868\u73b0\u51fa\u7ed3\u6784\u53d8\u5316\uff0c\u5e26\u6765\u8bf8\u5982\u8d1f\u6027\u6c14\u4f53\u5438\u9644\u3001\u547c\u5438\u6548\u5e94\u4ee5\u53ca\u6e29\u5ea6\u6216\u538b\u529b\u8bf1\u5bfc\u76f8\u53d8\u7b49\u6709\u8da3\u7684\u73b0\u8c61\u3002\u4f8b\u5982\uff0c\u5728\u8f83\u9ad8\u7684\u6e29\u5ea6\u548c\u538b\u529b\u4e0b\uff0c\u6cb8\u77f3\u54aa\u5511\u916f\u6846\u67b6\uff08ZIF\uff09\u80fd\u4e0e\u7ed3\u6784\u7c7b\u4f3c\u7684\u6cb8\u77f3\u4e00\u6837\u4fdd\u6301\u5fae\u5b54\u7ed3\u6784\uff1b\u5982\u679c\u6e29\u5ea6\u548c\u538b\u529b\u8fdb\u4e00\u6b65\u5347\u9ad8ZIF\u6700\u7ec8\u4f1a\u53d1\u751f\u76f8\u53d8\u5e76\u7194\u5316\uff0c\u4f46\u7531\u8fd9\u79cdZIF\u6db2\u4f53\u6dec\u706b\u5374\u4f1a\u5f62\u6210\u4e00\u7c7b\u65b0\u7684\u73bb\u7483\u6750\u6599\uff0c\u5305\u542b\u975e\u6676\u6001\u3001\u7c7b\u4f3cSiO<span style=\"font-size: 14px;\"><sub>2<\/sub><\/span>\u7684\u8fde\u7eed\u968f\u673a\u7f51\u7edc\uff0c\u800c\u4e14\u8fd9\u7c7b\u73bb\u7483\u8fd8\u201c\u7ee7\u627f\u201d\u4e86ZIF\u7684\u5316\u5b66\u8fde\u63a5\u6027\u548c\u7ec4\u6210\u3002\u7c7b\u4f3c\u7814\u7a76\u5438\u5f15\u4e86\u4e0d\u5c11\u6ce8\u610f\uff0c\u6e29\u5ea6\u6216\u538b\u529b\u76f8\u5173\u7684ZIF\u6027\u8d28\u7814\u7a76\u4e5f\u5df2\u89c1\u8bf8\u62a5\u9053\u3002<\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u8fd1\u65e5\uff0c<strong>\u82f1\u56fd\u5251\u6865\u5927\u5b66<\/strong>\u7684<strong>Thomas&nbsp;D.&nbsp;Bennett<\/strong>\u7814\u7a76\u56e2\u961f\u5728<em><strong>Nature&nbsp;Materials<\/strong><\/em>&nbsp;\u4e0a\u62a5\u9053\u4e86<strong>\u540c\u65f6\u65bd\u4ee5\u9ad8\u538b\u548c\u9ad8\u6e29\u6761\u4ef6\u4e0bZIF-62\u548cZIF-4\u7684\u590d\u6742\u76f8\u53d8\u884c\u4e3a<\/strong>\u3002\u8fd9\u4e24\u79cdMOF\u5728\u538b\u529b\uff08<em>P<\/em>\uff09-\u6e29\u5ea6\uff08<em>T<\/em>\uff09\u76f8\u56fe\u7684\u4e0d\u540c\u533a\u57df\u51fa\u73b0\u4e0d\u540c\u7684\u9ad8\u5bc6\u5ea6\u548c\u4f4e\u5bc6\u5ea6\u975e\u6676\u76f8\uff1b\u539f\u4f4d\u7c89\u672bX\u5c04\u7ebf\u884d\u5c04\uff08PXRD\uff09\u3001\u62c9\u66fc\u5149\u8c31\u548c\u5149\u5b66\u663e\u5fae\u955c\u7ed3\u679c\u53ca\u7b2c\u4e00\u6027\u539f\u7406\u5206\u5b50\u52a8\u529b\u5b66\uff08FPMD\uff09\u7814\u7a76\u8868\u660e\uff0c<strong>\u5916\u52a0\u538b\u529b\u8ba9MOF\u7194\u5316\u53d8\u5f97\u66f4\u5bb9\u6613<\/strong>\uff0c\u538b\u529b\u8bf1\u5bfc\u7684\u6846\u67b6\u8f6f\u5316\u4f7f\u5f97MOF\u7684\u7194\u5316\u5728\u70ed\u529b\u5b66\u4e0a\u66f4\u5bb9\u6613\u5b9e\u73b0\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u6dec\u706b\u7194\u878d\u7684MOF\u6db2\u4f53\u5f62\u6210\u7684MOF\u73bb\u7483\uff0c\u5177\u6709\u6c38\u4e45\u6027\u591a\u5b54\u7ed3\u6784\u3002<\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/3-1555471007-1.jpeg\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe1.&nbsp;\uff08a,&nbsp;b\uff09ZIF-62\u6676\u4f53\u7ed3\u6784\u548c\u62d3\u6251\u7f51\u7edc\u3002\uff08c,&nbsp;d\uff09\u539f\u4f4d\u8868\u5f81\u5b9e\u9a8c\u4eea\u5668\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">Nat.&nbsp;Mater.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u4f5c\u8005\u9009\u53d6\u4e86\u5df2\u62a5\u9053\u7684ZIF-62&nbsp;[Zn(Im)<span style=\"font-size: 14px;\"><sub>1.75<\/sub><\/span>(bIm)<span style=\"font-size: 14px;\"><sub>0.25<\/sub><\/span>]\uff08Im=\u54aa\u5511\uff0cbIm=\u82ef\u5e76\u54aa\u5511\uff09\u4f5c\u4e3a\u7814\u7a76\u5bf9\u8c61\u3002\u8fd9\u79cdMOF\u6750\u6599\u5728\u7194\u70b9\uff08430&nbsp;\u2103\uff09\u548c\u5206\u89e3\u6e29\u5ea6\uff08500&nbsp;\u2103\uff09\u95f4\u8868\u73b0\u51fa\u7a33\u5b9a\u7684\u6db2\u4f53\u72b6\u6001\uff08<em>J.&nbsp;Am.&nbsp;Chem.&nbsp;Soc.<\/em>,&nbsp;<strong>2016<\/strong>,&nbsp;<em>138<\/em>,&nbsp;3484\uff09\u3002ZIF-62\u6676\u4f53\u5177\u6709<em>Pbca<\/em>\u7a7a\u95f4\u7fa4\uff0c\u5e76\u4e14\u4e0e\u78f7\u9178\u76d0\u65b9\u89e3\u77f3\u548c\u7ea2\u78f7\u94c1\u77ff\u62e5\u6709\u4e00\u6837\u7684\u62d3\u6251\u7f51\u7edc\uff08\u56fe1a\u30011b\uff09\u3002\u4e3a\u4e86\u7ed8\u5236ZIF-62\u7684<em>P-T&nbsp;<\/em>\u76f8\u56fe\uff0c\u4f5c\u8005\u4f7f\u7528\u4e86PXRD\uff0c\u5e76\u4e14\u5c06\u5149\u5b66\u663e\u5fae\u955c\u4e0e\u539f\u4f4d\u7535\u5b50\u663e\u5fae\u955c\u5728\u9ad8\u538b\u548c\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7ed3\u5408\u8d77\u6765\u4f7f\u7528\u3002\u4ed6\u4eec\u8fd8\u8fdb\u884c\u4e86\u6052\u538bFPMD\u6a21\u62df\uff0c\u4ee5\u6df1\u5165\u4e86\u89e3\u5206\u5b50\u6c34\u5e73\u4e0a\u7684\u538b\u529b\u4f9d\u8d56\u6027\u3002\u4f5c\u8005\u9996\u5148\u4f7f\u7528\u7535\u963b\u52a0\u70ed\u7684\u819c\u9a71\u52a8\u91d1\u521a\u77f3\u538b\u7827\uff08\u56fe1c\/1d\uff09\u5206\u522b\u5728\u5e38\u538b\u81f38&nbsp;GPa\u548c\u5ba4\u6e29\u81f3450&nbsp;\u2103\u7684<em>P-T&nbsp;<\/em>\u8303\u56f4\u5185\u7814\u7a76ZIF-62\u7684\u76f8\u7a33\u5b9a\u6027\u3002<\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/7-1555471008.jpeg\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe2.&nbsp;\uff08a\uff09ZIF-62\u7684<em>P-T&nbsp;<\/em>\u76f8\u56fe\u3002\uff08b\uff09\u6676\u6001ZIF-62\u3002\uff08c\uff09\u9ad8\u538b\u4e0b\u56fa\u6001\u975e\u6676\u6001ZIF-62\u3002\uff08d\uff09\u9ad8\u538b\u7194\u878d\u6001ZIF-62\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">Nat.&nbsp;Mater.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">ZIF-62\u7684\u6676\u6001\u3001\u56fa\u6001-\u975e\u6676\u6001\u548c\u6db2\u6001\u7684\u7a33\u5b9a\u573a\u5982\u56fe2a\u6240\u793a\u3002\u5728\u5e38\u538b\u4e0b\uff0cZIF-62\u7ed3\u6784\u5728\u7ea6320&nbsp;\u2103\u4e0b\u53d8\u4e3a\u975e\u6676\u6001\uff08\u56fe2a\uff09\uff0c\u8fd9\u4e5f\u4e0e\u5148\u524d\u7684\u7814\u7a76\u7ed3\u679c\u76f8\u7b26\u3002\u5728\u9ad8\u538b\u548c\u5e38\u6e29\u4e0b\uff0c\u7ea65&nbsp;GPa\u65f6\u6846\u67b6\u5f00\u59cb\u53d1\u751f\u975e\u6676\u5316\uff08\u56fe2c\uff09\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u4ec5\u542b\u6709\u672a\u53d6\u4ee3\u7684\u54aa\u5511\u914d\u4f53\u4e14\u62d3\u6251\u7ed3\u6784\u76f8\u540c\u7684ZIF-4\uff0c\u5728\u7ea61&nbsp;GPa\u4e0b\u5c31\u4f1a\u53d1\u751f\u53ef\u9006\u7684\u538b\u529b\u8bf1\u5bfc\u975e\u6676\u5316\u3002\u8fd9\u4e24\u79cdZIF\u5728\u5e38\u6e29\u4e0b\u7684\u9ad8\u538b\u7a33\u5b9a\u6027\u7684\u663e\u8457\u5dee\u5f02\uff0c\u53ef\u80fd\u4e0eZIF-62\u4e2d\u5b58\u5728\u7684\u7a7a\u95f4\u4f4d\u963b\u66f4\u5927\u7684\u82ef\u5e76\u54aa\u5511\uff08bIm\uff09\u8fde\u63a5\u4f53\u6709\u5173\uff0c\u8fd9\u4e9b\u8fde\u63a5\u4f53\u4f38\u5165MOF\u7684\u5b54\u8154\u63d0\u9ad8\u7a33\u5b9a\u6027\u4ee5\u9632\u6b62\u6846\u67b6\u574d\u584c\u3002\u5728ZIF-62\u4e2d\uff0c\u538b\u529b\u8bf1\u5bfc\u7684\u975e\u6676\u5316\u4e0e\u6e29\u5ea6\u8bf1\u5bfc\u7684\u975e\u6676\u5316\u5728\u672c\u8d28\u4e0a\u5e76\u4e0d\u76f8\u540c\u3002\u540c\u6b65\u52a0\u901f\u5668\u9ad8\u538b\u7c89\u672b\u884d\u5c04\u5b9e\u9a8c\u8bc1\u660e\u538b\u529b\u8bf1\u5bfc\u7684\u975e\u6676\u5316\u53d1\u751f\u57285&nbsp;GPa\uff0c\u8fd9\u79cd\u975e\u6676\u6001\u5728\u51cf\u538b\u65f6\u8fd8\u4f1a\u8fd8\u539f\u4e3a\u8d77\u59cb\u6676\u76f8\uff0c\u56e0\u6b64\u538b\u529b\u8bf1\u5bfc\u7684\u975e\u6676\u5316\u4f5c\u7528\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u4f4d\u79fb\u76f8\u53d8\u3002\u800cZIF-62\u6e29\u5ea6\u8bf1\u5bfc\u7684\u975e\u6676\u5316\u5374\u662f\u4e0d\u53ef\u9006\u7684\uff0c\u8fd9\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u91cd\u5efa\u76f8\u53d8\u3002<\/p>\n<p style=\"text-align: center;\"><img class=\"rich_pages\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/10-1555471008.jpeg\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe3.&nbsp;\uff08a\uff09ZIF-62\u57fa\u4e8e\u538b\u529b\u548c\u6e29\u5ea6\u53d8\u5316\u7684\u6676\u80de\u53c2\u6570\u56fe\u3002<\/span><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\uff08b\uff09\u771f\u7a7a\u4e0b\u7684\u70ed\u81a8\u80c0\u3002<\/span><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\uff08c\uff09ZIF-62\u73bb\u7483\u4e8c\u6c27\u5316\u78b3\u5438\u9644\u66f2\u7ebf\u3002<\/span><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe\u7247\u6765\u6e90\uff1a<\/span><em><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">Nat.&nbsp;Mater.<\/span><\/em><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u4f5c\u8005\u63a5\u7740\u4ece\u540c\u6b65\u8f90\u5c04\u548cX-\u5c04\u7ebf\u7c89\u672b\u884d\u5c04\u6570\u636e\u4e2d\u7cbe\u4fee\u51fa\u4e86ZIF-62\u6676\u4f53\u7684\u6e29\u5ea6\u548c\u538b\u529b\u76f8\u5173\u6676\u683c\u53c2\u6570\u3002\u56fe3a\u663e\u793a\u4e86ZIF-62\u5728<em>P-T&nbsp;<\/em>\u533a\u95f4\u4e2d\u7684\u6676\u80de\u53c2\u6570\u4e0e\u5355\u4e00\u538b\u529b\u548c\u6e29\u5ea6\u76f8\u5173\u3002\u4ece\u5ba4\u6e29\u5230270&nbsp;\u2103\u7684\u52a0\u70ed\u8fc7\u7a0b\u4e2d\uff0c\u6676\u80de\u663e\u793a\u51c6\u7ebf\u6027\u4f53\u79ef\u81a8\u80c0\uff0c\u5728270&nbsp;\u2103\u65f6\u5f00\u59cb\u574d\u584c\uff0c\u5728320&nbsp;\u2103\u5b8c\u6210\u975e\u6676\u5316\uff08\u56fe3b\uff09\u3002\u5ba4\u6e29\u4e0b\u7684\u9759\u6c34\u538b\u7f29\u5b9e\u9a8c\u8868\u660e\uff0c\u6676\u4f53\u7684<em>c&nbsp;<\/em>\u8f74\u662f\u6700\u4e0d\u53ef\u538b\u7f29\u7684\u65b9\u5411\u3002\u5728\u771f\u7a7a\u6761\u4ef6\u4e0b\uff0c\u6676\u4f53\u7684<em>c<\/em>\u8f74\u65e0\u53d8\u5316\uff0c\u6cbf<em>a&nbsp;<\/em>\u8f74\u663e\u793a\u8f83\u5c0f\u7684\u70ed\u6536\u7f29\uff0c\u800c\u6cbf<em>b&nbsp;<\/em>\u8f74\u663e\u793a\u660e\u663e\u7684\u70ed\u81a8\u80c0\uff0c\u800c\u8fd9\u79cd\u6781\u7aef\u7684\u5404\u5411\u5f02\u6027\u884c\u4e3a\u53ef\u4ee5\u4ece\u76f8\u4e92\u8fde\u63a5\u7684\u950c\u4f4d\u70b9\u5f62\u6210\u7684\u73af\u72b6\u62d3\u6251\u7ed3\u6784\u4e2d\u5f97\u5230\u89e3\u91ca\u3002273&nbsp;K\u65f6\u7684\u4e8c\u6c27\u5316\u78b3\u7684\u5438\u9644\u884c\u4e3a\uff0c\u8bc1\u5b9e\u4e86ZIF-62\u73bb\u7483\u7684\u6c38\u4e45\u6027\u591a\u5b54\u7ed3\u6784\u3002\u8be5\u6750\u6599\u57281&nbsp;bar\u7684\u538b\u529b\u4e0b\u7684\u53ef\u9006\u5438\u9644\u91cf\u7ea6\u4e3a3.8&nbsp;wt%\u3002FPMD\u6a21\u62df\u8868\u660e\uff0c\u591a\u5b54\u6846\u67b6\u5728\u52a0\u538b\u65f6\u914d\u4f4d\u952e\u7684\u8f6f\u5316\u610f\u5473\u7740\u53d7\u538b\u60c5\u51b5\u4e0b\u6846\u67b6\u7684\u7194\u5316\u5728\u70ed\u529b\u5b66\u4e0a\u66f4\u5bb9\u6613\u53d1\u751f\uff0c\u8fd9\u5728\u56fa\u4f53\u4e2d\u5176\u5b9e\u5e76\u4e0d\u5e38\u89c1\uff0c\u5728\u5176\u4ed6\u56fa\u6001\u6750\u6599\u4e2d\u5916\u90e8\u538b\u529b\u5f80\u5f80\u4f1a\u6291\u5236\u7194\u5316\u3002<\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\">\u7efc\u4e0a\uff0c\u9ad8\u6e29\u3001\u9ad8\u538b\u4e0b\u7684\u7cfb\u5217\u7814\u7a76\u8868\u660e\uff0cMOF\u6750\u6599\u7684\u7194\u70b9\u53ef\u4ee5\u5728\u538b\u529b\u589e\u52a0\u7684\u60c5\u51b5\u4e0b\u663e\u8457\u964d\u4f4e\uff0c\u8fd9\u6709\u52a9\u4e8e\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5236\u5907\u5177\u6709\u6c38\u4e45\u6027\u591a\u5b54\u7ed3\u6784\u7684MOF\u73bb\u7483\uff0c\u4ece\u800c\u907f\u514d\u5e38\u538b\u4e0b\u52a0\u70ed\u6e29\u5ea6\u592a\u9ad8\u800c\u5bfc\u81f4\u7684\u5206\u89e3\u3002\u8fd9\u4e00\u7814\u7a76\u5c06\u805a\u5408\u7269\u5316\u5b66\u4e0e\u77ff\u7269\u5b66\u8054\u7cfb\u8d77\u6765\uff0c\u53ef\u6307\u5bfc\u521b\u9020\u66f4\u591a\u529f\u80fd\u6027\u6750\u6599\u3002<\/p>\n<p><br  \/><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762<\/span><span style=\"font-size: 14px;\">\uff09\uff1a<\/span><\/p>\n<p><span style=\"font-size: 14px;\"><\/span><img class=\"rich_pages\"       style=\"text-align: left;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/3-1555471008.jpeg\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Pressure promoted low-temperature melting of metal-organic frameworks<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">Nat.&nbsp;Mater.<\/span><\/em><span style=\"font-size: 14px;\">,&nbsp;<strong>2019<\/strong>,&nbsp;<em>18<\/em>,&nbsp;370\u2013376,&nbsp;DOI:<\/span><span style=\"font-size: 14px;\">&nbsp;10.1038\/s41563-019-0317-4<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: right;\"><span style=\"font-size: 16px;\">\uff08\u672c\u6587\u7531<strong>\u53f6\u821e\u77e5\u79cb<\/strong>\u4f9b\u7a3f\uff09<\/span><\/p>\n<p><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657607803&amp;idx=2&amp;sn=0ae58a9d5ee3da4d5b7e6428662d19f8&amp;chksm=80f7c9abb78040bd88223e7ce0e1ff884b265e03a57b28d9a8bbb273b7dc8ebf92414828b4a1&amp;scene=21#wechat_redirect\" target=\"_blank\"  ><span style=\"top: auto;left: auto;right: auto;bottom: auto;\"><span class=\"js_jump_icon h5_image_link\"  style=\"top: auto;left: auto;margin: 0px;right: auto;bottom: auto;\"><img class=\"\"          style=\"height: 116px;width: 556px;top: auto;left: auto;right: auto;bottom: auto;margin: 0px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/8-1555471008.jpeg\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/span><\/span><\/a><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/6-1555471009.png\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;overflow-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/p>\n<p style=\"box-sizing: border-box;\"><br style=\"box-sizing: border-box;\"  \/><\/p>\n<p style=\"box-sizing: border-box;\"><span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">\u957f\u6309<\/strong><\/span>\u4e0b\u56fe<strong style=\"box-sizing: border-box;\">\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/p>\n<\/section>\n<\/section>\n<\/section>\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<p style=\"margin-top: 10px;margin-bottom: 10px;text-align: center;box-sizing: border-box;\"><img class=\"\"     style=\"vertical-align: middle;box-sizing: border-box;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2019\/04\/4-1555471009.jpeg\" alt=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\" title=\"\u7194\u878d\u540e\u8fd8\u80fd\u5f62\u6210\u591a\u5b54\u7ed3\u6784\uff1f\u65b0\u578bMOF\u73bb\u7483\"  \/><\/p>\n<\/section>\n<\/section>\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-bottom: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-bottom: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-top-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section style=\"white-space: normal;\">\n<section >\n<section>\n<section>\n<section>\n<section >\n<section>\n<section>\n<p style=\"text-align: center;\"><br  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;overflow-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 17px;box-sizing: border-box !important;overflow-wrap: break-word !important;\">\u70b9\u51fb\u201c<span style=\"max-width: 100%;color: rgb(0, 122, 170);\">\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b&nbsp;<strong>\u5316\u5b66 \u2022 \u6750\u6599&nbsp;<\/strong>\u9886\u57df<span style=\"max-width: 100%;background-color: rgb(255, 218, 81);\">\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;overflow-wrap: break-word !important;\">\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u662f\u5f53\u524d\u6750\u6599\u9886\u57df\u7684\u4e00\u4e2a\u7814\u7a76\u70ed\u95e8\uff0c\u5230\u76ee\u524d\u4e3a\u6b62\u6709\u5f62\u5f62\u8272\u8272\u8fd16\u4e07\u79cdMOF\u88ab\u62a5\u9053\uff0c\u5b83\u4eec\u5728\u6c14\u4f53\u5438\u9644\u548c [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":84917,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/84916"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=84916"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/84916\/revisions"}],"predecessor-version":[{"id":84926,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/84916\/revisions\/84926"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/84917"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=84916"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=84916"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=84916"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}