{"id":84941,"date":"2019-04-15T00:00:50","date_gmt":"2019-04-17T03:16:57","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/84941\/"},"modified":"2019-04-17T11:16:59","modified_gmt":"2019-04-17T03:16:59","slug":"1bc4ccec5c","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/84941\/","title":{"rendered":"\u3010\u6750\u6599\u3011\u5b9e\u73b0NASICON\u7ed3\u6784Na3MnTi(PO4)3\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94"},"content":{"rendered":"
\n

\"\u3010\u6750\u6599\u3011\u5b9e\u73b0NASICON\u7ed3\u6784Na3MnTi(PO4)3\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\"<\/span><\/a><\/p>\n


<\/p>\n

\u7531\u4e8e\u94a0\u8d44\u6e90\u4e30\u5bcc\u3001\u5206\u5e03\u5e7f\u6cdb\u3001\u6210\u672c\u4f4e\u5ec9\uff0c\u4e14\u94a0\u79bb\u5b50\u5177\u6709\u4e0e\u9502\u79bb\u5b50\u76f8\u4f3c\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u4f7f\u5f97\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIB\uff09\u5728\u50a8\u80fd\u9886\u57df\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u524d\u666f\uff0c\u6210\u4e3a\u5927\u89c4\u6a21\u7535\u7f51\u50a8\u80fd\u6700\u5177\u524d\u666f\u7684\u9009\u62e9\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u7531\u4e8eNa+<\/sup><\/span>\u7684\u79bb\u5b50\u534a\u5f84\u5927\uff0c\u5728\u5176\u5d4c\u5165\u548c\u8131\u51fa\u65f6\u901a\u5e38\u4f34\u968f\u7740\u8f83\u5927\u7684\u4f53\u79ef\u53d8\u5316\u548c\u52a8\u529b\u5b66\u8fc7\u7a0b\u7f13\u6162\u7b49\u95ee\u9898\uff0c\u5f00\u53d1\u9002\u5408\u94a0\u79bb\u5b50\u50a8\u5b58\u7684\u7535\u6781\u6750\u6599\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n


<\/p>\n

\u4f17\u6240\u5468\u77e5\uff0cNa3<\/sub><\/span>V2<\/sub><\/span>(PO4<\/sub><\/span>)3<\/sub><\/span>\u662f\u4e00\u79cd\u53ef\u5b9e\u73b0\u94a0\u79bb\u5b50\u5feb\u901f\u8131\u5d4c\u7684NASICON\u7ed3\u6784\u7535\u6781\u6750\u6599\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u8005\u5728\u6b64\u57fa\u7840\u4e0a\u5df2\u5f00\u53d1\u51fa\u4e86\u4e00\u7cfb\u5217\u66f4\u52a0\u5ec9\u4ef7\u548c\u5b89\u5168\u73af\u4fdd\u7684NASICON\u7ed3\u6784\u7535\u6781\u6750\u6599\uff08Na3<\/sub><\/span>Fe2<\/sub><\/span>(PO4<\/sub><\/span>)3<\/sub><\/span>\u3001Na3<\/sub><\/span>MnTi(PO4<\/sub><\/span>)3<\/sub><\/span>\u3001Na3<\/sub><\/span>MgTi(PO4<\/sub><\/span>)3<\/sub><\/span>\u7b49\uff09\u3002\u7136\u800c\uff0c\u4e0a\u8ff0NASICON\u7ed3\u6784\u5316\u5408\u7269\u5728\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\u6d89\u53ca\u7684\u7535\u5b50\u5f97\u5931\u6570\u5927\u591a\u4e3a2\uff0c\u7406\u8bba\u5bb9\u91cf\u4e00\u822c\u5728130 mAh\u2022g-1<\/sup><\/span>\u4ee5\u4e0b\u3002\u8fd1\u65e5\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66<\/strong>\u7684\u9ea6\u7acb\u5f3a<\/strong>\u6559\u6388\u548c\u5468\u4eae<\/strong>\u6559\u6388\u56e2\u961f\u5229\u7528\u55b7\u96fe\u5e72\u71e5\u8f85\u52a9\u5408\u6210\u6cd5\u5236\u5907\u4e86\u4e00\u79cdNa3<\/sub><\/span>MnTi(PO4<\/sub><\/span>)3<\/sub><\/span>\/C\u4e2d\u7a7a\u5fae\u7403\u5e76\u5c06\u5176\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u7814\u7a76<\/strong>\u3002\u4e0e\u4f20\u7edfNASICON\u7ed3\u6784\u5316\u5408\u7269\u76f8\u6bd4\uff0c\u8be5\u6750\u6599\u5b9e\u73b0\u4e86\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u6bd4\u5bb9\u91cf\u8fbe\u5230160 mAh\u2022g-1<\/sup><\/span>\uff08\u7406\u8bba\u5bb9\u91cf\u7ea6176 mAh\u2022g-1<\/sup><\/span>\uff09\uff0c\u540c\u65f6\u5faa\u73af\u7a33\u5b9a\u6027\u4e5f\u5f97\u5230\u5927\u5e45\u5ea6\u63d0\u5347\u3002<\/p>\n

\"\u3010\u6750\u6599\u3011\u5b9e\u73b0NASICON\u7ed3\u6784Na3MnTi(PO4)3\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\"<\/p>\n


<\/p>\n

\u901a\u8fc7\u55b7\u96fe\u5e72\u71e5\u8f85\u52a9\u5408\u6210\u6cd5\u5236\u5907\u7684Na3<\/sub><\/span>MnTi(PO4<\/sub><\/span>)3<\/sub><\/span>\/C\uff08NMTP\/C\uff09\u57282.1\u30013.5\u548c4.0 V\uff08vs. Na+<\/sup><\/span>\/Na\uff09\u8868\u73b0\u51fa\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u5206\u522b\u5bf9\u5e94\u4e8eTi4+<\/sup><\/span>\/Ti3+<\/sup><\/span>\u3001Mn3+<\/sup><\/span>\/Mn2+<\/sup><\/span>\u548cMn4+<\/sup><\/span>\/Mn3+<\/sup><\/span>\u6c27\u5316\u8fd8\u539f\u7535\u5bf9\u3002\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u8d4b\u4e88NMTP\/C 160 mAh\u2022g-1<\/sup><\/span>\u7684\u9ad8\u6bd4\u5bb9\u91cf\uff0c\u7a33\u5b9a\u548c\u5f00\u653e\u7684NASICON\u6846\u67b6\u786e\u4fdd\u4e86NMTP\/C\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff082 C\u4e0b500\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a92 %\uff09\u3002\u4ed6\u4eec\u901a\u8fc7\u539f\u4f4dXRD\u5bf9\u6750\u6599\u7684\u50a8\u94a0\u673a\u7406\u8fdb\u884c\u63a2\u7a76\uff0c\u53d1\u73b0\u8be5\u6750\u6599\u5728\u8fdb\u884c\u7a33\u5b9a\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u65f6\u56fa\u6eb6\u4e0e\u4e24\u76f8\u53cd\u5e94\u540c\u65f6\u53d1\u751f\u3002Na+<\/sup><\/span>\u8131\u5d4c\u793a\u610f\u56fe\u5c55\u793a\u4e86\u7b2c\u4e00\u5708\u4ee5\u53ca\u968f\u540e\u5145\u653e\u7535\u8fc7\u7a0b\u4e2dNMTP\/C\u7684\u7ed3\u6784\u53d8\u5316\u3002\u9274\u4e8e\u5176\u4f18\u5f02\u7684\u534a\u7535\u6c60\u6027\u80fd\uff0c\u4f5c\u8005\u53c8\u7ec4\u88c5\u4e86NMTP\/C-650\/\/\u78b3\u94a0\u79bb\u5b50\u5168\u7535\u6c60\uff0c\u57280.5 C\u65f6\u5177\u6709139 mAh\u2022g-1<\/sup><\/span>\uff08\u57fa\u4e8e\u6b63\u6781\u6750\u6599\u7684\u8d28\u91cf\uff09\u7684\u6bd4\u5bb9\u91cf\u3002\u8fd9\u4e00\u7814\u7a76\u6210\u679c\u5bf9\u63a2\u7d22\u65b0\u578bNASICON\u7ed3\u6784\u7535\u6781\u6750\u6599\u4ee5\u5b9e\u73b0\u591a\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\"\u3010\u6750\u6599\u3011\u5b9e\u73b0NASICON\u7ed3\u6784Na3MnTi(PO4)3\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\"<\/p>\n


<\/p>\n

\u8be5\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728Advanced Energy Materials <\/em><\/strong><\/span>\u4e0a\uff0c\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u7684\u535a\u58eb\u7814\u7a76\u751f\u6731\u5a77<\/strong>\u3002<\/p>\n


<\/p>\n

\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/p>\n

Ting Zhu, Ping Hu, Xuanpeng Wang, Zhenhui Liu, Wen Luo, Kwadwo Asare Owusu, Weiwei Cao, Changwei Shi, Jiantao Li, Liang Zhou, Liqiang Mai<\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"\u3010\u6750\u6599\u3011\u5b9e\u73b0NASICON\u7ed3\u6784Na3MnTi(PO4)3\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\"<\/p>\n

Realizing Three-Electron Redox Reactions in NASICON-Structured Na<\/span>3<\/sub><\/span>MnTi(PO<\/span>4<\/sub>)<\/span>3<\/sub><\/span> <\/sub>for Sodium-Ion Batteries<\/span><\/p>\n

Adv. Energy Mater.<\/span><\/em>, 2019<\/strong>, DOI:10.1002\/aenm.201803436<\/span><\/p>\n


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\u9ea6\u7acb\u5f3a\u6559\u6388\u4ecb\u7ecd<\/strong><\/p>\n


<\/strong><\/p>\n

\"\u3010\u6750\u6599\u3011\u5b9e\u73b0NASICON\u7ed3\u6784Na3MnTi(PO4)3\u9ad8\u5ea6\u53ef\u9006\u7684\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\"<\/p>\n

\u9ea6\u7acb\u5f3a\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u79d1\u9996\u5e2d\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u9662\u957f\u3001\u6559\u80b2\u90e8\u201c\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\u201d\uff082016\u5e74\u5ea6\uff09\u3001\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u201c\u7eb3\u7c73\u79d1\u6280\u201d\u91cd\u70b9\u4e13\u9879\u603b\u4f53\u4e13\u5bb6\u7ec4\u6210\u5458\u3001\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u5b66\u4f1a\u4f1a\u58eb\uff08Fellow of the Royal Society of Chemistry\uff09\uff1b2004\u5e74\u5728\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u83b7\u5de5\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u968f\u540e\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\u7f8e\u56fd\u4f50\u6cbb\u4e9a\u7406\u5de5\u5b66\u9662\u738b\u4e2d\u6797\u6559\u6388\u8bfe\u9898\u7ec4\u3001\u7f8e\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u54c8\u4f5b\u5927\u5b66Charles M. Lieber\u6559\u6388\u8bfe\u9898\u7ec4\u3001\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u6768\u57f9\u4e1c\u6559\u6388\u8bfe\u9898\u7ec4\u4ece\u4e8b\u535a\u58eb\u540e\u53ca\u9ad8\u7ea7\u7814\u7a76\u5b66\u8005\u7814\u7a76\uff1b\u957f\u671f\u4ece\u4e8b\u7eb3\u7c73\u80fd\u6e90\u6750\u6599\u4e0e\u5668\u4ef6\u7814\u7a76\uff0c\u53d1\u8868SCI\u8bba\u6587300\u4f59\u7bc7\uff0c\u5305\u62ecNature<\/em>\u53ca\u5176\u5b50\u520a11\u7bc7\uff0cChem. Rev.\u3001Chem. Soc. Rev.\u3001Acc. Chem. Res.\u3001Energy Environ. Sci.\u3001Chem<\/em>.\u54041\u7bc7\uff0cAdv. Mater.<\/em>14\u7bc7\uff0cJ. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001PNAS\u3001Joule<\/em>\u54042\u7bc7\uff0cNano Lett. <\/em>25\u7bc7\uff0c\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u5728\u5f71\u54cd\u56e0\u5b5010.0\u4ee5\u4e0a\u7684\u671f\u520a\u53d1\u8868\u8bba\u6587100\u4f59\u7bc7\uff0c55\u7bc7\u8bba\u6587\u5165\u9009ESI\u8fd1\u5341\u5e74\u9ad8\u88ab\u5f15\u8bba\u6587\uff0c11\u7bc7\u5165\u9009ESI\u5168\u7403TOP 0.1%\u70ed\u70b9\u8bba\u6587\uff0c\u83b7\u6388\u6743\u56fd\u5bb6\u53d1\u660e\u4e13\u5229100\u4f59\u9879\uff1b\u4e3b\u6301\/\u627f\u62c5\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u7a76\u8ba1\u5212\u3001\u56fd\u5bb6\u56fd\u9645\u79d1\u6280\u5408\u4f5c\u4e13\u9879\u3001\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\u7b4930\u4f59\u9879\u79d1\u7814\u9879\u76ee\uff1b\u83b7\u4e2d\u56fd\u9752\u5e74\u79d1\u6280\u5956\u3001\u5149\u534e\u5de5\u7a0b\u79d1\u6280\u5956\uff08\u9752\u5e74\u5956\uff09\u3001\u6e56\u5317\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\u3001\u4faf\u5fb7\u699c\u5316\u5de5\u79d1\u5b66\u6280\u672f\u5956\uff08\u9752\u5e74\u5956\uff09\u30012018\u5e74\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u4e0e\u6280\u672f\u5927\u4f1a\u5353\u8d8a\u7814\u7a76\u5956\uff08EEST2018 Research Excellence Award\uff09\u3001Nanoscience Research Leader\u5956\uff0c\u5165\u9009\u56fd\u5bb6\u201c\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u8ba1\u5212\u201d\u3001\u79d1\u6280\u90e8\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\u8ba1\u5212\u3001\u6559\u80b2\u90e8\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u8ba1\u5212\uff0c\u5e76\u88ab\u6388\u4e88\u201c\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u201d\u8363\u8a89\u79f0\u53f7\uff0c\u4eab\u53d7\u56fd\u52a1\u9662\u653f\u5e9c\u7279\u6b8a\u6d25\u8d34\uff1b\u5165\u90092017\u5e74\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1aTop 1%\u9ad8\u88ab\u5f15\u4e2d\u56fd\u4f5c\u8005\uff0c\u6307\u5bfc\u5b66\u751f\u83b7\u201c\u4e2d\u56fd\u9752\u5c11\u5e74\u79d1\u6280\u521b\u65b0\u5956\u201d\uff083\u5c4a\uff09\uff0c\u5168\u56fd\u5927\u5b66\u751f\u201c\u6311\u6218\u676f\u201d\u7279\u7b49\u5956\uff081\u5c4a\uff09\u3001\u4e00\u7b49\u5956\uff082\u5c4a\uff09\u3001\u4e8c\u7b49\u5956\uff084\u5c4a\uff09\uff0c\u4e2d\u56fd\u5927\u5b66\u751f\u81ea\u5f3a\u4e4b\u661f\u6807\u5175\uff081\u5c4a\uff09\u548c2014\u5e74\u5927\u5b66\u751f\u201c\u5c0f\u5e73\u79d1\u6280\u521b\u65b0\u56e2\u961f\u201d \u7b49\uff1b\u4efbAdv. Mater.<\/em>\u5ba2\u5ea7\u7f16\u8f91\uff0cAcc. Chem. Res.\u3001Joule\u3001ACS Energy Lett.\u3001Adv. Electron. Mater.<\/em>\u56fd\u9645\u7f16\u59d4\uff0cNano Res.\u3001Sci. China Mater.<\/em>\u7f16\u59d4\u3002
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\u9ea6\u7acb\u5f3a<\/span><\/p>\n

https:\/\/www.x-mol.com\/university\/faculty\/26717<\/span><\/p>\n

\u8bfe\u9898\u7ec4\u94fe\u63a5<\/span><\/p>\n

http:\/\/mai.group.whut.edu.cn<\/span><\/p>\n

\u8bfe\u9898\u7ec4\u5fae\u4fe1\u516c\u4f17\u53f7\uff1aMLQ_group<\/span><\/p>\n


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\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/p>\n


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\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/p>\n<\/section>\n<\/section>\n<\/section>\n

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