{"id":85114,"date":"2019-04-13T00:00:50","date_gmt":"2019-04-17T03:18:12","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/85114\/"},"modified":"2019-04-17T11:18:14","modified_gmt":"2019-04-17T03:18:14","slug":"2d08671eda","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/85114\/","title":{"rendered":"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50"},"content":{"rendered":"
\n

\"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50\"<\/span><\/a><\/p>\n


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\u6700\u65e9\u671f\u7684\u91d1\u5c5e\u6709\u673a\u5316\u5408\u7269\u662f1827\u5e74\u5408\u6210\u7684Zeise\u76d0[KPtCl3<\/sub><\/span>(CH2<\/sub><\/span>=CH2<\/sub><\/span>)]\u548c1849\u5e74\u82f1\u56fd\u5316\u5b66\u5bb6Frankland\u5f97\u5230\u7684\u4e8c\u4e59\u57fa\u950c\uff08ZnEt2<\/sub><\/span>\uff09\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u7684\u53d1\u5c55\u5728\u6574\u4e2a\u5341\u4e5d\u4e16\u7eaa\u9887\u4e3a\u7f13\u6162\u3002\u4e8c\u5341\u4e16\u7eaa\u521d\u671f\uff0c\u6cd5\u56fd\u79d1\u5b66\u5bb6Grignard\u6210\u529f\u5236\u5907\u4e86\u70c3\u57fa\u5364\u5316\u9541\uff0c\u5373\u5927\u540d\u9f0e\u9f0e\u7684\u201c\u683c\u6c0f\u8bd5\u5242\u201d\uff0c\u63a8\u52a8\u4e86\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u7684\u53d1\u5c55\u3002\u53e6\u4e00\u4e2a\u91cd\u8981\u7684\u91cc\u7a0b\u7891\u662f\u4e8c\u8302\u94c1\u201c\u5939\u5fc3\u7ed3\u6784\u201d\u7684\u53d1\u73b0\u3002\u591a\u79cd\u591a\u6837\u5e26\u6709\u4e0d\u540c\u53d6\u4ee3\u57fa\u7684\u73af\u620a\u4e8c\u70ef\u57fa\uff08\u8302\u57fa\uff09\u914d\u4f53\u88ab\u666e\u904d\u5e94\u7528\u4e8e\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u7684\u65b9\u65b9\u9762\u9762\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4e0d\u80dc\u679a\u4e3e\u7684\u8302\u57fa\u7a33\u5b9a\u7684\u201c\u534a\u5939\u5fc3\u7ed3\u6784\u201d\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u4e5f\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u548c\u62a5\u9053\uff08\u56fe1a\uff09\u3002\u7136\u800c\uff0c\u8302\u57fa\u914d\u4f53\u7528\u4e8e\u5408\u6210\u65b0\u9896\u7684\u4e3b\u65cf\u5143\u7d20\u5316\u5408\u7269\u5374\u8f83\u4e3a\u5c11\u89c1\u3002\u5728\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u4e2d\uff0c\u8302\u57fa\u901a\u5e38\u91c7\u7528\u4e94\u914d\u4f4d\uff08\u03b7<\/em>5<\/sup><\/span>\uff09\u7684\u6a21\u5f0f\u4e0e\u4e2d\u5fc3\u91d1\u5c5e\u7edc\u5408\uff1b\u800c\u5728\u4e3b\u65cf\u5143\u7d20\u5316\u5408\u7269\u4e2d\uff0c\u7531\u4e8e\u53d7\u201c\u516b\u9685\u89c4\u5219\u201d\u9650\u5236\uff0c\u53ef\u4ee5\u63d0\u4f9b6\u4e2a\u914d\u4f4d\u7535\u5b50\u7684\u8302\u57fa\u914d\u4f53\u96be\u4ee5\u4e0e\u4ef7\u5c42\u7535\u5b50\u4e30\u5bcc\u7684\u4e3b\u65cf\u5143\u7d20\u4ee5\u03b7<\/em>5<\/sup><\/span>\u7684\u6a21\u5f0f\u952e\u8fde\u3002\u56e0\u6b64\uff0c\u5408\u6210\u03b7<\/em>5<\/sup><\/span>\u914d\u4f4d\u7684\u8302\u57fa\u4e3b\u65cf\u5143\u7d20\u5316\u5408\u7269\u5177\u6709\u5f88\u5927\u6311\u6218\u6027\uff08\u56fe1b\uff09\u3002<\/p>\n

\"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50\"<\/p>\n

\u56fe1. \uff08a\uff09\u8302\u57fa\u914d\u4f53\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\uff0c\uff08b\uff09\u8302\u57fa\u914d\u4f53\u78f7\u7837\u5316\u5408\u7269\u3002<\/span><\/p>\n


<\/p>\n

\u65e9\u671f\u7684\u6587\u732e\u4e2d\u62a5\u9053\uff1a\u4e8c\uff08\u4e94\u7532\u57fa\u73af\u620a\u4e8c\u70ef\u57fa\uff08Cp*\uff09\uff09\u914d\u4f4d\u7684\u78f7\u548c\u7837\u5355\u9633\u79bb\u5b50\u5177\u6709\u626d\u66f2\u7684\u201c\u5939\u5fc3\u7ed3\u6784\u201d\uff08Chem. Eur. J.<\/em>, 2011<\/strong>, 17<\/em>, 12975\uff1bAngew. Chem. Int. Ed<\/em>., 1983<\/strong>, 22<\/em>, 250\uff09\uff0c\u7531\u4e8e\u5143\u7d20\u4e2d\u5fc3\u7f3a\u4e4f\u7a7a\u7684\u4ef7\u5c42\u8f68\u9053\uff0c\u5176\u4e2d\u4e24\u4e2aCp*\u914d\u4f53\u5747\u4e0d\u662f\u4ee5\u03b7<\/em>5<\/sup><\/span>\u7684\u6a21\u5f0f\u4e0e\u4e2d\u5fc3\u5143\u7d20\u952e\u8fde\u3002\u4e3a\u4e86\u79fb\u9664\u201c\u8fc7\u5269\u201d\u7684\u914d\u4f53\u7535\u5b50\uff0c\u4fc3\u4f7f\u8302\u57fa\u4ee5\u03b7<\/em>5<\/sup><\/span>\u6a21\u5f0f\u914d\u4f4d\uff0c\u52a0\u62ff\u5927\u591a\u4f26\u591a\u5927\u5b66<\/strong>\u7684Douglas W. Stephan<\/strong>\u6559\u6388\u8bfe\u9898\u7ec42018\u5e74\u5728Chem <\/em><\/strong>\u4e0a\u62a5\u9053\u4e86\u5229\u7528Cp*PF2<\/sub><\/span><\/span>\u548c[Et3<\/sub><\/span>Si][B(C6<\/sub><\/span>F5<\/sub><\/span>)4<\/sub><\/span>]\u7684\u652b\u6c1f\u53cd\u5e94\uff08fluoride abstraction\uff09\uff0c\u5408\u6210\u4e86\u201c\u534a\u5939\u5fc3\u201d\u7684\u5355Cp*\u914d\u4f4d\u7684\u78f7\u53cc\u9633\u79bb\u5b50[Cp*P<\/strong>]<\/strong>2+<\/sup><\/strong><\/span>\uff08\u56fe2\uff09[1]<\/sup><\/span>\u3002\u78f7\u539f\u5b50\u4e2d\u5fc3\u7b26\u5408\u201c\u516b\u9685\u89c4\u5219\u201d\uff0c\u5e76\u4e14Cp*\u914d\u4f53\u9996\u6b21\u4ee5\u03b7<\/em>5<\/sup><\/span>\u6a21\u5f0f\u4e0e\u78f7\u4e2d\u5fc3\u914d\u4f4d\u3002\u8be5\u78f7\u53cc\u9633\u79bb\u5b50\u4f5c\u4e3a\u9996\u4f8b\u03b7<\/em>5<\/sup><\/span>\u8302\u57fa\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\u7684\u78f7\u7c7b\u4f3c\u7269\uff0c\u663e\u793a\u51fa\u8d85\u5f3a\u7684Lewis\u9178\u6027\u4ee5\u53ca\u591a\u6837\u7684\u914d\u4f53\u9f7f\u5408\u5ea6\u5f02\u6784\u53cd\u5e94\u3002\u76f8\u5173\u6210\u679c\u4e00\u7ecf\u53d1\u8868\uff0c\u5c31\u88abChemistryworld<\/em>\u4ee5\u201cRare phosphorus dication synthesised\u201d\u4e3a\u9898\u8fdb\u884c\u4eae\u70b9\u4ecb\u7ecd [2]<\/sup><\/span>\u3002<\/p>\n

\"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50\"<\/p>\n

\u56fe2. \u5355Cp*\u914d\u4f4d\u7684\u78f7\u53cc\u9633\u79bb\u5b50[Cp*P]<\/span>2+<\/sup><\/span>\u4ee5\u53ca\u5176\u914d\u4f53\u9f7f\u5408\u5ea6\u5f02\u6784\u53cd\u5e94\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span>Chem <\/span><\/em>[1]<\/sup><\/span><\/span><\/p>\n


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\u57fa\u4e8e\u4e0a\u8ff0\u7814\u7a76\u57fa\u7840\uff0c\u8fd1\u671f Stephan\u8bfe\u9898\u7ec4\u5229\u7528\u7c7b\u4f3c\u7684\u7b56\u7565\uff08Cp*AsCl2<\/sub><\/span>\u548c[Et3<\/sub><\/span>Si][B(C6<\/sub><\/span>F5<\/sub><\/span>)4<\/sub><\/span>]\u7684\u652b\u6c2f\u53cd\u5e94\uff09\u6210\u529f\u5408\u6210\u4e86\u03b7<\/em>5<\/sup><\/span>\u914d\u4f4d\u7684\u8302\u57fa\u7837\u53cc\u9633\u79bb\u5b50\u5316\u5408\u7269[Cp*As]2+<\/sup><\/span><\/strong>\u3002[Cp*As]2+<\/sup><\/span>\u5316\u5408\u7269\u662f\u9996\u4f8b\u4e09\u4ef7As\u7684\u8d85\u5f3aLewis\u9178\u5e76\u4e14\u663e\u793a\u51fa\u591a\u6837\u7684\u914d\u4f53\u9f7f\u5408\u5ea6\u5f02\u6784\u53cd\u5e94<\/strong>\u3002\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728Angew. Chem. Int. Ed.<\/strong><\/em>\u6742\u5fd7\u4e0a\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5468\u5409\u4eae<\/strong>\u535a\u58eb\u3002<\/p>\n


<\/p>\n

\u5728\u8be5\u53cc\u9633\u79bb\u5b50\u7684\u56fa\u4f53\u7ed3\u6784\u4e2d\uff08\u56fe3a\uff09\uff0cCp*\u4ee5\u03b7<\/em>5<\/sup><\/span>\u7684\u6a21\u5f0f\u4e0eAs\u76f8\u8fde\uff0c\u4e00\u4e2a\u4e2d\u6027\u7684\u7532\u82ef\u6eb6\u5242\u5206\u5b50\u4e0eAs\u6709\u76f8\u4e92\u4f5c\u7528\uff0c\u6697\u6307\u5176\u5f3a\u7684Lewis\u9178\u6027\u3002Intrinsic bond orbital\uff08IBO\uff09\u5206\u6790\u8868\u660e[Cp*As]2+<\/sup><\/span>\u7684\u6210\u952e\u6a21\u5f0f\u548c\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269[(Cp*)Ir(OH2<\/sub><\/span>)3<\/sub><\/span>]2+<\/sup><\/span>\u7c7b\u4f3c\uff08\u56fe3b\uff09\uff0c\u5373\u5177\u6709[As]3+<\/sup><\/span>\u548c[Cp*]–<\/sup><\/span>\u4ee5\u03b7<\/em>5<\/sup><\/span>\u7684\u6a21\u5f0f\u952e\u8fde\u7684\u7279\u5f81\u3002<\/p>\n

\"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50\"<\/p>\n

\u56fe3. \uff08a\uff09[Cp*As]<\/span>2+<\/sup><\/span>\u53cc\u9633\u79bb\u5b50\u7684\u56fa\u4f53\u7ed3\u6784\uff0c\uff08b\uff09[Cp*As]<\/span>2+<\/sup><\/span>\u7684IBO\u8f68\u9053\u3002\u56fe\u7247\u6765\u6e90\uff1a<\/span>Angew. Chem. Int. Ed<\/span><\/em>.<\/span><\/p>\n


<\/p>\n

\u5728Lewis\u9178\u4e2d\uff0c\u62e5\u6709\u6bd4\u4e94\u6c1f\u5316\u9511\uff08SbF5<\/sub><\/span>\uff09\u66f4\u5f3a\u4eb2\u6c1f\u6027\u7684\u5316\u5408\u7269\u88ab\u79f0\u4e3a\u8d85\u5f3aLewis\u9178\u3002[Cp*As]2+<\/sup><\/span>\u53cc\u9633\u79bb\u5b50\u5316\u5408\u7269\u53ef\u4ee5\u4ece\u516d\u6c1f\u5316\u9511\u9634\u79bb\u5b50\u4e2d\u652b\u53d6\u6c1f\u79bb\u5b50\uff0c\u5f62\u6210[(\u03b7<\/em>2<\/sup><\/span>-Cp*)AsF]+<\/sup><\/span>\uff0c\u8868\u660e\u4e86\u5176\u8d85\u5f3aLewis\u9178\u6027\uff0c\u5373\u9996\u4f8b\u4e09\u4ef7As\u7684\u8d85\u5f3aLewis\u9178\u3002\u53e6\u5916\uff0c\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u5728[Cp*As]2+<\/sup><\/span>\u4e0e\u8054\u5421\u5576\u7684\u53cd\u5e94\u4e2d\uff0cCp*\u914d\u4f53\u8868\u73b0\u51fa\u591a\u53d8\u7684\u914d\u4f4d\u6a21\u5f0f\uff08\u56fe4\uff09\u3002<\/p>\n

\"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50\"<\/p>\n

\u56fe4. \uff08a\uff09[Cp*As]<\/span>2+<\/sup><\/span>\u4e0e2,2\u2019-\u8054\u5421\u5576\u548c\u56db\u6c22\u544b\u5583\u7684\u53cd\u5e94\uff0c\uff08b\uff09\u4ea7\u7269\u56fa\u4f53\u7ed3\u6784\u8868\u5f81\u3002<\/span>\u56fe\u7247\u6765\u6e90\uff1a<\/span>Angew. Chem. Int. Ed.<\/span><\/em><\/p>\n


<\/p>\n

\u8fd1\u5341\u5e74\u6765\uff0cStephan\u6559\u6388\u63d0\u51fa\u7684\u53d7\u963b\u8def\u6613\u65af\u9178\u78b1\u5bf9\uff08Frustrated Lewis Pair, FLP\uff09\u5316\u5b66\u6210\u4e3a\u4e00\u4e2a\u65b0\u5174\u9886\u57df\u3002\u5728[Cp*As]2+<\/sup><\/span>\u4e0e\u56db\u6c22\u544b\u5583\u7684\u53cd\u5e94\u4e2d\uff0cLewis\u9178\u6027\u7684As\u4e2d\u5fc3\u4e0eLewis\u78b1\u6027\u7684\u56db\u6c22\u544b\u5583\u5206\u5b50\u8bf1\u5bfc\u4e86\u53e6\u4e00\u5206\u5b50\u56db\u6c22\u544b\u5583\u7684\u5f00\u73af\u53cd\u5e94\uff08\u56fe4\uff09\uff0c\u8fd9\u4e00\u53cd\u5e94\u8868\u660e\u4e86[Cp*As]2+<\/sup><\/span>\u5728FLP\u5316\u5b66\u4e2d\u7684\u6f5c\u5728\u5e94\u7528\u3002<\/p>\n


<\/p>\n

\u6709\u610f\u601d\u7684\u662f\uff0c[Cp*As]2+<\/sup><\/span>\u8fd8\u80fd\u4e0e\u81a6\u5316\u5408\u7269\u53d1\u751f\u610f\u6599\u4e4b\u5916\u7684\u53cd\u5e94\uff08\u56fe5\uff09\u3002\u5728\u8fd9\u4e9b\u53cd\u5e94\u4e2d\uff0c\u6240\u6709As\u2212C\u952e\u53d1\u751f\u65ad\u88c2\uff0c\u5206\u522b\u8f6c\u79fb\u4e00\u4ef7[As]+<\/sup><\/span>\u9633\u79bb\u5b50\u548c[Cp*]+<\/sup><\/span>\u9633\u79bb\u5b50\u952e\u8fde\u5230\u81a6\u5316\u5408\u7269\u3002\u8fd9\u4e3a\u6784\u5efa\u542bAs\u5316\u5408\u7269\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50\"<\/p>\n

\u56fe5. [Cp*As]2+<\/sup>\u7684[As]<\/span>+<\/sup><\/span>\u548c[Cp*]<\/span>+<\/sup><\/span>\u79bb\u5b50\u8f6c\u79fb\u53cd\u5e94\u3002\u56fe\u7247\u6765\u6e90\uff1aAngew. Chem. Int. Ed.<\/em><\/span><\/p>\n


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\u81f3\u6b64\uff0cStephan\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u9996\u4f8b\u03b7<\/em>5<\/sup><\/span>-\u8302\u57fa\u914d\u4f53\u7a33\u5b9a\u7684\u8d85\u5f3aLewis\u9178\u6027\u7684\u78f7\u7837\u53cc\u9633\u79bb\u5b50\u5316\u5408\u7269\uff0c\u7b80\u4fbf\u7684\u5408\u6210\u65b9\u6cd5\u4f7f\u5f97\u8be5\u7c7b\u5316\u5408\u7269\u5728Lewis\u9178\u50ac\u5316\u9886\u57df\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u3002\u53e6\u5916\uff0c\u4e0a\u8ff0\u4e24\u4e2a\u53cc\u9633\u79bb\u5b50\u4f5c\u4e3a\u8302\u57fa\u8fc7\u6e21\u91d1\u5c5e\u7684\u78f7\u7837\u7c7b\u4f3c\u7269\uff0c\u867d\u7136\u5177\u6709\u7c7b\u4f3c\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u4f46\u662f\u663e\u793a\u51fa\u6bd4\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u66f4\u5bb9\u6613\u7684\u914d\u4f53\u9f7f\u5408\u5ea6\u5f02\u6784\u53cd\u5e94\u3002\u8be5\u7cfb\u5217\u7814\u7a76\u6210\u679c\u4e3a\u7a33\u5b9a\u9ad8\u6d3b\u6027\u8302\u57fa\u4e3b\u65cf\u5316\u5408\u7269\u5f00\u8f9f\u4e86\u72ec\u7279\u601d\u8def\uff0c\u4e3a\u6784\u5efa\u7f3a\u7535\u5b50\u7684\u4e3b\u65cf\u5143\u7d20\u4e2d\u5fc3\u63d0\u4f9b\u4e86\u5168\u65b0\u624b\u6bb5\uff0c\u5bf9\u4e3b\u65cf\u5316\u5b66\u7684\u57fa\u7840\u7814\u7a76\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n


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\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

<\/span>\"\u201c\u8302\u201d\u5408\u201c\u78f7\u7837\u201d\u4e0d\u79bb\uff1a\u8d85\u5f3aLewis\u9178\u6027\u7684\u8302\u57fa\u78f7\u7837\u53cc\u9633\u79bb\u5b50\"<\/p>\n

The Arene-Stabilized \u03b7<\/em><\/span>5<\/sup><\/span>-Pentamethylcyclopentadienyl Arsenic Dication [(\u03b7<\/em><\/span>5<\/sup><\/span>-Cp*)As(toluene)]<\/span>2+<\/sup><\/span><\/span><\/p>\n

Jiliang Zhou, Liu Leo Liu, Levy L. Cao, Douglas W. Stephan<\/span><\/p>\n

Angew. Chem. Int. Ed.<\/span><\/em>, 2019<\/strong>, 58<\/em>, 5407-5412, DOI: 10.1002\/anie.201902039<\/span><\/p>\n


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\u53c2\u8003\u8d44\u6599\uff1a<\/span><\/p>\n

1. A Phosphorus Lewis Super Acid:<\/span> \u03b7<\/em>5<\/sup>-Pentamethylcyclopentadienyl Phosphorus Dication. Chem<\/em>, 2018<\/strong>, 4<\/em>, 2699-2708<\/span><\/p>\n

https:<\/span>\/\/www.cell.com\/chem\/fulltext\/S2451-9294(18)30391-7<\/span><\/p>\n

2.https:<\/span>\/\/www.chemistryworld.com\/news\/rare-phosphorus-dication-synthesised\/3009617.article<\/span><\/p>\n


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Douglas W. Stephan\u6559\u6388\u7b80\u4ecb<\/strong>\uff1a<\/strong>1980\u5e74\u5728\u52a0\u62ff\u5927\u897f\u5b89\u5927\u7565\u5927\u5b66\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\u30021980-1982\u5e74\u5728\u54c8\u4f5b\u5927\u5b66R. H. Holm\u8bfe\u9898\u7ec4\u8fdb\u884c\u535a\u58eb\u540e\u7814\u7a76\uff0c\u4e4b\u540e\u5728\u52a0\u62ff\u5927\u6e29\u838e\u5927\u5b66\u6210\u4e3a\u52a9\u7406\u6559\u6388\uff0c\u5e76\u4e8e1992\u5e74\u63d0\u5347\u4e3a\u6559\u6388\u30022008\u5e74\u6210\u4e3a\u52a0\u62ff\u5927\u9996\u5e2d\u79d1\u5b66\u5bb6\u548c\u591a\u4f26\u591a\u5927\u5b66\u6559\u6388\u3002Stephan\u6559\u6388\u83b7\u5f97\u4e86\u591a\u9879\u56fd\u5185\u53ca\u56fd\u9645\u8363\u8a89\uff0c\u5176\u4e2d\u5305\u62ec\u6d2a\u5821\u57fa\u91d1\u4f1a\u79d1\u5b66\u5bb6\u79d1\u7814\u5956\u3001\u8def\u5fb7\u7ef4\u683c\u8499\u5fb7\u5956\u3001\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u5b66\u4f1aCiapetta\u6770\u51fa\u5b66\u672f\u62a5\u544a\u5956\u7b49\u3002Stephan\u6559\u6388\u662f\u52a0\u62ff\u5927\u7687\u5bb6\u5b66\u4f1a\u9662\u58eb\uff0c\u5e76\u4e14\u4e3aChemical Society Reviews <\/em>\u671f\u520a\u7684Chair of Editorial Board\u3002<\/p>\n


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https:<\/span>\/\/www.x-mol.com\/university\/faculty\/44756<\/span><\/p>\n


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\u5468\u5409\u4eae\u535a\u58eb\u7b80\u4ecb\uff1a<\/strong>2010\u5e746\u6708\u5728\u5c71\u4e1c\u5927\u5b66\u83b7\u5f97\u5316\u5b66\u4e13\u4e1a\u5b66\u58eb\u5b66\u4f4d\u30022015\u5e746\u6708\u5728\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u83b7\u5f97\u6709\u673a\u5316\u5b66\u4e13\u4e1a\u535a\u58eb\u5b66\u4f4d\u3002\u6bd5\u4e1a\u4e4b\u540e\u81f32016\u5e749\u6708\uff0c\u7559\u6240\u505a\u79d1\u7814\u52a9\u7406\uff0c\u5bfc\u5e08\u4e3a\u9648\u8000\u950b\u7814\u7a76\u5458\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u7a00\u571f\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u3002\u4e3b\u8981\u8bfe\u9898\u662f\u7a00\u571f\u91d1\u5c5e\u6c22\u5316\u7269\u53ca\u81a6\u5bbe\u914d\u5408\u7269\u7684\u7814\u7a76\u3002\u81ea2016\u5e749\u6708\u81f3\u4eca\uff0c\u52a0\u5165Douglas W. Stephan\u6559\u6388\u8bfe\u9898\u7ec4\u8fdb\u884c\u535a\u58eb\u540e\u5de5\u4f5c\uff0c\u7814\u7a76\u65b9\u5411\u662f\u4e3b\u65cf\u5143\u7d20\u5316\u5b66\u3002\u4e3b\u8981\u8bfe\u9898\u662f\u6c2e\u65cf\u5143\u7d20Lewis\u9178\u53ca\u5728\u53d7\u9650Lewis\u9178\u78b1\u5316\u5b66\u4e2d\u7684\u5e94\u7528\u3002\u5df2\u5728Chem\u3001J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001Chem. Commun.\u3001Chem. Eur. J.\u3001Organometallics <\/em><\/span>\u7b49\u671f\u520a\u53d1\u8868\u591a\u7bc7\u7814\u7a76\u5de5\u4f5c\u3002<\/p>\n


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\uff08\u672c\u6587\u7531chemliu<\/strong>\u4f9b\u7a3f\uff09<\/span><\/p>\n


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\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"

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