{"id":85186,"date":"2019-04-13T00:00:50","date_gmt":"2019-04-17T03:18:41","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/85186\/"},"modified":"2019-04-17T11:18:44","modified_gmt":"2019-04-17T03:18:44","slug":"0b96e3d28d","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/85186\/","title":{"rendered":"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60"},"content":{"rendered":"
\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/span><\/a><\/p>\n


<\/p>\n

\u9502\u786b\u7535\u6c60<\/span><\/strong>\u7531\u4e8e\u5177\u6709\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\u548c\u80fd\u91cf\u5bc6\u5ea6\u800c\u6709\u671b\u53d1\u5c55\u6210\u4e3a\u4e0b\u4e00\u4ee3\u50a8\u80fd\u8bbe\u5907\u3002\u7136\u800c\uff0c\u9634\u6781\u578b\u63a7\u5236\u673a\u5236\u7535\u6c60\u7cfb\u7edf\u4e2d\u6240\u9700\u7684\u9ad8\u7535\u89e3\u6db2\/\u786b\u6bd4\u4f8b\u548c\u4e25\u91cd\u7684\u591a\u786b\u5316\u7269\u7a7f\u68ad\u6548\u5e94\u4e25\u91cd\u963b\u788d\u9502\u786b\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5bf9\u4e8e\u5b9e\u73b0\u9ad8\u6bd4\u80fd\u91cf\u9502\u786b\u7535\u6c60\u6765\u8bf4\uff0c\u964d\u4f4e\u7535\u89e3\u6db2\u7684\u7528\u91cf\uff0c\u5ef6\u7f13\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002<\/span><\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n


<\/span><\/p>\n

\u8fd1\u65e5\uff0c\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb<\/strong>\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u5728<\/span>Journal of Materials Chemistry A<\/strong><\/em><\/span>\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u8bbe\u8ba1\u5236\u5907\u4e86<\/span>\u4e00\u79cd\u9499\u949b\u77ff\u578b\u5feb\u79bb\u5b50\u5bfc\u4f53La<\/span>0.56<\/sub><\/span>Li<\/span>0.33<\/sub><\/span>TiO<\/span>3<\/sub><\/span> (LLTO)\u5e76\u5c06\u5176\u9996\u6b21\u7528\u4f5c\u591a\u786b\u5316\u7269\u7684\u5438\u9644\u5242\u548c\u591a\u786b\u5316\u7269\u8f6c\u5316\u7684\u50ac\u5316\u5242<\/span><\/strong>\u3002\u7ecf\u8bc1\u5b9e\uff0cLLTO\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff082.94\u00d710<\/span>-4<\/sup><\/span> S cm<\/span>-1<\/sup><\/span>\uff09\uff0c\u5e76\u4e14\u80fd\u591f\u4f5c\u4e3a\u8d2b\u7535\u89e3\u6db2\u6761\u4ef6\u4e0b\u591a\u786b\u5316\u7269\u8f6c\u6362\u7684\u9ad8\u6548\u7535\u50ac\u5316\u5242\u3002LLTO\u4e2d\u4eb2\u786b(O)\u4f4d\u548c\u4eb2\u786b(Ti)\u4f4d\u7684\u5171\u5b58\u80fd\u4f7f\u5176\u4e0e\u591a\u786b\u5316\u7269\u5f62\u6210\u826f\u597d\u7684\u754c\u9762\u4eb2\u548c\u529b\u3002\u56e0\u6b64\uff0c\u5305\u542bLLTO\u7684\u9502\u786b\u7535\u6c60\u53ef\u4ee5\u6709\u6548\u5730\u964d\u4f4e\u7535\u89e3\u6db2\/\u6d3b\u6027\u7269\u8d28\u7684\u6bd4\u4f8b\uff0c\u52a0\u901f\u4e86\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u6291\u5236\u4e86\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\uff0c\u663e\u8457\u964d\u4f4e\u5145\u653e\u7535\u8fc7\u7a0b\u7684\u8fc7\u7535\u4f4d\uff0c\u63d0\u9ad8\u9502\u786b\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u80fd\u3002<\/span><\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

\u56fe1 (a) XRD\u56fe\u8c31\uff0c(b) \u626b\u63cf\u7535\u955c\u56fe\u50cf\uff0c(c) \u7c92\u5ea6\u5206\u5e03\uff0c(d) N<\/span>2<\/sub><\/span>\u5438\u9644\u7b49\u6e29\u7ebf\uff0c(E) \u5b54\u5f84\u5206\u5e03\uff0c(F) LLTO\u7684EIS\u6d4b\u8bd5\u3002<\/span><\/p>\n


<\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

\u56fe2 (a) LLTO\u548cCNT\u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31(\u63d2\u56fe\uff1aLLTO\u548cCNT\u57285 mmol L<\/span>-1<\/sup><\/span> Li<\/span>2<\/sub><\/span>S<\/span>6<\/sub><\/span>\u4e2d\u7684\u5438\u9644\u5bf9\u6bd4\u7167\u7247)\uff1b(b) \u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\uff1b(c) \u7528CNT@PP(\u4e0a)\u548cLLTO@PP(\u5e95\u90e8)\u5206\u79bb\u5668\u8fdb\u884c\u6e17\u900f\u8bd5\u9a8c\u3002<\/span><\/p>\n


<\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

\u56fe3 LLTO-Li<\/span>2<\/sub><\/span>S<\/span>6<\/sub><\/span>\u548cLLTO\u7684 (a) La 3d\uff0c(b) O1s\uff0c(c) Ti 2p XPS\u8c31\uff0c(d) LLTO-Li<\/span>2<\/sub><\/span>S<\/span>6<\/sub><\/span>\u7684S 2p XPS\u8c31\u3002<\/span><\/p>\n


<\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

\u56fe4 (a) 0.4 mA cm<\/span>-2<\/sup><\/span>\u548c(b) 0.8 mA cm<\/span>-2<\/sup><\/span>\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff1b(c) \u5145\u653e\u7535\u66f2\u7ebf\uff1b(d) LLTO-7\/CNT\/S\u548cCNT\/S\u5728\u8d2b\u7535\u89e3\u8d28\u6761\u4ef6(E\/S = 7 \u03bcLE mg-1 <\/sup><\/span>S)\u4e0b\u7684\u5e73\u5747\u6ede\u540e\u7535\u538b\u3002<\/span><\/p>\n


<\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

\u56fe5 LLTO-10\/CNT\/S\u5728(a) E\/S =5 \u03bcLE mg<\/span>-1 <\/sup><\/span>S\uff0c(b) E\/S =6 \u03bcLE mg<\/span>-1 <\/sup><\/span>S\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff0c(c) \u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u548c(d) LLTO-10\/CNT\/S\u7535\u6781\u7684\u6ede\u540e\u7535\u538b\u3002<\/span><\/p>\n


<\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

\u56fe6 (a) \u9ad8\u786b\u8d28\u91cf\u8d1f\u8f7d\u4e0b\u7684\u500d\u7387\u6027\u80fd\uff0c(b) \u5faa\u73af\u6027\u80fd(\u63d2\u56fe\uff1a\u53d1\u5149\u4e8c\u6781\u7ba1\u706f)\uff0c(c) \u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6240\u5236\u5907\u7684\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd\u3002<\/span><\/p>\n


<\/p>\n

\u5c0f\u7ed3<\/span><\/strong><\/span><\/p>\n


<\/p>\n

\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u6559\u6388\u56e2\u961f\u53d1\u73b0\uff0c\u9499\u949b\u77ff\u578b\u5feb\u79bb\u5b50\u5bfc\u4f53La0.56<\/sub><\/span>Li0.33<\/sub><\/span>TiO3<\/sub><\/span>  (LLTO)\u5bf9\u9502\u786b\u7535\u6c60\u5c55\u793a\u4e86\u663e\u8457\u7684\u7535\u50ac\u5316\u4f5c\u7528\uff0c\u5b83\u80fd\u591f\u4e0e\u591a\u786b\u5316\u7269\u5f62\u6210\u826f\u597d\u7684\u4eb2\u548c\u754c\u9762\uff0c\u52a0\u901f\u591a\u786b\u5316\u7269\u7684\u7535\u5316\u5b66\u8f6c\u5316\u53cd\u5e94\uff0c\u4ece\u800c\u5728\u8d2b\u7535\u89e3\u6db2\u6761\u4ef6\u4e0b\uff0c\u4e5f\u80fd\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u57280.8 mA cm<\/span>-2<\/sup><\/span>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cE\/S\u964d\u4e3a5\u65f6\uff0c\u5176\u6bd4\u5bb9\u91cf\u4e3a721 mAh g<\/span>-1<\/sup><\/span>\uff0c\u5f53\u786b\u8d1f\u8f7d\u4e3a6.4 mg cm-2<\/sup><\/span>\u65f6\uff0c\u9762\u79ef\u6bd4\u5bb9\u91cf\u4ecd\u53ef\u8fbe\u52304.3 mAh cm-2<\/sup><\/span>\u3002\u672c\u7814\u7a76\u521b\u9020\u6027\u5730\u5c06\u5feb\u79bb\u5b50\u5bfc\u4f53LLTO\u5f15\u5165\u9502\u786b\u7535\u6c60\uff0c\u4ee5\u4fc3\u8fdb\u786b\u57fa\u5206\u5b50\u7684\u5feb\u901f\u6eb6\u89e3\u548c\u8c03\u8282Li<\/span>2<\/sub><\/span>S\u7684\u5747\u5300\u6c89\u79ef\uff0c\u4ece\u800c\u52a0\u5feb\u591a\u786b\u5316\u9502\u7535\u5316\u5b66\u8f6c\u5316\u7684\u52a8\u529b\u5b66\uff0c\u63d0\u9ad8\u53cd\u5e94\u7684\u53ef\u9006\u6027\uff0c\u589e\u52a0\u7535\u6c60\u7684\u53ef\u9006\u5bb9\u91cf\u548c\u5faa\u73af\u5bff\u547d\u3002\u672c\u7814\u7a76\u4e3a\u8d2b\u7535\u89e3\u6db2\u6761\u4ef6\u4e0b\u5b9e\u73b0\u9ad8\u6027\u80fd\u9502\u786b\u7535\u6c60\u4f5c\u4e86\u79ef\u6781\u7684\u63a2\u7d22\u3002\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a2016\u7ea7\u535a\u58eb\u7814\u7a76\u751f\u9648\u66fc\u82b3<\/strong>\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u738b\u5148\u53cb<\/strong>\u6559\u6388\u3002<\/span><\/p>\n


<\/p>\n

\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1aManfang Chen, Cheng Huang, Yongfang Li, Shouxin Jiang, Peng Zeng, Gairong Chen, Hongbo Shu, Hong Liu, Zhihao Li, Xianyou Wang<\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

Perovskite-type La<\/span>0.56<\/sub><\/span>Li<\/span>0.33<\/sub><\/span>TiO<\/span>3 <\/sub><\/span>as an effective polysulfide promoter for stable lithium-sulfur batteries in lean electrolyte condition<\/span><\/p>\n

J. Mater. Chem. A<\/span><\/em>, 2019<\/strong>, DOI: 10.1039\/C9TA01500K<\/span><\/p>\n


<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/span><\/strong><\/p>\n


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\"\u3010\u80fd\u6e90\u3011\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u56e2\u961f\uff1a\u9499\u949b\u77ff\u578bLLTO\u4f5c\u4e3a\u591a\u786b\u5316\u7269\u4fc3\u8fdb\u5242\u52a9\u529b\u8d2b\u6db2\u5f0f\u9502\u786b\u7535\u6c60\"<\/p>\n

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\u6e58\u6f6d\u5927\u5b66\u738b\u5148\u53cb\u6559\u6388\u56e2\u961f\u5728\u9502\u786b\u7535\u6c60\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u4e86\u4e00\u7cfb\u7c7b\u7814\u7a76\u6210\u679c\uff0c\u53d1\u8868\u4e86\u591a\u7bc7\u9ad8\u6c34\u5e73\u6587\u7ae0\u3002\u5982\u6b63\u6781\u6750\u6599\u7ed3\u6784\u8bbe\u8ba1\uff08Small<\/em>, 2018<\/strong>, 14(49): 1803134\uff1bACS Appl. Mater. Inter<\/em>., 2018<\/strong>, 10<\/em>, 13562-13572\uff1bChem. Eng. J<\/em>., 2018<\/strong>, 335<\/em>, 831-842\uff1bJ. Mater. Chem. A<\/em>, 2016<\/strong>, 4<\/em>, 16148-16156\uff1bChemSusChem<\/em>, 2017<\/strong>, 10<\/em>, 1803-1812\uff1bChem. Eng. J.<\/em>, 2017<\/strong>, 313<\/em>, 404-414\uff1bACS Sustain. Chem. Eng<\/em>., 2018<\/strong>, 6<\/em>, 7545-7557\uff1bJ. Electrochem. Soc<\/em>., 2016<\/strong>, 163<\/em>, A2922-A2929\uff09\u3001\u9694\u819c\u4f18\u5316\u8bbe\u8ba1\uff08Chem. Eng. J.<\/em>, 2019<\/strong>, 355<\/em>, 478-486\uff1b\uff09\u7b49\u65b9\u9762\u3002<\/span><\/p>\n


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\u738b\u5148\u53cb<\/span><\/p>\n

https:\/\/www.x-mol.com\/university\/faculty\/14262<\/span><\/p>\n

\u8bfe\u9898\u7ec4\u7f51\u7ad9<\/span><\/p>\n

http:\/\/nem.xtu.edu.cn\/<\/span><\/p>\n


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\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/p>\n


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\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"

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