{"id":8612,"date":"2018-06-13T01:00:00","date_gmt":"2018-07-27T09:33:22","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/07\/27\/%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91%e5%b1%b1%e8%a5%bf%e5%a4%a7%e5%ad%a6%e6%96%87%e6%8c%af%e5%ba%b7%e5%9b%a2%e9%98%9f%ef%bc%9a%e9%92%af%e5%82%ac%e5%8c%96%e4%b8%8b%e7%8e%af%e7%8a%b6%e7%83%af%e9%85%ae\/"},"modified":"2018-07-27T17:33:25","modified_gmt":"2018-07-27T09:33:25","slug":"%e3%80%90%e6%9c%89%e6%9c%ba%e3%80%91%e5%b1%b1%e8%a5%bf%e5%a4%a7%e5%ad%a6%e6%96%87%e6%8c%af%e5%ba%b7%e5%9b%a2%e9%98%9f%ef%bc%9a%e9%92%af%e5%82%ac%e5%8c%96%e4%b8%8b%e7%8e%af%e7%8a%b6%e7%83%af%e9%85%ae","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/8612\/","title":{"rendered":"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e"},"content":{"rendered":"<div class=\"bpp-post-content\">\n<p style=\"white-space: normal;\"><span style=\"line-height: 0px;\">\u200d\u200d<\/span><span style=\"font-size: 18.018px;line-height: 0px;\">\u200d<a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657590253&amp;idx=1&amp;sn=af64055348b35e9185b67c634d7ef95c&amp;chksm=80f7b23db7803b2bc868baa456f16ab2329ba355b97bce33703e32440ef4260a6f34c1ea970a&amp;scene=21#wechat_redirect\" target=\"_blank\" style=\"text-align: center;\"><img class=\"\"      src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress5-1532684003.gif\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/a><\/span><a href=\"http:\/\/mp.weixin.qq.com\/s?__biz=MzAwOTExNzg4Nw==&amp;mid=2657574730&amp;idx=1&amp;sn=7001a26433acb77dcdd5629f27cd8b20&amp;chksm=80f7769ab780ff8cedab5baefd9bc7a02dd18b2191cd29afb2d190e8ea149564133c9437e7d5&amp;scene=21#wechat_redirect\" target=\"_blank\"><\/a><\/p>\n<p style=\"white-space: normal;line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u95f4\uff0c\u94af\u50ac\u5316\u7684Fujiwara\u2013Moritani\u2013Heck coupling\u5076\u8054\u53cd\u5e94\u5df2\u7ecf\u6210\u4e3aC-H\u952e\u5b98\u80fd\u5316\u6700\u4e3a\u9ad8\u6548\u3001\u539f\u5b50\u53ca\u6b65\u9aa4\u7ecf\u6d4e\u6027\u7684\u7b56\u7565\u3002\u5c3d\u7ba1\u8fd1\u5e74\u6765\uff0c\u4eba\u4eec\u5df2\u7ecf\u5b9e\u73b0\u4e86\u94fe\u72b6\u70ef\u70c3\u4e0e\u6742\u82b3\u9999\u70c3\u4e4b\u95f4\u7684\u4ea4\u53c9\u5076\u8054\uff0c\u4f46\u662f\u73af\u72b6\u70ef\u70c3\u4e0e\u6742\u82b3\u70c3\u7684\u76f4\u63a5\u5076\u8054\u5c1a\u65e0\u62a5\u9053\uff0c\u9762\u4e34\u7684\u6311\u6218\u4e3b\u8981\u6709\u4ee5\u4e0b\u4e09\u4e2a\u65b9\u9762\uff1a\uff081\uff09\u7531\u73af\u72b6\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u548cAr-Pd(II)-X\u5171\u8f6d\u52a0\u6210\u5f62\u6210\u7684Pd(II)-\u70ef\u9187\u5f0f\u4e2d\u95f4\u4f53\u66f4\u6613\u53d1\u751f\u8d28\u5b50\u5316\u800c\u975e\u03b2-H\u6d88\u9664\u53cd\u5e94\uff1b\uff082\uff09\u6742\u82b3\u9999\u70c3\u7684\u81ea\u8eab\u5076\u8054\u53cd\u5e94\u548c\u73af\u72b6\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u7684\u8fc7\u5ea6\u6c27\u5316\u7b49\u526f\u53cd\u5e94\u96be\u4ee5\u907f\u514d\uff1b\uff083\uff09\u5e95\u7269\u5206\u5b50\u4e2d\u6ca1\u6709\u5bfc\u5411\u57fa\u56e2\u548c\u6742\u82b3\u9999\u70c3\u81ea\u8eab\u53cd\u5e94\u6d3b\u6027\u4f4e\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4e5f\u9650\u5236\u4e86\u5076\u8054\u53cd\u5e94\u7684\u53d1\u751f\u3002\u6b64\u5916\uff0c\u867d\u7136\u4eba\u4eec\u4e5f\u62a5\u9053\u8fc7\u5229\u7528\u73af\u72b6\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u4e0e\u82b3\u9999\u70c3\u53d1\u751f\u5076\u8054\u53cd\u5e94\u7684\u4f8b\u5b50\uff0c\u4f46\u662f\u53cd\u5e94\u6761\u4ef6\u90fd\u76f8\u5bf9\u82db\u523b\uff1a\u5982\u8be5\u7c7b\u578b\u7684\u53cd\u5e94\u9700\u8981\u4f7f\u7528\u81f3\u5c1115\u5f53\u91cf\u7684\u82b3\u9999\u70c3\uff0c\u6216\u8005\u76f4\u63a5\u4ee5\u82b3\u9999\u70c3\u4f5c\u4e3a\u6eb6\u5242\uff0c\u53cd\u5e94\u5fc5\u987b\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u53cd\u5e94\u6240\u9700\u6e29\u5ea6\u8f83\u9ad8\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress6-1532684003.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe1. \u82b3\u9999\u70c3\u4e0e\u73af\u72b6\u70ef\u916e\u8fdb\u884c\u5076\u8054\u53cd\u5e94\u7684\u53cd\u5e94\u8def\u5f84<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong><span style=\"font-size: 18px;\">\u5c71\u897f\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662<\/span><\/strong><span style=\"font-size: 18px;\">\u7684<strong>\u6587\u632f\u5eb7<\/strong>\u8bfe\u9898\u7ec4\u5229\u7528\u914d\u4f53\u5bfc\u5411\u5e76\u52a0\u901f\u7684C-H\u952e\u6d3b\u5316\uff0c\u53d1\u5c55\u4e86<strong>\u4e00\u79cd\u6742\u82b3\u9999\u70c3\u4e0e\u73af\u72b6\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u76f4\u63a5\u4ea4\u53c9\u5076\u8054\u7684\u65b9\u6cd5<\/strong>\u3002\u8be5\u53cd\u5e94\u6761\u4ef6\u8f83\u4e3a\u6e29\u548c\uff0c\u5316\u5b66\u9009\u62e9\u6027\u597d\uff0c\u5bf9\u4e0d\u540c\u5927\u5c0f\u7684\u73af\u72b6\u70ef\u916e\u548c\u4fee\u9970\u4e0d\u540c\u53d6\u4ee3\u57fa\u7684\u567b\u5429\u90fd\u5177\u6709\u826f\u597d\u7684\u517c\u5bb9\u6027\uff0c\u4e3a3\u4f4d\u6742\u82b3\u57fa\u5316\u82ef\u915a\u7684\u5236\u5907\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u8be5\u5076\u8054\u53cd\u5e94\u65e0\u9700\u4f7f\u7528\u8fc7\u91cf\u7684\u6742\u82b3\u9999\u70c3\uff0c\u4e5f\u907f\u514d\u4f7f\u7528\u9884\u5148\u5b98\u80fd\u5316\u7684\u5364\u4ee3\u82b3\u9999\u70c3\u3001\u82b3\u57fa\u787c\u9178\u3001\u82b3\u57fa\u7fa7\u9178\uff0c\u66f4\u52a0\u7b26\u5408\u539f\u5b50\u7ecf\u6d4e\u6027\u7684\u8981\u6c42\u3002\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728<\/span><span style=\"font-size: 16px;\"><strong><em>Chemical Communications&nbsp;<\/em><\/strong><\/span><span style=\"font-size: 18px;\">\u4e0a\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a<strong>\u6587\u632f\u5eb7<\/strong>\u6559\u6388\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress0-1532684003.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe2. \u567b\u5429\u4e0e\u73af\u72b6\u70ef\u916e\u8fdb\u884c\u5076\u8054\u53cd\u5e94\u7684\u53cd\u5e94\u8fc7\u7a0b<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u6c28\u57fa\u9178\u914d\u4f53\u4e0e\u94af\u50ac\u5316\u5242\u7ed3\u5408\u5df2\u7ecf\u6210\u529f\u5b9e\u73b0\u4e86\u8bb8\u591aC-H\u952e\u5b98\u80fd\u5316\u53cd\u5e94\u3002\u4f5c\u8005\u4ee5\u567b\u5429\u548c\u73af\u5df1\u70ef\u916e\u4e3a\u6a21\u677f\u5e95\u7269\u3001\u78b3\u9178\u94f6\u4e3a\u6c27\u5316\u5242\u3001\u918b\u9178\u94af\u4e3a\u50ac\u5316\u5242\u7684\u6761\u4ef6\u4e0b\uff0c\u5bf9\u4e00\u7cfb\u5217\u7684\u6c28\u57fa\u9178\u914d\u4f53\u548c\u6eb6\u5242\u8fdb\u884c\u7b5b\u9009\uff0c\u53d1\u73b0\u4ee5<em>N<\/em>-\u4e59\u9170\u7518\u6c28\u9178\u4e3a\u914d\u4f53\u3001\u4e8c\u6c27\u516d\u73af\u4e3a\u6eb6\u5242\u65f6\uff0c\u567b\u5429\u4e0e\u73af\u5df1\u70ef\u916e\u53ef\u4ee5\u987a\u5229\u5730\u8fdb\u884c\u5076\u8054\u53cd\u5e94\uff0c\u4f46\u662f\u53cd\u5e94\u7684\u4ea7\u7387\u53ea\u80fd\u8fbe\u523018%\u3002\u6700\u7ec8\uff0c\u4ed6\u4eec\u901a\u8fc7\u5bf9\u4e00\u7cfb\u5217\u6df7\u5408\u6eb6\u5242\u8fdb\u884c\u7b5b\u9009\uff0c\u53d1\u73b0\u5411\u4f53\u7cfb\u4e2d\u52a0\u51655%\u7684HFIP\u540e\uff0c\u53cd\u5e94\u4ea7\u7387\u6709\u6240\u63d0\u9ad8\uff0c\u66f4\u6362\u94af\u50ac\u5316\u5242\u4e3a\u6c2f\u5316\u94af\u66f4\u6709\u5229\u4e8e\u8be5\u5076\u8054\u53cd\u5e94\uff0c\u800cAgSbF<\/span><span style=\"font-size: 14px;\"><sub>6<\/sub><\/span><span style=\"font-size: 18px;\">\u4f5c\u4e3a\u6dfb\u52a0\u5242\u65f6\uff0c\u8be5\u53cd\u5e94\u7684\u4ea7\u7387\u5f97\u5230\u8fdb\u4e00\u6b65\u63d0\u9ad8\u3002\u5728\u53cd\u5e94\u4f53\u7cfb\u63a2\u7d22\u7684\u57fa\u7840\u4e0a\uff0c\u4f5c\u8005\u6700\u7ec8\u53d1\u73b0\u6dfb\u52a00.05 mL\u7684DMSO\u53ef\u4f7f\u8be5\u5076\u8054\u53cd\u5e94\u7684\u4ea7\u7387\u8fbe\u523064%\uff0c\u53ef\u80fd\u7684\u539f\u56e0\u662fDMSO\u53ef\u4ee5\u7a33\u5b9a\u96f6\u4ef7\u94af\uff0c\u4ece\u800c\u963b\u6b62\u4e0d\u6d3b\u6cfc\u7684\u94af\u9ed1\u5f62\u6210\u3002\u63a7\u5236\u5b9e\u9a8c\u53d1\u73b0\uff0c\u94af\u50ac\u5316\u5242\u548c\u6c28\u57fa\u9178\u914d\u4f53\u5bf9\u8be5\u5076\u8054\u53cd\u5e94\u7684\u987a\u5229\u8fdb\u884c\u81f3\u5173\u91cd\u8981\uff0c\u4e24\u8005\u7f3a\u4e00\u4e0d\u53ef\u3002<\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\"><br  \/><\/span><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u6709\u4e86\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\uff0c\u4f5c\u8005\u9996\u5148\u5bf9\u567b\u5429\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u8fdb\u884c\u8003\u5bdf\uff0c\u53d1\u73b0\u53cd\u5e94\u5177\u6709\u8f83\u597d\u7684\u5316\u5b66\u9009\u62e9\u6027\uff0c\u8bb8\u591a\u5b98\u80fd\u56e2\u5982Br\u3001Cl\u3001CO<\/span><span style=\"font-size: 14px;\"><sub>2<\/sub><\/span><span style=\"font-size: 18px;\"><span style=\"text-align: justify;font-size: 14px;\"><\/span>Me\u3001COCH<span style=\"text-align: justify;font-size: 14px;\"><sub>3<\/sub><\/span>\u3001Ph\u90fd\u53ef\u4ee5\u4e0e\u53cd\u5e94\u5f88\u597d\u5730\u517c\u5bb9\u3002\u6b64\u5916\uff0c\u5728\u8be5\u4f18\u5316\u6761\u4ef6\u4e0b\uff0c\u544b\u5583\u4e5f\u53ef\u4ee5\u4e0e\u73af\u70ef\u916e\u53d1\u751f\u5076\u8054\u53cd\u5e94\u3002\u968f\u540e\uff0c\u4f5c\u8005\u53c8\u5bf9\u4e0d\u540c\u5c3a\u5bf8\u5927\u5c0f\u7684\u73af\u70ef\u916e\u8fdb\u884c\u8003\u5bdf\uff0c\u73af\u620a\u70ef\u916e\u3001\u73af\u5df1\u70ef\u916e\u3001\u73af\u5e9a\u70ef\u916e\u7b49\u73af\u72b6\u70ef\u916e\u90fd\u9002\u7528\u4e8e\u8be5\u4f53\u7cfb\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress3-1532684003.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe3. \u567b\u5429\u5e95\u7269\u9002\u7528\u8303\u56f4\u7684\u8003\u5bdf<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc1\u660e\u8be5\u65b9\u6cd5\u7684\u5b9e\u7528\u6027\uff0c\u4f5c\u8005\u8fd8\u5bf9\u53cd\u5e94\u5f97\u5230\u7684\u4ea7\u7269\u8fdb\u884c\u884d\u751f\u5316\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u4ea7\u7269<strong>2<\/strong>\u53ef\u4ee5\u987a\u5229\u5730\u8f6c\u5316\u4e3a\u95f4\u4f4d\u53d6\u4ee3\u7684\u82ef\u915a\u3002\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u6bcf\u6b65\u53cd\u5e94\u7684\u4ea7\u7387\u90fd\u8f83\u9ad8\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress0-1532684004.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe4. \u95f4\u4f4d\u6742\u82b3\u57fa\u5316\u82ef\u915a\u7684\u5408\u6210<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u4e3a\u4e86\u63a2\u7a76\u53cd\u5e94\u7684\u673a\u7406\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u5b9e\u9a8c\uff0cKIE\u4e3a<strong>4<\/strong>\u3002\u6b64\u5916\uff0c\u4ed6\u4eec\u8fd8\u8bbe\u8ba1\u4e862-\u7532\u57fa\u567b\u5429\u548c2-\u6c2f\u567b\u5429\u4e0e\u73af\u5df1\u70ef\u916e\u7684\u7ade\u4e89\u53cd\u5e94\uff0c\u6700\u7ec8\u76ee\u6807\u4ea7\u7269\u7684\u6bd4\u4f8b\u4e3a2.5\uff0c\u8bf4\u660e\u8be5\u53cd\u5e94\u7684\u6d3b\u6027\u4e0e\u567b\u5429\u73af\u4e0a\u7684\u7535\u5b50\u5c5e\u6027\u5bc6\u5207\u76f8\u5173\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress4-1532684004.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe5. \u52a8\u529b\u5b66\u540c\u4f4d\u7d20\u6548\u5e94\u5b9e\u9a8c<\/span><\/p>\n<p><br  \/><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress3-1532684004.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe6. \u7ade\u4e89\u53cd\u5e94<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u57fa\u4e8e\u4e0a\u8ff0\u63a2\u7a76\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u5982\u4e0b\u53cd\u5e94\u673a\u7406\uff1a\u9996\u5148\u567b\u5429\u5728Pd\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\u53d1\u751fC-H\u952e\u6d3b\u5316\u5f62\u6210\u4e2d\u95f4\u4f53<strong>I<\/strong>\uff0c\u968f\u540e\u7ecf\u73af\u5df1\u70ef\u916e\u8fc1\u79fb\u63d2\u5165\u5f62\u6210\u4e2d\u95f4\u4f53<strong>II<\/strong>\uff0c\u4e2d\u95f4\u4f53<strong>II<\/strong>\u7ecf\u8fc7\u5feb\u901f\u7684\u5f02\u6784\u5316\u540e\u5f62\u6210\u4e2d\u95f4\u4f53<strong>IIB<\/strong>\uff0c\u4ece\u800c\u53d1\u751f\u987a\u5f0f\u7684\u03b2-H\u6d88\u9664\u53cd\u5e94\uff0c\u5f97\u5230\u76ee\u6807\u4ea7\u7269<strong>III<\/strong>\u548cPd(0)\u7269\u79cd\uff0cPd(0)\u4e2d\u95f4\u4f53\u7ecf\u6c27\u5316\u5242\u6c27\u5316\uff0c\u91cd\u751fPd(II)\u50ac\u5316\u5242\u53c2\u4e0e\u4e0b\u4e00\u6b21\u50ac\u5316\u5faa\u73af\u3002<\/span><\/p>\n<p><img class=\"\"       style=\"\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress9-1532684004.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 16px;color: rgb(136, 136, 136);\">\u56fe7. \u53cd\u5e94\u53ef\u80fd\u7684\u673a\u7406<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: center;line-height: 1.75em;\"><span style=\"color: rgb(33, 127, 188);\"><strong><span style=\"font-size: 18px;\">\u5c0f\u7ed3<\/span><\/strong><\/span><\/p>\n<p style=\"line-height: normal;\"><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><span style=\"font-size: 18px;\">\u6587\u632f\u5eb7\u8bfe\u9898\u7ec4\u53d1\u5c55\u4e86\u4ee5\u4e59\u9170\u57fa\u4fee\u9970\u7684\u6c28\u57fa\u9178\u4f5c\u4e3a\u914d\u4f53\uff0c\u5728Pd(II)\u50ac\u5316\u5242\u53c2\u4e0e\u7684\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u567b\u54292\u4f4d\u4e0e\u73af\u70ef\u916e3\u4f4d\u7684\u5076\u8054\u3002\u8be5\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u65e0\u9700\u4f7f\u7528\u8fc7\u91cf\u7684\u6742\u82b3\u9999\u70c3\u4f5c\u4e3a\u5076\u8054\u8bd5\u5242\uff0c\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u8f83\u597d\uff0c\u6240\u5f97\u7684\u5076\u8054\u4ea7\u7269\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u8f6c\u5316\u4e3a\u95f4\u4f4d\u6742\u82b3\u57fa\u5316\u7684\u82ef\u915a\u3002\u4f5c\u8005\u5e0c\u671b\u901a\u8fc7\u8be5\u8131\u6c22\u5076\u8054\u7684\u7b56\u7565\u8bbe\u8ba1\u65b0\u7684\u95f4\u4f4d\u6742\u82b3\u57fa\u5316\u7684\u82ef\u915a\u5316\u5408\u7269\uff0c\u63a8\u52a8\u5176\u5728\u5408\u6210\u548c\u533b\u836f\u7814\u7a76\u4e2d\u7684\u5e94\u7528\u3002<\/span><\/p>\n<p><br  \/><\/p>\n<p style=\"text-align: justify;line-height: 1.75em;\"><strong><span style=\"font-size: 16px;\">\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong><span style=\"font-size: 16px;\">Zhen-Kang Wen, Ting-Ting Song, Yu-Fang Liu, Jian-Bin Chao<\/span><\/p>\n<p><span style=\"font-size: 14px;\">\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n<p><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress4-1532684004-1.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<p><span style=\"font-size: 14px;\">Palladium-catalyzed dehydrogenative coupling of cyclic enones with thiophenes: a rapid access to \u03b2-heteroarylated cyclic enones<\/span><\/p>\n<p><em><span style=\"font-size: 14px;\">Chem. Commun.<\/span><\/em><span style=\"font-size: 14px;\">, <strong>2018<\/strong>, <em>54<\/em>, 3668, DOI: 10.1039\/C8CC01059E<\/span><\/p>\n<p style=\"line-height: normal;\"><span style=\"font-size: 14px;\"><br  \/><\/span><\/p>\n<p><span style=\"font-size: 14px;\">\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n<p><span style=\"font-size: 14px;\">\u6587\u632f\u5eb7<\/span><\/p>\n<p><span style=\"font-size: 14px;\">http:\/\/www.x-mol.com\/university\/faculty\/49655<\/span><\/p>\n<p><br  \/><\/p>\n<section style=\"white-space: normal;\">\n<section class=\"Powered-by-XIUMI V5\" >\n<section class=\"\">\n<section class=\"\">\n<p style=\"text-align: center;\"><img class=\"\"       src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress2-1532684004.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p style=\"white-space: normal;\"><br  \/><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;text-align: center;\"><img      style=\"font-size: 18px;background-color: rgb(255, 255, 255);line-height: 25.6px;width: 556px;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress2-1532684004.png\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<section style=\"white-space: normal;background-color: rgb(255, 255, 255);box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"margin-top: 10px;margin-bottom: 10px;box-sizing: border-box;\">\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-top: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 206);border-right-color: rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"height: 15.9961px;width: 24px;float: right;border-top: 6px solid rgb(9, 158, 206);border-right: 6px solid rgb(9, 158, 206);border-bottom-color: rgb(9, 158, 206);border-left-color: rgb(9, 158, 206);box-sizing: border-box;\"><\/section>\n<section style=\"display: inline-block;color: transparent;clear: both;box-sizing: border-box;\"><\/section>\n<\/section>\n<section class=\"\" style=\"margin: -13px 3px;padding: 12px;border-width: 1px;border-style: solid;border-color: rgb(9, 158, 206);border-radius: 6px;word-wrap: break-word;box-sizing: border-box;\">\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<section class=\"\" style=\"box-sizing: border-box;\">\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e<span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">X-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n<p style=\"box-sizing: border-box;\"><br style=\"box-sizing: border-box;\"  \/><\/p>\n<p style=\"box-sizing: border-box;\"><span style=\"font-size: 18px;\"><span style=\"color: rgb(9, 158, 206);box-sizing: border-box;\"><strong style=\"box-sizing: border-box;\">\u957f\u6309<\/strong><\/span>\u4e0b\u56fe<strong style=\"box-sizing: border-box;\">\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<section class=\"Powered-by-XIUMI V5\"  style=\"box-sizing: border-box;\">\n<p style=\"margin-top: 10px;margin-bottom: 10px;text-align: center;box-sizing: border-box;\"><img class=\"\"     style=\"vertical-align: middle;box-sizing: border-box;\" src=\"http:\/\/www.05921.net\/wp-content\/uploads\/2018\/07\/beepress1-1532684005.jpeg\" alt=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\" title=\"\u3010\u6709\u673a\u3011\u5c71\u897f\u5927\u5b66\u6587\u632f\u5eb7\u56e2\u961f\uff1a\u94af\u50ac\u5316\u4e0b\u73af\u72b6\u70ef\u916e\u4e0e\u567b\u5429\u7684\u8131\u6c22\u5076\u8054\u53cd\u5e94\u5408\u6210\u03b2-\u6742\u82b3\u57fa\u5316\u7684\u73af\u70ef\u916e\"  \/><\/p>\n<\/section>\n<\/section>\n<section class=\"\" style=\"height: 16px;box-sizing: border-box;\">\n<section style=\"height: 15.9961px;width: 24px;float: left;border-bottom: 6px solid rgb(9, 158, 206);border-left: 6px solid rgb(9, 158, 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18px;box-sizing: border-box !important;word-wrap: break-word !important;\">\u70b9\u51fb\u201c<span style=\"max-width: 100%;color: rgb(0, 122, 170);\">\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b&nbsp;<strong>\u5316\u5b66 \u2022 \u6750\u6599&nbsp;<\/strong>\u9886\u57df<span style=\"max-width: 100%;background-color: rgb(255, 218, 81);\">\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n<p style=\"white-space: normal;line-height: 25.6px;font-size: 18.018px;max-width: 100%;min-height: 1em;color: rgb(62, 62, 62);background-color: rgb(255, 255, 255);box-sizing: border-box !important;word-wrap: break-word !important;\"><span style=\"max-width: 100%;color: rgb(0, 0, 0);font-size: 14px;box-sizing: border-box !important;word-wrap: break-word !important;\"><\/span><\/p>\n<blockquote class='keep-source'>\n<p>\u59cb\u53d1\u4e8e\u5fae\u4fe1\u516c\u4f17\u53f7\uff1a                         X\u4e00MOL\u8d44\u8baf                      <\/p>\n<\/blockquote>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>\u200d\u200d\u200d \u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u95f4\uff0c\u94af\u50ac\u5316\u7684Fujiwara\u2013Moritani\u2013Heck coupling\u5076\u8054\u53cd\u5e94\u5df2\u7ecf\u6210\u4e3a [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":8613,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/8612"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=8612"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/8612\/revisions"}],"predecessor-version":[{"id":8626,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/8612\/revisions\/8626"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/8613"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=8612"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=8612"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=8612"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}