{"id":8752,"date":"2018-06-11T01:00:00","date_gmt":"2018-07-27T09:34:11","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/07\/27\/%e9%85%8d%e4%bd%93%e6%8c%87%e6%8c%a5%e5%b9%b3%e9%9d%a2%e7%94%9f%e7%89%a9%e7%a2%b1%e5%a4%9a%e6%a0%b7%e6%80%a7%e5%90%88%e6%88%90\/"},"modified":"2018-07-27T17:34:13","modified_gmt":"2018-07-27T09:34:13","slug":"%e9%85%8d%e4%bd%93%e6%8c%87%e6%8c%a5%e5%b9%b3%e9%9d%a2%e7%94%9f%e7%89%a9%e7%a2%b1%e5%a4%9a%e6%a0%b7%e6%80%a7%e5%90%88%e6%88%90","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/8752\/","title":{"rendered":"\u914d\u4f53\u201c\u6307\u6325\u201d\u5e73\u9762\u751f\u7269\u78b1\u591a\u6837\u6027\u5408\u6210"},"content":{"rendered":"
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\u56fe1. \u5e73\u9762\u751f\u7269\u78b1<\/span><\/p>\n


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\"\u914d\u4f53\u201c\u6307\u6325\u201d\u5e73\u9762\u751f\u7269\u78b1\u591a\u6837\u6027\u5408\u6210\"<\/p>\n

\u56fe2. \u83f2\u5576\u916e\u548c\u5416\u5576\u916e\u591a\u6837\u6027\u6784\u5efa\u3002\u56fe\u7247\u6765\u6e90\uff1aAngew. Chem. Int. Ed.<\/em><\/span><\/p>\n


<\/p>\n

2016\u5e74\uff0c\u8be5\u5c0f\u7ec4\u518d\u6b21\u8fd0\u7528\u914d\u4f53\u6548\u5e94\u548c\u5bfc\u5411\u6548\u5e94\u534f\u540c\u201c\u6307\u6325\u201d\u91d1\u914d\u4f4d\uff0c\u6210\u529f\u5730\u5b9e\u73b0\u4e86\u4e24\u7c7b\u4e0d\u540c\u53d6\u4ee3\u7684\u4e8c\u6c22\u55b9\u5549\uff085\u4f4d\u53d6\u4ee3\u548c7\u4f4d\u53d6\u4ee3\uff09\u7ed3\u6784\u7684\u9009\u62e9\u591a\u6837\u6027\u6784\u5efa\uff08J. Am. Chem. Soc<\/em>., 2016<\/strong>, 138<\/em>, 5218-52221\uff09\u3002<\/span><\/p>\n

\"\u914d\u4f53\u201c\u6307\u6325\u201d\u5e73\u9762\u751f\u7269\u78b1\u591a\u6837\u6027\u5408\u6210\"<\/p>\n

\u56fe3. 5\u4f4d\u53ca7\u4f4d\u53d6\u4ee3\u4e8c\u6c22\u55b9\u5549\u9aa8\u67b6\u591a\u6837\u6027\u6784\u5efa\u3002\u56fe\u7247\u6765\u6e90\uff1aJ. Am. Chem. Soc.<\/em><\/span><\/p>\n


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\u6700\u8fd1\uff0c\u4ed6\u4eec\u8fd0\u7528\u914d\u4f53\u8c03\u63a7\u7b56\u7565\u518d\u6b21\u5b9e\u73b0\u544b\u5583\u5e76\u55b9\u5549\u916e\u548c\u5432\u54da\u5e76\u9999\u8c46\u7d20\u4e24\u7c7b\u7ed3\u6784\u7684\u591a\u6837\u6027\u6784\u5efa<\/strong>\u3002\u4f5c\u8005\u901a\u8fc7\u5bf9\u544b\u5583\u5e76\u55b9\u5549\u916e\u548c\u5432\u54da\u5e76\u9999\u8c46\u7d20\u8fd9\u4e24\u7c7b\u770b\u4f3c\u4e0d\u76f8\u5e72\u7684\u9aa8\u67b6\u7ed3\u6784\u8fdb\u884c\u9006\u5408\u6210\u5206\u6790\uff0c\u53d1\u73b0\u4e86\u5b83\u4eec\u90fd\u5177\u6709\u5171\u540c\u7684\u57fa\u5143\u7247\u6bb5\uff1a2-\u7f9f\u57fa-2′-\u6c28\u57fa\u4e8c\u82ef\u7094\u548c\u7fb0\u57fa\u3002\u5047\u5982\u80fd\u7528\u8fd9\u6837\u4e00\u4e2a\u7b80\u5355\u5e95\u7269\u9009\u62e9\u6027\u63d2\u7fb0\u73af\u5408\uff0c\u5c31\u53ef\u4ee5\u4e00\u6b65\u5408\u6210\u8fd9\u6837\u4e24\u7c7b\u4e0d\u540c\u7684\u7ed3\u6784\u3002\u7136\u800c\uff0c\u7531\u4e8e\u7094\u70c3\u7684\u4e24\u7aef\u4e00\u8fb9\u662f\u82ef\u80fa\u53d6\u4ee3\u3001\u4e00\u8fb9\u662f\u82ef\u915a\u53d6\u4ee3\uff0c\u8fd9\u5c31\u4ea7\u751f\u4e86\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\uff1a\u9762\u5bf9\u4e24\u79cd\u4e0d\u540c\u7684\u914d\u4f4d\u4f4d\u70b9\u3001\u4eb2\u6838\u4f4d\u70b9\u3001\u73af\u5408\u4f4d\u70b9\u3001\u63d2\u7fb0\u4f4d\u70b9\uff0c\u5982\u4f55\u8ba9\u8fd9\u4e2a\u7b80\u5355\u5e95\u7269\u6309\u7167\u610f\u613f\u6709\u5e8f\u5730\u3001\u9009\u62e9\u6027\u5730\u8fdb\u884c\u63d2\u7fb0\u73af\u5408\uff1f\u4f5c\u8005\u518d\u6b21\u8fd0\u7528\u914d\u4f53\u6548\u5e94\u3001\u914d\u4f4d\u7535\u8d1f\u6027\u4ee5\u53ca\u63d2\u7fb0\u901f\u7387\u7684\u5fae\u5c0f\u5dee\u522b\uff0c\u5927\u5e45\u5ea6\u7684\u626d\u8f6c\u4e86\u53cd\u5e94\u9014\u5f84\u3002<\/span><\/p>\n

\"\u914d\u4f53\u201c\u6307\u6325\u201d\u5e73\u9762\u751f\u7269\u78b1\u591a\u6837\u6027\u5408\u6210\"<\/p>\n

\u56fe4. \u5408\u6210\u6311\u6218\u53ca\u89e3\u51b3\u7b56\u7565\u3002\u56fe\u7247\u6765\u6e90\uff1aAngew. Chem. Int. Ed.<\/em><\/span><\/p>\n


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\u901a\u8fc7\u5bf9\u50ac\u5316\u5242\u4ee5\u53ca\u914d\u4f53\u6548\u5e94\u7684\u8003\u5bdf\uff0c\u53d1\u73b0\u4f7f\u7528\u5e73\u9762\u521a\u6027\u7f3a\u7535\u6027\u76841,10-\u83f2\u5570\u5549\u4e8c\u916e\u4f5c\u4e3a\u914d\u4f53\uff0c\u53ef\u4ee5\u5b9e\u73b0\u201c\u6c27\u73af\u5408\u6c2e\u63d2\u7fb0\u201d\u7684\u9014\u5f84\uff0c\u83b7\u5f97\u544b\u5583\u5e76\u55b9\u5549\u916e\u7ed3\u6784\uff1b\u800c\u4f7f\u7528\u5927\u4f4d\u963b\u5bcc\u7535\u6027\u7684\u53cc\u9f7f\u81a6dppm\u4f5c\u4e3a\u914d\u4f53\u65f6\uff0c\u5219\u5b9e\u73b0\u201c\u6c2e\u73af\u5408\u6c27\u63d2\u7fb0\u201d\u7684\u9014\u5f84\uff0c\u9009\u62e9\u6027\u83b7\u5f97\u5432\u54da\u5e76\u9999\u8c46\u7d20\u7ed3\u6784\u3002\u540c\u65f6\uff0c\u8fd9\u4e00\u6a21\u578b\u8fd8\u53ef\u9002\u7528\u4e8e\u5176\u4ed6\u4e00\u7cfb\u5217\u4eb2\u6838\u8bd5\u5242\uff08\u7fa7\u57fa\u3001\u6c28\u57fa\u3001\u9170\u80fa\u3001\u5bcc\u7535\u5b50\u82b3\u70c3\u7b49\uff09\uff0c\u975e\u5e38\u9ad8\u6548\u7684\u5b9e\u73b0\u591a\u79cd\u591a\u5e76\u73af\u7ed3\u6784\u751f\u7269\u78b1\u7684\u591a\u6837\u6027\u5408\u6210\u3002<\/span><\/p>\n

\"\u914d\u4f53\u201c\u6307\u6325\u201d\u5e73\u9762\u751f\u7269\u78b1\u591a\u6837\u6027\u5408\u6210\"<\/p>\n

\u56fe5. \u544b\u5583\u5e76\u55b9\u5549\u916e\u548c\u5432\u54da\u5e76\u9999\u8c46\u7d20\u7684\u591a\u6837\u6027\u6784\u5efa\u3002\u56fe\u7247\u6765\u6e90\uff1aAngew. Chem. Int. Ed.<\/em><\/span><\/p>\n


<\/p>\n

\u8fd9\u4e00\u5de5\u4f5c\u6700\u8fd1\u53d1\u8868\u5728<\/span>Angew. Chem. Int. Ed. <\/strong><\/em><\/span>\u4e0a\u3002<\/span><\/p>\n


<\/p>\n

\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong>Dong Ding, Guohao Zhu and Xuefeng Jiang<\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

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Ligand Controlled Pd(II)-Catalyzed Regiodivergent Carbonylation of Alkynes for Syntheses of Indolo[3,2-c]coumarins and Benzofuro[3,2-c]quinolinones<\/span><\/p>\n

Angew. Chem. Int. Ed.<\/span><\/em>, 2018<\/strong>, DOI: 10.1002\/anie.201804788<\/span><\/p>\n


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\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n

\u59dc\u96ea\u5cf0<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/10557<\/span><\/p>\n


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\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

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\u59cb\u53d1\u4e8e\u5fae\u4fe1\u516c\u4f17\u53f7\uff1a X\u4e00MOL\u8d44\u8baf <\/p>\n<\/blockquote>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

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