{"id":8795,"date":"2018-06-11T01:00:00","date_gmt":"2018-07-27T09:34:26","guid":{"rendered":"http:\/\/www.05921.net\/index.php\/2018\/07\/27\/%e3%80%90%e5%82%ac%e5%8c%96%e3%80%91%e9%9d%9e%e8%a1%80%e7%ba%a2%e7%b4%a0%e9%94%b0%e9%85%8d%e5%90%88%e7%89%a9%e4%bf%83%e8%bf%9b%e4%bb%bf%e7%94%9f%e5%82%ac%e5%8c%96%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94\/"},"modified":"2018-07-27T17:34:27","modified_gmt":"2018-07-27T09:34:27","slug":"%e3%80%90%e5%82%ac%e5%8c%96%e3%80%91%e9%9d%9e%e8%a1%80%e7%ba%a2%e7%b4%a0%e9%94%b0%e9%85%8d%e5%90%88%e7%89%a9%e4%bf%83%e8%bf%9b%e4%bb%bf%e7%94%9f%e5%82%ac%e5%8c%96%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"https:\/\/www.05921.net\/index.php\/8795\/","title":{"rendered":"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55"},"content":{"rendered":"
\n

\u200d\u200d<\/span>\u200d\"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\"<\/a><\/span><\/a><\/p>\n


<\/p>\n

\u751f\u7269\u4f53\u5229\u7528\u91d1\u5c5e\u9176\u6d3b\u5316\u6c27\u6c14\u5b8c\u6210\u65b0\u9648\u4ee3\u8c22\u7684\u6c27\u5316\u8fc7\u7a0b\uff0c\u53d7\u6b64\u542f\u53d1\uff0c\u8fd1\u5e74\u6765\u4eba\u4eec\u53d1\u5c55\u4e86\u4e00\u7c7b\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\uff0c\u5229\u7528\u57fa\u4e8e\u56db\u6c2e\u914d\u4f53\u7684\u94c1\u3001\u9530\u914d\u5408\u7269\uff0c\u5728\u7fa7\u9178\u7684\u8f85\u52a9\u4e0b\u6d3b\u5316H<\/span>2<\/sub><\/span>O<\/span>2<\/sub><\/span>\uff0c\u5b9e\u73b0\u4e86\u5bf9C=C\u952e\u548cC-H\u952e\u7684\u9ad8\u6548\u3001\u9ad8\u7acb\u4f53\u9009\u62e9\u6027\u6c27\u5316\u3002\u4e0e\u94c1\u4f53\u7cfb\u76f8\u6bd4\uff0c\u9530\u50ac\u5316\u4f53\u7cfb\u4e0d\u4ec5\u66f4\u52a0\u9ad8\u6548\uff0c\u800c\u4e14\u5e38\u8868\u73b0\u51fa\u66f4\u597d\u7684\u9009\u62e9\u6027\u3002\u7136\u800c\uff0c\u5728\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u65b9\u9762\uff0c\u7531\u4e8e\u8c31\u5b66\u8868\u5f81\u65b9\u9762\u7684\u6b20\u7f3a\uff0c\u9530\u50ac\u5316\u4f53\u7cfb\u7684\u673a\u7406\u7814\u7a76\u843d\u540e\u4e8e\u76f8\u5e94\u7684\u94c1\u4f53\u7cfb\uff0c\u5236\u7ea6\u4e86\u8be5\u7c7b\u4eff\u751f\u50ac\u5316\u4f53\u7cfb\u7684\u53d1\u5c55\u3002<\/span><\/p>\n

\"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\"<\/p>\n


<\/span><\/p>\n

\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5170\u5dde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240<\/strong>\u7684\u5b59\u4f1f<\/strong>\u7814\u7a76\u56e2\u961f\u5728\u524d\u671f\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff08Chem. Eur. J.<\/em>, 2012<\/strong>, 18<\/em>, 6750; Chem. Eur. J.<\/em>, 2012<\/strong>, 18<\/em>, 7332; J. Am. Chem. Soc.<\/em>, 2016<\/strong>, 138<\/em>, 936\uff09\uff0c\u7cfb\u7edf\u5730\u5f00\u5c55\u4e86\u9530\u914d\u5408\u7269\u50ac\u5316\u70ef\u70c3\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u53cd\u5e94\u7684\u673a\u7406\u7814\u7a76<\/strong>\u3002\u4ed6\u4eec\u5229\u7528\u4e00\u5bf9\u7ed3\u6784\u76f8\u4f3c\u7684\u56db\u6c2e\u548c\u4e94\u6c2e\u9530\u914d\u5408\u7269\u7814\u7a76\u4e86\u7fa7\u9178\u5728\u9530\u50ac\u5316\u5242\u6d3b\u5316H<\/span>2<\/sub><\/span>O<\/span>2<\/sub><\/span>\u8fc7\u7a0b\u4e2d\u7684\u4f5c\u7528\uff0c\u53d1\u73b0\u9530\u4e2d\u5fc3\u914d\u4f4d\u7684\u7fa7\u9178\u662f\u52a0\u901f\u6c27\u5316\u5242O-O\u952e\u65ad\u88c2\u7684\u5173\u952e\u56e0\u7d20\uff0c\u8fdb\u800c\u5f62\u6210\u9ad8\u6d3b\u6027\u7684Mn=O\u4e2d\u95f4\u4f53\u3002\u8be5\u53d1\u73b0\u4e5f\u9002\u7528\u4e8e\u70f7\u57fa\u8fc7\u6c27\u5316\u6c22\u6c27\u5316\u5242\uff08\u5982\u53d4\u4e01\u57fa\u8fc7\u6c27\u5316\u6c22\u3001\u67af\u57fa\u8fc7\u6c27\u5316\u6c22\uff09\u7684\u6d3b\u5316\u3002\u4ed6\u4eec\u8fd8\u53d1\u73b0\uff0c\u5728\u4e0d\u540c\u6c27\u5316\u5242\uff08\u5982H<\/span>2<\/sub><\/span>O<\/span>2<\/sub><\/span>\u3001\u70f7\u57fa\u8fc7\u6c27\u5316\u6c22\u3001PhIO\uff09\u7684\u6761\u4ef6\u4e0b\uff0c\u70ef\u70c3\u73af\u6c27\u5316\u4ea7\u7269\u7684\u5bf9\u6620\u9009\u62e9\u6027\u76f8\u540c\uff0c\u987a\u5f0f\u4e8c\u82ef\u4e59\u70ef\u73af\u6c27\u5316\u53cd\u5e94\u4ea7\u7269\u7684\u5f02\u6784\u5316\u6bd4\u4f8b\u4e5f\u76f8\u540c\uff0c\u7531\u6b64\u63a8\u6d4b\u5728\u6709\u673a\u7fa7\u9178\u7684\u5b58\u5728\u4e0b\uff0c\u8fd9\u4e9b\u6c27\u5316\u5242\u4e0e\u9530\u50ac\u5316\u5242\u5f62\u6210\u76f8\u540c\u7684\u6d3b\u6027\u4e2d\u95f4\u4f53\uff08LMn=O\uff09\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u83b7\u5f97\u6d3b\u6027\u4e2d\u95f4\u4f53\uff08LMn=O\uff09\u7684\u4fe1\u606f\uff0c\u4ed6\u4eec\u5229\u7528\u67af\u57fa\u8fc7\u6c27\u5316\u6c22\u63a2\u9488\u5b9e\u9a8c\uff0c\u9610\u660e\u4e86O-O\u952e\u901a\u8fc7\u5f02\u88c2\u65b9\u5f0f\u5f97\u5230LMn<\/span>V<\/sup><\/span>=O\u7684\u8fc7\u7a0b\u3002\u7531\u4e8eMn<\/span>V<\/sup><\/span>=O\u5177\u6709\u9ad8\u53cd\u5e94\u6d3b\u6027\uff0c\u96be\u4ee5\u7528\u73b0\u6709\u7684\u8c31\u5b66\u8868\u5f81\u624b\u6bb5\u6355\u83b7\u3002\u9274\u4e8e\u6b64\uff0c\u4ed6\u4eec\u8fd8\u5236\u5907\u5e76\u8868\u5f81\u4e86LMn<\/span>IV<\/sup><\/span>=O\uff0c\u53d1\u73b0\u5176\u4e0d\u5177\u5907\u6c27\u5316\u70ef\u70c3\u7684\u80fd\u529b\uff0c\u8fdb\u800c\u95f4\u63a5\u8bc1\u660e\u53cd\u5e94\u7684\u5173\u952e\u6d3b\u6027\u4e2d\u95f4\u4f53\u4e3aLMn<\/span>V<\/sup><\/span>=O\u3002\u4ee5\u4e0a\u7814\u7a76\u63ed\u793a\u4e86\u7fa7\u9178\u53c2\u4e0e\u9530\u50ac\u5316\u5242\u6d3b\u5316\u8fc7\u6c27\u5316\u6c22\u53cd\u5e94\u673a\u7406\u7684\u672c\u8d28\uff0c\u660e\u786e\u4e86\u91d1\u5c5e\u4e2d\u5fc3\u63d0\u4f9b\u4e24\u4e2acis <\/em>\u914d\u4f4d\u70b9\u7684\u91cd\u8981\u6027\uff0c\u4e3a\u9ad8\u6548\u6c27\u5316\u50ac\u5316\u5242\u7684\u4f18\u5316\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u7406\u8bba\u4f9d\u636e\u3002<\/span><\/p>\n

\"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\"<\/p>\n


<\/p>\n

\u76f8\u5173\u6210\u679c\u53d1\u8868\u5728<\/span>ACS Catalysis <\/em><\/strong><\/span>\u4e0a\uff0c\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u535a\u58eb\u751f\u675c\u4fca\u6bc5<\/strong>\uff0c\u901a\u4fe1\u4f5c\u8005\u4e3a\u5b59\u4f1f<\/strong>\u7814\u7a76\u5458\u548cNam Wonwoo<\/strong>\u6559\u6388\uff08\u4e2d\u79d1\u9662\u5170\u5dde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u201c\u5916\u4e13\u5343\u4eba\u201d\uff09\u3002<\/span><\/p>\n


<\/span><\/p>\n

\u8be5\u7cfb\u5217\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\uff0821473226, 21773273\uff09\u3001\u4e2d\u7ec4\u90e8\u201c\u5916\u4e13\u5343\u4eba\u201d\u548c\u5170\u5dde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u201c\u4e00\u4e09\u4e94\u201d\u89c4\u5212\u9879\u76ee\u4ee5\u53ca\u7fb0\u57fa\u5408\u6210\u4e0e\u9009\u62e9\u6c27\u5316\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7684\u652f\u6301\u3002<\/span><\/p>\n


<\/p>\n

\u8be5\u8bba\u6587\u4f5c\u8005\u4e3a\uff1a<\/span><\/strong>Junyi Du, Chengxia Miao, Chungu Xia, Yong-Min Lee, Wonwoo Nam and Wei Sun<\/span><\/p>\n

\u539f\u6587\uff08\u626b\u63cf\u6216\u957f\u6309\u4e8c\u7ef4\u7801\uff0c\u8bc6\u522b\u540e\u76f4\u8fbe\u539f\u6587\u9875\u9762\uff09\uff1a<\/span><\/p>\n

\"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\"<\/p>\n

Mechanistic Insights into the Enantioselective Epoxidation of Olefins by Bioinspired Manganese Complexes: Role of Carboxylic Acid and Nature of Active Oxidant<\/span><\/p>\n

ACS Catal.<\/span><\/em>, 2018<\/strong>, 8<\/em>, 4528, DOI: 10.1021\/acscatal.8b00874<\/span><\/p>\n


<\/span><\/p>\n

\u5bfc\u5e08\u4ecb\u7ecd<\/span><\/p>\n

\u5b59\u4f1f<\/span><\/p>\n

http:\/\/www.x-mol.com\/university\/faculty\/16685<\/span><\/p>\n


<\/p>\n

\n
\n
\n
\n

\"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\"<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n


<\/p>\n

\"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\"<\/p>\n

\n
\n
\n
\n
<\/section>\n
<\/section>\n
<\/section>\n<\/section>\n
\n
\n
\n
\n

\u672c\u6587\u7248\u6743\u5c5e\u4e8eX-MOL<\/strong><\/span>\uff08x-mol.com\uff09\uff0c\u672a\u7ecf\u8bb8\u53ef\u8c22\u7edd\u8f6c\u8f7d\uff01\u6b22\u8fce\u8bfb\u8005\u670b\u53cb\u4eec\u5206\u4eab\u5230\u670b\u53cb\u5708or\u5fae\u535a\uff01<\/span><\/p>\n


<\/p>\n

\u957f\u6309<\/strong><\/span>\u4e0b\u56fe\u8bc6\u522b\u56fe\u4e2d\u4e8c\u7ef4\u7801<\/strong>\uff0c\u8f7b\u677e\u5173\u6ce8\u6211\u4eec\uff01<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n

\n

\"\u3010\u50ac\u5316\u3011\u975e\u8840\u7ea2\u7d20\u9530\u914d\u5408\u7269\u4fc3\u8fdb\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76\u53d6\u5f97\u65b0\u8fdb\u5c55\"<\/p>\n<\/section>\n<\/section>\n

\n
<\/section>\n
<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\n
\n
\n
\n
\n
\n
\n
\n


<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u70b9\u51fb\u201c\u9605\u8bfb\u539f\u6587<\/span>\u201d\uff0c\u67e5\u770b \u5316\u5b66 \u2022 \u6750\u6599 <\/strong>\u9886\u57df\u6240\u6709\u6536\u5f55\u671f\u520a<\/span><\/span><\/p>\n

<\/span><\/p>\n

\n

\u59cb\u53d1\u4e8e\u5fae\u4fe1\u516c\u4f17\u53f7\uff1a X\u4e00MOL\u8d44\u8baf <\/p>\n<\/blockquote>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

\u200d\u200d\u200d \u751f\u7269\u4f53\u5229\u7528\u91d1\u5c5e\u9176\u6d3b\u5316\u6c27\u6c14\u5b8c\u6210\u65b0\u9648\u4ee3\u8c22\u7684\u6c27\u5316\u8fc7\u7a0b\uff0c\u53d7\u6b64\u542f\u53d1\uff0c\u8fd1\u5e74\u6765\u4eba\u4eec\u53d1\u5c55\u4e86\u4e00\u7c7b\u4eff\u751f\u50ac\u5316\u6c27\u5316\u53cd\u5e94\uff0c\u5229\u7528\u57fa […]<\/p>\n","protected":false},"author":1,"featured_media":8796,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[2],"tags":[],"_links":{"self":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/8795"}],"collection":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/comments?post=8795"}],"version-history":[{"count":1,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/8795\/revisions"}],"predecessor-version":[{"id":8804,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/posts\/8795\/revisions\/8804"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media\/8796"}],"wp:attachment":[{"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/media?parent=8795"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/categories?post=8795"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.05921.net\/index.php\/wp-json\/wp\/v2\/tags?post=8795"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}